1. Report of the CCQM-K123: trace elements in biodiesel fuel
- Author
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J Murby, Tom Oduor Okumu, Sutthinun Taebunpakul, Ian White, Wai-hong Fung, Mónica B Borinsky, N Tokman, J A S Télle, Mabel Puelles, Takayoshi Kuroiwa, S J Christopher, Marcelo Dominguez de Almeida, Nattikarn Kaewkhomdee, Jochen Vogl, H P Yau, Kazumi Inagaki, E Z Campos, Yanbei Zhu, Murat Tunç, Rodrigo Caciano de Sena, Jeffrey Merrick, E C Galv́n, Charun Yafa, U Thiengmanee, Pranee Phukphatthanachai, David Saxby, Stephen E. Long, Nadia Hatamleh, J N Kang'iri, and Süleyman Zühtü Can
- Subjects
Acid digestion ,Measurement method ,Biodiesel ,010405 organic chemistry ,010401 analytical chemistry ,Radiochemistry ,General Engineering ,Isotope dilution ,01 natural sciences ,0104 chemical sciences ,Reference measurement ,Environmental science ,NIST ,Optical emission spectrometry - Abstract
The CCQM-K123 key comparison was organized by the Inorganic Analysis Working Group (IAWG) of CCQM to assess and document the capabilities of the national metrology institutes (NMIs) or the designated institutes (DIs) to measure the mass fractions of sodium, calcium, potassium, magnesium phosphorous and sulfur in biodiesel fuel (BDF). The National Metrology Institute of Japan (NMIJ) and National Institute of Standards and Technology (NIST) acted as the coordinating laboratories. Results were submitted by 11 NMIs and DIs. The participants used different measurement methods, though most of them used inductively coupled plasma-mass spectrometry (ICP-MS), isotope dilution technique with ICP-MS and inductively coupled plasma-optical emission spectrometry (ICP-OES) with microwave acid digestion. The material was quite challenging and a number of questions were raised at the IAWG meeting. Concerning S, the variation in S results between participants, particularly those using IDMS methods was discussed at the IAWG meeting. BAM, NