Search

Energy use, together with consumption of raw materials, machine clothing, and wet end chemicals, are some of the most critical aspects in successful tissue making today. This work was aimed at developing a laboratory-scale method of estimating dewatering mechanisms, vacuum efficiency, and energy use of Through Air Drying (TAD) of tissue. When compared to pilot data, the results of the new laboratory method for investigating dewatering during TAD were in the same magnitude, around 24 to 26% dryness after vacuum dewatering, and 27 to 29% dryness after TAD molding. Sheet properties, such as caliper and surface profile, were evaluated and compared to commercial tissue sheets. The results indicate that it will be possible to precisely measure accurate dryness development and penetrated air volume for tissue sheet forming and TAD molding at a laboratory scale. This can contribute to the efforts of implementing a circular forest-based bioeconomy by increasing the fundamental understanding of dewatering of tissue paper materials, which is facilitated by improvements in energy use. The new method developed in this work will make it easier to assess ideas that are difficult to bring to pilot scale or full scale before learning more of the dewatering capabilities. The authors are convinced that improved knowledge of tissue dewatering mechanisms, forming, and material transport during and after TAD dewatering can increase the efficiency of the industrial manufacturing processes.

Environmental problems have attracted much attention in recent years, especially for papermaking wastewater discharge. To reduce the loss of effluence discharge violation, quality-related multivariate statistical methods have been successfully applied to achieve a robust wastewater treatment system. In this work, a new dynamic multiblock partial least squares (DMBPLS) is proposed to extract the time-varying information in a large-scale papermaking wastewater treatment process. By introducing augmented matrices to input and output data, the proposed method not only handles the dynamic characteristic of data and reduces the time delay of fault detection, but enhances the interpretability of model. In addition, the DMBPLS provides a capability of fault location, which has certain guiding significance for fault recovery. In comparison with other models, the DMBPLS has a superior fault detection result. Specifically, the maximum fault detection rate of the DMBPLS is improved by 35.93% and 12.5% for bias and drifting faults, respectively, in comparison with partial least squares (PLS).

The pursuit for sustainability in the papermaking industry calls for the elimination or reduction of synthetic additives and the exploration of renewable and biodegradable alternatives. Cellulose nanofibrils (CNFs), due to their inherent morphological and biochemical properties, are an excellent alternative to synthetic additives. These properties enable CNFs to improve the mechanical, functional, and barrier properties of different types of paper. The nanosize diameter, micrometre length, semicrystalline structure, high strength, and modulus of CNFs have a direct influence on the mechanical properties of paper, such as tensile index, burst index, Scott index, breaking length, tear index, Z-strength, E-modulus, strain at break, and tensile stiffness. This review details the role played by CNFs as an additive to improve strength properties of paper and the factors affecting the improvement in paper quality when CNFs are added as additives. The paper also includes techno-economic aspects of the process and identifies areas that need further research.

The bamboo biomass is widely available in tropical countries and is actually being used for papermaking on a commercial scale in other countries. Its comparable cellulosic content to wood resources in the pulp and paper industry corresponds to its suitability as a substitute in view to reduce our dependency on wood and in line with sustainability. Accordingly, the study investigated the production of paper from the non-wood fibre for subsequent uses hinged on its physical and mechanical characteristics. It also targets paper waste since the latter was employed in different mixing ratios (20:80, 40:60, 60:40 and 80:20). Value added materials, namely envelopes, paper bags and holders were produced in order to open new arenas for the Mauritian fibre industry. Soda process was employed as the chemical pulping process. The optimum cooking conditions, giving rise to the highest pulp yield were found to be 16% w/v NaOH and a cooking time of 2 h at 90 °C. The thickness of the formed sheets was between 0.376 mm and 0.593 mm. Paper made from 100% bamboo was found to be most resistant to soil degradation. The highest bursting index was obtained from 80% bamboo sheet, amounting to 1.86kPam2/g. Sheets constituting of 20% and 40% bamboo showed favourable results to be used as printing materials and were observed to be most resistant to abrasion, requiring 40 and 26 turns, respectively. The minimum water absorbency rate of sheets derived from 80 and 100% bamboo connotes to their use as absorbents. The crease recovery angles were found to be within 27.5° to 63.8°, implying the application of 100%, 80% and 60% bamboo mix in the manufacture of envelopes and paper bags.

Graphene paper with good mechanical strength, flexibility, and high conductivity is an emerging functional material for wide applications, but its feasible and scalable preparation remains a challenge. Herein, a high strength, flexible, and conductive graphene/polypropylene (PP) fiber paper was prepared by a traditional papermaking process. In the composite paper, graphene nanosheets were well stabilized on the PP fibers forming a stable three-dimensional conductive interleaved network. Chitosan was found able to build a polar active interface on PP fibers and graphene nanosheets, which can not only promote PP fiber dispersion in water yielding a uniform pulp, but also favor the retention of graphene in the composite paper. As a result, the composite paper presents high strength (15.32 MPa), good conductivity (11,995 S/m), shielding effectiveness (31.1 dB), water resistance, fungi-proof, and thermal conductivity (10.17 W m−1 k−1) properties. This work demonstrates the feasibility of large-scale preparation of graphene composite paper with commercial synthetic fibers through a traditional papermaking process, and expands the potential industrial application of graphene materials. Graphene/chitosan co-aggregates were absorbed on the surface of graphene/chitosan/PP fiber under the electrostatic interaction of CPAM to form graphene/PP fiber.

Pulp writing materials made from wood-based origin and incorporating other fibers such as hemp waste, rags, and fishnets has been in existence since 105 CE when Cai Lun, a Chinese political official and inventor in the court of Emperor Hedi of Han, created the machinery and effective process of papermaking in China using the inner bark of the mulberry plant, hemp, rags from used clothing, and used fishnets. The mulberry bark was boiled down to create strands of fibers and macerated with hemp, rags, and fishnets to create the pulp used in processing the paper. Lun was assisted by his apprentice, Zuo Bo, who helped improve the overall process in 150 CE. Lun’s paper products superseded bamboo tablets and cloth made of pure silk as the primary writing material in China at that time [2] . The secret of papermaking was closely held by the Chinese until the sixth century, when the Japanese acquired the knowledge to produce their own paper. Then, by the eighth century, the Arab world began utilizing fine grades of hemp and linen with water to create pulp that they processed into a high grade of paper that was coated with rice starch when dried so it would be more receptive to inks. Unfortunately, the rice starch coating served also as a source of food for insects that destroyed many of the finished goods.

Guided bone regeneration (GBR) technology is a commonly used surgical procedure for the repair of damaged periodontal tissues. Poor mechanical property and rapid degradation rate are the major reasons for GBR membrane failure in clinical applications. Herein, we applied a green papermaking method to fabricate silk fibroin (SF) membranes blended with collagen and tested their performance. The results showed that the blended SF75 (SF and collagen in a weight ratio of 75:25) membranes are biocompatible with good mechanical properties in the wet condition and appropriate biodegradation rate. MC3T3-E1 osteoblast cell adhesion and proliferation on the membranes were improved by the hybrid biological functions of SF and collagen. Subcutaneous implantation in rats for 9 weeks demonstrated that the membranes induced a less severe inflammatory response. The biodegradation time of the SF75 membranes was appropriate for tissue regeneration. This research, for the first time, reports a blended membrane prepared from silk fibroin and collagen with an ecofriendly method, which shows promise for application in guided bone regeneration.

Polylactic acid is a biodegradable thermoplastic polyester derived from renewable polysaccharides. In this work, softwood fibers were used to reinforce the paper sheet made from polylactic acid fibers, thus addressing the challenges regarding low density, rough surface, and weak strength. The impact of wood fibers and calendering on the physical properties (density, roughness, tensile strength, and folding endurance) of the composite paper were identified. Furthermore, the morphology of papers with different fiber contents and those that had been calendered was characterized with a scanning electron microscope. The use of wood fibers resulted in the improvement of the physical properties of the polylactic acid paper, and the enhanced refining of wood fibers had a favorable role in improving paper density, smoothness, and mechanical strength. The tensile index increased 37.9% when the beating degree of wood fibers increased from 25 to 60 °SR. After calendering, the density, smoothness, tensile strength, folding endurance, and air barrier property of the paper were improved 60.2%, 45.8%, 15.5%, 148.1%, and 79.4%, respectively. The calendering-based papermaking process involving the combined use of wood fibers and polylactic acid fibers would be a promising strategy for designing composite materials for tailorable end-uses.

We present how harmful different wood extractives carried over to paper mill with unbleached softwood Kraft pulp are for the strength of packaging papers and boards. The investigations were done by simulating industrial papermaking conditions in laboratory-scale trials for handsheet production. It was found that fatty acids are the most relevant compounds in the carryover pitch extractives (CPEs), as they readily interfere in fiber–fiber bonding strength, control the properties of CPE micelles, and are furthermore the most abundant compounds. Addition of cationic starch improved strength and evened out the strength differences of handsheets with different CPE compounds. Oleic acid (unsaturated fatty acid) was an exception, as it was above average harmful for paper strength without cationic starch and also heavily impaired the functioning of cationic starch. As a whole, these findings demonstrate that fatty acids, especially unsaturated ones, are the most relevant CPE compounds contributing to the reduced efficiency of cationic starch and decreased strength of unbleached softwood Kraft paper. This makes the cleaning of process waters by precipitating CPEs on the pulp fibers harmful for paper strength.

In papermaking, pre-flocculation of fillers such as ground calcium carbonate (GCC) improves the tensile strength of paper sheets. However, the pre-flocculated fillers mostly suffer from the instability of the floc shape such as the decrease in floc diameter with time elapse after preparation and no improvement of bulk and stiffness. The addition of calcium compounds such as calcium oxide or calcium hydroxide to the pre-flocculated GCC, and injection with carbon dioxide caused pre-flocculated GCC flocs to be covered with newly formed calcium carbonate. This product, called post hybrid calcium carbonate (pHCC), was found to be more stable in size and gave better sheet strength than the pre-flocculated ones. Furthermore, pHCC gave remarkably higher bulk and stiffness than the pre-flocculated flocs did without impairing smoothness that was essential in printing paper. The proper use of pHCC in papermaking could allow the production of high loaded paper with more than 10% higher filler contents, which could reduce paper production cost and save drying energy. The proportion of the newly formed calcium carbonate in pHCC, turbulence intensity at preparation stage, and the effect of storage time were investigated.

Developing a feasible and efficient separation membrane for the purification of emulsified oily wastewater is challenging due to the critical limitations of serious fouling during membrane preparation. Herein, underwater superoleophobic paper-based materials with high wet strength were prepared by low cost and green papermaking technology. The fibrillation of cellulose fibers was achieved by beating to optimize the pore structure of paper sheets. Simple modification of paper sheets with 1,2,3,4-butanetetracarboxylic acid significantly improves the surface hydrophilicity and the wet strength through the crosslinking reaction between fibers. The maximum underwater oil contact angle and wet strength of the modified paper sheets are high up to 167.8°and 36.5 N·m/g, respectively. The water flux can be adjusted in the range of 25.8 L m−2 h−1–4920 L m−2 h−1 by controlling the average pore size from 6.64 μm to 18.9 μm. Lower pore size and higher carboxyl content of the paper-based materials are beneficial to improve the oil rejection, which can reach more than 99.3% even for submicron emulsified oils. Most of the paper sheets achieve efficient oil–water separation although the average pore size is remarkably larger than the emulsified oil droplet. The reason can be attributed to the zigzag pore structure of paper sheets, which is favorable to form liquid bridge on the surface as well as collision demulsification in the Z-direction channel, thereby promoting the mechanical interception effects. The low-cost, eco-friendly, easily-manufactured and highly efficient paper-based separation materials possess wide applications in oily wastewater treatment.

This study proposes a data-driven model for monitoring and diagnosis in energy system of papermaking process based on kernel component analysis (KPCA) and the kernel slow feature analysis (KSFA). F...

Paper drying is the most energy-intensive step in papermaking and around 90% of the total amount of manufactured paper is produced in multi-cylinder dryers. A framework based on a physical model of...

There have been recent attempts to revive the traditional production of handmade paper from the bark of the Coi (Streblus asper Lour.) tree in Thailand. A sheet sample of Coi handmade paper, made from the traditional production, was collected and examined microscopically for the first time. Film-like material and cubic calcium particles were found on the sheet sample surface, which is consistent with the results of the authors’ previous research. Meanwhile, handsheets derived from Coi pulp fiber, freshly made in the laboratory, demonstrated a low air permeance and brightness with high opacity due to the film-like material and cubic calcium particles. With a high felting power of Coi pulp fiber coupled with a possible strengthening role of the film-like material, both the beaten and unbeaten fibers were used to form handsheets with high strength. Some potential aspects of Coi pulp fiber suitable for creating a unique Thai banknote paper have been demonstrated, for which further studies are suggested.

The X-ray diffraction internal standard method can quantitatively determine the ash content of paper, but the requirements for the experimental environment are high, the determination is not convenient and the cost is high, and it is difficult to be widely used in the papermaking enterprises. In order to determine the total ash and its components of the single filler paper samples, and meet the ash determination requirements of papermaking enterprises, the continuous X-ray method is proposed. In this paper, an X-ray tube is used as the radiation source and an ionization chamber is used as the detector. Through polynomial fitting of the total ash and voltage logarithm ratio of the single filler paper samples, the mathematical model of total ash is established; the total ash and its components content of paper are calculated according to the mathematical model of total ash and the Beer–Lambert law deformation formula; the total ash and its components content of paper are verified by the burning method. The research results show that the total ash error of the single filler paper samples is less than 4%, and the ash component error is less than 5%.

Despite previous efforts, the fabrication of superhydrophobic substrate via an environment friendly and easy approach remains a great challenge. In this study, a low cost, simple, and green procedure was developed to prepare a superhydrophobic paper surface that is acceptable for the papermaking industry. First, a wax mixture (beeswax & carnauba wax) was emulsified and coated on the filter paper surface. Then, the coated paper was annealed at different temperatures. The further heat-treatment-rendered wax-coated paper hydrophobic or superhydrophobic because submicrometer or micrometer wax structures were present on the paper surface. The water contact angle of the annealed filter paper sample reached 151.5° at 60 °C, and the sliding angle was under 10°. Further, the relationship between surface composition and the hydrophobic properties of the coated paper samples was discussed. The obtained paper samples showed great potential in water/oil separation, as they had an efficiency over 99%. This work proposed a new simple and mild approach to fabricate superhydrophobic filter papers and explored the hydrophobicity and water/oil separation properties.

Hura crepitans L. (Euphorbiaceae) is a tropic tree species that was investigated for pulp and paper characteristics in this study. The diameters of five (5) different stands of Hura crepitans trees were first determined using diameter tape. Wood slivers were obtained from sapwood of the trees parallel to grain and at three (3) different positions along the axis, at the base (5%), middle (50%) and top (90%). The wood slivers were macerated in a mixture of equal volumes of glacial acetic acid and hydrogen peroxide at between 80 -100 degrees Celsius for 2 hours. Macerated fibres were washed and used to prepare microscopic slides where 15 fibres were measured per slide. Data recorded was subjected to One-way Analysis of Variance (ANOVA) based on Completely Randomized Design (CRD). Results show that both the primary fibre characteristics and derived characteristics were significantly different at p

Mechanical pulping of raw wood material is a highly energy intensive and pollution generating step in the papermaking process. This study focused on combined mechanical and xylanase treatment prior to the kraft pulping of E. tereticornis. A screened pulp yield of 49.1% (on oven-dry wood basis) with a Kappa number of 24.9 was obtained at the optimum cooking temperature of 160 °C without any pretreatment of the wood chips. After mechanical treatment (destructuring), a slightly higher screened pulp yield (49.4%) was obtained with a Kappa number of 24.2 at the cooking temperature of 145 °C with the same active alkali charge (15%). The optimum cooking temperature was further reduced to 140 °C for the destructured xylanase-treated wood chips. The xylanase treatment resulted in a 2% reduction in screened pulp yield due to hydrolysis of xylan. However, the Kappa number was reduced to 18.2 after xylanase pretreatment of the mechanically destructured wood chips. The combined pretreatment (destructured and xylanase treatment) of wood chips resulted in a reduction in cooking temperature by 20°C compared to untreated wood chips. Such a reduction in cooking temperature can effectively reduce steam consumption. The combined pretreatment improved the pulp brightness by 2.0 (ISO points) and physical strength properties, which included the tensile index, tear index, and burst index by 11.06%, 21.72%, and 21.79%, respectively, compared to the control.

Hybrid calcium carbonate (HCC) is prepared by pre-flocculating calcium oxide and ground calcium carbonate (GCC) with ionic polymers, and by injecting carbon dioxide to the pre-flocculated flocs until termination of the reaction at neutral pH. When used in papermaking, HCC gave higher bulk, higher stiffness, and higher tensile strength than GCC did. Furthermore, when higher wet pressing pressure was applied to the paper containing HCC, higher solid content was achieved with still better stiffness, smoothness, and tensile strength in comparison with the paper containing GCC. Actually, very high bulk of the HCC containing paper was compromisingly reduced to obtain high solid content by applying higher wet pressing pressure. Higher solid content achieved by combination of HCC technology and higher wet pressing pressure resulted in paper drying energy savings of more than 10%, while a high quality of all the essential printing paper properties was maintained. Drying energy savings may contribute to greenhouse gas (GHG) reduction and lowering of the paper production cost.

Papermaking is one of the outstanding creations of the Chinese nation, from the “Cai Lun’s Technique” of the Eastern Han Dynasty to the “Four Great Inventions” of modern times and further to the present academic hotspot of “intangible cultural heritage”. The naming and expression of this object reflect the cultural cognition and interpretation of papermaking in different periods of time. It is important to note that, in the context of the intercommunication between Eastern and Western discourses, the study of papermaking is not only about the exploration of the scientific value of a traditional technique, but also is the re-examination of the communication and dissemination of cultures and technologies between the East and the West, in order to form a new understanding of “Sinicized Europe”.

Although wood is the main source for pulp and paper industry in Brazil, other renewable non-wood fibers could be key alternatives for papermaking. Thus, this study aimed to evaluate the properties of handsheets produced from a mixture of totora (Schoenoplectus californicus) (C.A. Mey.) and Eucalyptus spp. (eucalyptus) fibers. The pulps were refined in laboratory dybeater “PFI type,” varying the number of revolutions, in order to obtain refining curves in the range of 15° to 60° SR. The optical, physical, and mechanical properties of the papers produced were evaluated. The addition of totora fibers influenced refining process and paper properties. Moreover, the handsheets produced with the highest content of totora fibers showed low mechanical resistance. Totora is not suitable to be used as a single source of fibers, especially when good mechanical performance is required. However, when the fibers were mixed with eucalyptus, the mixture achieved reasonable resistance. Furthermore, higher opacity was obtained by the addition of totora (≥97%), which is interesting for the printing and writing segment.

The anisotropic ceramic fiber skeleton and its aerogel composite materials have important applications in the fields of high temperature insulation and aerospace. However, the traditional ceramic fiber skeleton has been limited in its application due to the complexity of its preparation process. Here, referencing the traditional papermaking technology, a flexible and recoverable SiO2 fiber skeleton with anisotropic layered structure was prepared through papermaking process and low-temperature sintering (170 °C) technology. Complete heteromorphic skeleton could be prepared by this simple process. On this basis, we impregnated the fiber skeleton with silica aerogel to further improve the composite properties of the pure fiber block. Compared with SiO2 fiber skeleton, the SiO2 aerogel/fiber skeleton composite exhibited lower thermal conductivity (0.023 W/(m·k)), higher compressive strength (2.19 MPa) and excellent high temperature thermal insulation. The recoverable and excellent thermal insulation properties of anisotropic layered composite materials provide an effective way for the manufacture of low-cost aerogel composite materials. At the same time, it has potential application value in high-temperature thermal insulation materials.

The traditional real-time data scheduling method ignores the optimization process of job data that leads to delayed delivery, high inventory cost, and low utilization rate of equipment. This paper proposes a novel real-time data scheduling method based on deep learning and an improved fuzzy algorithm for flexible operations in the papermaking workshop. The algorithm is divided into three parts: the first part describes the flexible job shop scheduling problem; the second part constructs the fuzzy scheduling model of flexible job data in papermaking workshop; and finally the third part uses a genetic algorithm to obtain the optimal solution of fuzzy scheduling of flexible job data in papermaking workshop. The results show that the optimal solution is obtained in 48 seconds at the 23rd attempt (iteration) under the application of the proposed method. This result is much better than the three traditional scheduling methods with which we compared our results. Hence, this paper improves the work efficiency and quality of papermaking workshop and reduces the operating cost of the papermaking enterprise.

Flocculation is the first and important step to remove suspended and slightly soluble pollutants in industrial wastewater treatment. Flocculant is just the key element for flocculation process. Polyacrylamide (PAM) is the most widely used flocculant. But it still holds some potential flaws which are ignored by people. An eco-friendly bamboo cellulose-grafted-ployacrylamide flocculant (BC-g-PAM) was then synthesized by free-radical graft copolymerization in homogeneous aqueous solution. The optimal synthesis conditions of the BC-g-PAM was investigated. FTIR, TG, XRD and FESEM were employed to characterize and define its molecular structure and physical characteristics. The BC-g-PAM was also adopted to treat an actual papermaking wastewater. The positive results showed that the BC-g-PAM exhibited an excellent flocculation performance on the papermaking wastewater. The average turbidity removal rate reached 99.7 % and related suspended solids exhibited the corresponding decline. This flocculation also caused a positive effect on the reduction of CODCr and BOD5 of the wastewater. Meanwhile, the BC-g-PAM exhibited an excellent biodegradability. Its degradation rate reached 63.4 % at 90 d in soil extracting solution.

Waste paper from newsprint, a key feedstock for molded pulp trays, is globally deficient due to digital shifts. Hence, the alternative fiber source needs to be explored. The potential use of fiber ...

One of the major challenges in the pulp and paper industry is taking advantage of the large amount of data generated through its processes in order to develop models for optimization purposes, mainly in the paper-making, where the current practice for solving optimization problems is the error-proofing method. First, the multi-ple linear regression technique is applied to find the variables that affect the output pressure controlling the gap of the paper sheet between the rod sizer and spooner sections, which is the main cause of paper breaks. As a measure to determine the predictive capacity of the adjusted model, the coefficient of determination (R2) and s values for the output pressure were considered, while the variance inflation factor was used to identify and elimi-nate the collinearity problem. Considering the same amount of data available by using machine learning, the regres-sion tree was the best model based on the root mean square error (RSME) and R2. To find the optimal operating con-ditions using the regression tree model as source of output pressure measurement, a full factorial design was developed. Using an alpha level of 5%, findings show that linear regression and the regression tree model found only four independent variables as significant; thus, the regression tree model demonstrated a clear advantage over the linear regression model alone by improving operating conditions and demonstrating less variability in output pressure. Furthermore, in the present work, it was demonstrated that the adjusted models with good predictive capacity can be used to design noninvasive experiments and obtain.

The combination of metal organic frameworks (MOFs) with other functional materials is a potential strategy for the preparation of advanced MOF-based materials. In this study, a simple approach is reported for the fabrication of cellulosic paper containing zeolitic imidazolate framework (ZIF-8) through in-situ loading in the papermaking process. The results showed that the ZIF-8 was evenly distributed in the paper substrate owing to the multi-layers structure of the cellulosic fibers, although the loading of the ZIF-8 particles on the single cellulosic fiber was nonuniform. The as-prepared ZIF-8 composites can be used as a highly efficient adsorbent material for anionic dyes in aqueous solution thanks to the positive charge on the surface of the ZIF-8 particles. More than 92% of the methyl orange (MO-) dye in the aqueous solution was rapidly removed through a simple filtration process using the ZIF-8 composite cellulosic paper (hand-sheets made in lab) when the content of ZIF-8 in cellulosic paper was high as 25.1%. In addition, the ZIF-8 composite paper had acceptable flexibility and could be reused at least 4 cycles by washing out the adsorbed dye.

Modified cassava starch is widely used in a range of applications such as food and beverage, papermaking, textiles, chemicals, constructions, adhesives, and pharmaceuticals. Hence, there is a massive demand for modified cassava starch in Indonesia. Nowadays, in the agricultural sector, our production capacity is only 1% of the total demand and this means that there are not many modified starch plantations in Indonesia. The aim of this research is to identify the external and internal factors that influence the foreign direct investment potential of modified cassava starch in Indonesia.

Modeling of the dryer section of a paper machine is of high importance in both designing and operation points of view. In this research, a novel thermodynamic and heat and mass transfer model has b...

Gelatine sizing was used extensively for western papermaking before the nineteenth century and this technique is still applied nowadays for restoration purposes. Despite its wide use, the relationships between gelatine types, the strength of the size and its distribution inside the paper sheet are still unclear. Different concentrations of three gelatines of various origins and types (A/B) were used to size model papers. The gelatine uptake, the strength of the size and the presence of gelatine at the papers surface were investigated by using a water drop test method and ATR-FTIR spectroscopy. At a given concentration, similar uptakes were found for all gelatines but great variations were observed in terms of size strength and of gelatine ability to cover the surface of paper sheets. In addition, Scanning transmission X-ray microscopy was performed on paper fibres cross sections to map the distribution of the organic compounds (both cellulosic and proteinaceous) on a nanometer scale. This showed that gelatine coats but does not penetrate the fibres. It can be inferred that the different size strengths observed between the tested gelatines are mainly due to different ways of filling holes between fibres inside the paper mat, some gelatines being more prone to go inside the sheet than others which remain mostly distributed near the surface.

Physical chemical methods were used to treat papermaking white water used to produce plant fiber mulch sheet that contained fine fibers and inorganic fillers as suspended solids. The ordinary chemical oxygen demand (CODCr) was obviously reduced after the papermaking white water was treated by the flocculant. By comparing three different coagulants (aluminum sulfate (Al2(SO4)3), poly-aluminum chloride (PAC), and poly(diallyldimethylammonium chloride) (PDADMAC)) and flocculant (poly-acrylamide copolymer (PAM)) to process papermaking white water, it was found that Al2(SO4)3 had the best coagulation effect and the lowest cost. The best flocculation conditions were 2,733 mg/L of Al2(SO4)3 and 4.52 mg/L of PAM to treat the papermaking white water. Under the best flocculation conditions, the CODCr was less than 300 mg/L. The goal of closed recycling and zero discharge of white water in the production process of plant fiber mulch sheet was realized.

In the current examination, another sort of proficient recyclable nanocomposite material dependent on characteristic biopolymer was combined with different strategies. Cellulose nanocrystals (CNCs) separated from an alternate source was set up by various methodologies, and their properties were contemplated and identified with the synthesis, handling history, and introduction to water as a boost. Other than extraction from plants, cellulose can be delivered by elective strategies, specifically by utilizing various kinds of microorganisms (certain microscopic organisms, green growth or parasites). Cellulose is utilized as a framework in the creation of nanocomposites, Cellulose has significance since it is the most plentiful and generally spread biopolymer being used. Knowing its plenitude and explicit properties, it is significant to set apart for the improvement of natural agreeable, biocompatible, and useful composites separated from its customary and enormous use in papermaking and cotton materials there are various kinds of cellulose are accessible for the arrangement of the nanocomposite, in particular vegetable cellulose (VC), bacterial cellulose (BC) and Nano fibrillated cellulose (NFC). The joining of cellulose with various fillers or grid can bring benefits like improvement of properties like optical, mechanical, and therapeutic and have exceptional capacities by their utilization. Metal NPs shows properties that vary from the fillers because of size and surface impacts, in this manner the properties of the last materials can be balanced as an element of the size, shape, molecule size dispersion of the nanofillers just as by associations happening with the cellulose fiber's surfaces.

The alarming global deforestation rate has great impacts on the output of the Pulp and paper Industry since wood is the principal papermaking fiber material. Although, generally, bamboo is an alter...

To effectively operate burning system of lignin residues from bamboo papermaking factories to provide heating, the calorific value, proximate and ultimate analysis of lignin samples with different washing processes were determined. Their combustion properties were also investigated by TGA Q500 at different heating rates. The results showed that washing processes changed fuel properties of lignin samples. The ash content decreased and the volatile content increased during washing process. They had a different content of C, H, O, N, S and calorific value. The effect of acid-soluble and acid-insoluble lignin on calorific value was not significant. Even though combustion process of all lignin samples included four stages, about 41–65% of weight loss occurred at the IV stage. The combustion characteristics and kinetics of lignin samples also varied at different heating rates. This research will provide scientific guideline for utilization of lignin residues from the bamboo papermaking industry as a biofuel.

We normally hardly notice the mass-produced paper products that pass through our hands on a daily basis, which we then recycle. In fact it has recently been predicted that books printed on paper will be replaced by digital formats. However, paper endures and specialist craft papers are now being produced in increasing quantities, especially valued by artists and conservators, but also by tourists visiting paper-producing areas around the world. Paper is therefore flourishing even in our computer and mobile-phone focused world. One of the areas benefiting from this revival is the Himalayas. As well as serving the tourist trade these products are now exported world-wide, as they were when paper first arrived in Europe in the eleventh century. There are even organisations that run Tibetan-style paper making workshops in Amer­ica. This paper focuses on the papermaking revival in Tibet (China), Nepal, Bhutan and Sikkim (India). Using information gained from visits to producers, middle men, as well as retail and export operations, it seeks to compare the economic and social factors influencing the revival, including conservation issues. The conclusion highlights the fact that, even in the twenty first century, hand-crafted items still play an important rôle in our lives.

The cultural background of the proliferation of early paper in Central Asia and its use outside China has rarely been explored. Since written sources are inconclusive regarding the origins and spread of papermaking, archaeological and material evidence assumes increased importance. The preserved manuscripts found along the Silk Road have been used as a key source in the study of religion, literature and the cultural history of Central Asia. They have, however, rarely been viewed as artefacts in their own right, with their own specific form and produced by a specific technology. Paper is one of the most important physical aspects of a manuscript and at the same time bears witness to early papermaking technologies. As an introduction to the vol­ume Asian paper as writing support, this article outlines the early history and technology of pa­permaking as revealed by the oldest manuscripts in existence, those found along the Silk Road.

Cleaner production of sugars and pulp from renewable feedstocks has captured significant scientific attention in the recent past because they can be used for various end applications. In the papermaking industry, a major fraction of hemicellulosic sugars is lost during the pulping. The present study aims at retrieving these hemicellulosic sugars through alkali-, hot-water-, and acid-mediated extraction prior to pulping, which otherwise would have been lost during pulping and washing of pulp. These retrieved sugars can be used as feedstocks for renewable energy and value-added products. Different pretreatments were applied, aided with varying temperature, chemical concentrations, and time. Substantial amounts of total reducing sugars (TRSs) up to 21.98, 13.2, and 15.01% were extracted prior to pulping by acid, alkali, and hot-water pretreatments. Compositions of mono sugars present in the treated liquor were also characterized and confirmed by high-performance liquid chromatography analysis. The morphological changes in the wheat straw after pre-extraction were studied using the field emission gun scanning electron microscopy technique. Pulping of untreated and pretreated wheat straw was carried out at different alkali charges (12, 14, and 16% NaOH). Among all, acid-pretreated straw showed an increase in pulp yield by 10.9% at a 16% alkali charge. Physical strength properties of different pulps were further examined. Alkali- and hot-water-pretreated straw pulp retained 94.26 and 83.16% tensile indices and 92.43 and 87.02% burst indices, respectively. An increase in tear index up to 4.32, 2.01, and 2.30% for alkali-, hot-water-, and acid-pretreated straw pulp was achieved, respectively. Hot-water- and alkali-pretreated wheat straw was observed to be conducive for paper production. The integrated use of wheat straw for extraction of underutilized sugars and pulp production in this way may serve as a key stepping stone for future biorefinery designs in pulp and paper mills.

Nano- and microparticles were produced from hemp shives and hemp cellulose obtained thereof, using the thermocatalytic mechanical destruction method. The partially destructed material, at concentrations of 8-9%, was dispersed in water medium in a ball mill or ground without the presence of water in a ball mill (~15 h). In the first case, a gel-like dispersion, which contained nanoparticles and microparticles, was obtained. In the second case, microparticle powder (from hemp shives) was obtained. The obtained materials were used as fillers and coatings in paper sheets. The air resistance and mechanical properties of paper sheets were investigated. It has been established that the nano/microparticle fillers improve the mechanical properties and air resistance of paper sheets. The properties of paper are improved also by coatings made from nanoparticle gels on both sides of paper sheets. Therefore, the nano/microparticle fillers and coatings obtained from hemp shives and hemp cellulose can be used in papermaking, improving the properties of paper sheets.

Theobroma glandiflorum and T. cacao, known as cupuacu and cacao, respectively, are species widely used for food purposes. However, when plantations are renewed, these plants are discarded, making studies on the reuse of this material necessary. Thus, the objective of this study was to perform biometry of cellular elements and to investigate the papermaking potential of the fibers of these two species. We used the cellular element maceration technique to measure fiber and vessel element dimensions and calculated the fiber slenderness ratio, wall fraction, coefficient of flexibility and the Runkel index. According to the classification literature, the fibers of these species were of medium size, and there was a significant difference in wall thickness, with cupuacu fibers being thicker. The values of the fiber slenderness ratio and the coefficient of flexibility were higher in cocoa, while those of wall fraction and the Runkel index were higher in cupuacu. To conclude, the fibers of both species have papermaking potential. However, the paper manufactured with these fibers should be tested to confirm the results of this study.

This article reviews publications with the goal of understanding the role of hydrophobic copolymers added to size-press starch as a means to make paper products more resistant to penetration by aqueous fluids. The underlying technology is considered, including background related to starch, size-press equipment, and various hydrophobic copolymers and latex products that have been evaluated. The resulting hydrophobization of the paper has been reported to depend not only on the dosage of the hydrophobic additive, but also on its molecular mass and ionic form. The mechanism appears to rely on an ability of starch to serve as a temporary host for hydrophobic compounds in aqueous solution. It has been proposed that hydrophobic copolymers added with size press starch tend to migrate to the air interface during drying of the starch film, thus allowing the low-energy functional groups, such as styrene or alkyl chains, to face outwards. Further research is needed to address various mechanistic questions. There may be opportunities to further raise the performance of this type of technology as practiced within paper production factories.

In this work, we prepared novel cellulosic paper by incorporating tannin into the kraft pulp for potential application in active food packaging. The kraft pulp fibers were firstly periodate oxidized to obtain the dialdehyde cellulosic fibers, and then reacted with varied dosages of tannin to incorporate them into the fibers by covalent bondings between aldehyde groups on cellulose and active hydrogen on tannin. Handsheets were prepared using the tannin incorporated fibers through papermaking process and the properties were characterized. The percentage of tannin in the paper increased with the increase of the tannin dosage. FT-IR spectra confirmed the successful incorporation of tannin into the cellulosic fibers. It was found that paper after incorporation of tannin turned to be surface hydrophobic with contact angles higher than 90°, which may probably due to the covalent bonds between tannin and cellulose. The handsheets show high antioxidative and UV-shielding properties, which both increased with the increase of the tannin percentage in the paper. Water vapor transmission rate (WVTR) decreased after the incorporation of tannin, and this could facilitate its application in food packaging. The breaking length of tannin incorporated paper decreased insignificantly, less than 10% with the tannin percentage as high as 45%.

Starch and derivatives thereof have proven their usefulness in paper coating processes. Among these derivatives, cationic starch has been widely used in the paper industry as a flocculation, dispersion and ink fixing agent. In another context, nanoscale cellulosic materials have been shown to improve the strength, retention of fillers, the barrier properties of packaging paper products, and printing qualities. This review summarizes the recent studies on the general components used in paper coating, describes the conventional and alternative synthetic processes of cationic starches and nanocellulose, and deals with their current and potential applications in papermaking, focusing primarily on surface treatments. Moreover, environmental applications have been considered to expand the understanding and usefulness of these materials. Further research on modified polysaccharides is encouraged to replace, in a feasible way, petro-based components of coating formulations, and to provide paper surfaces with new properties.

The potential use of coir fiber for pulping and papermaking has been investigated. This research aimed to study effects of pulping processing variables (temperature, pulping time, and alkali charge/solvent pulping) on the properties of pulp (residual lignin, alpha cellulose, kappa number and pulp yield) from coir fiber. For this purpose, the coir fibers were cooked using alkali charge (10 to 20% oven dried, as NaOH), pulping time from 60 to 120 min and temperature from 65 to 180oC. Results indicated that alkali charge and pulping time gave more impact on the properties of pulp than temperature. Pulping at high temperature, long pulping time, and high alkali charge resulted in decreasing of lignin, pulp yield, and kappa number but instead on alpha cellulose content. Keywords: coir, soda pulping, lignin

Eco-friendly and cost-effective materials and processes to manufacture functional substrates are crucial to further advance the area of printed electronics. One potential key component in the printed electronics platform is an electrically functionalized paper, produced by simply mixing common cellulosic pulp fibers with high-performance electroactive materials. Herein, an electronic paper including nanographite has been prepared using a standardized and scalable papermaking technique. No retention aid was needed to achieve a conducting nanographite loading as high as 50 wt %. The spontaneous retention that provides the integrity and stability of the nanographite paper, likely originates partially from an observed water-stable adhesion of nanographite flakes onto the fiber surfaces. The resulting paper exhibits excellent electrical characteristics, such as an in-plane conductivity of 107 S/cm and an areal capacitance of 9.2 mF/cm(2), and was explored as the back-electrode in printed electrochromic displays. Funding Agencies|Digital Cellulose Centre, a competence center set up by the Swedish Innovation Agency VINNOVA; consortium of Swedish forest industries; Wallenberg Wood Science Center (Knut and Alice Wallenberg Foundation); VINNOVA "EPIC" projectVinnova [2017-05413]; Karl-Erik Onnesjo Foundation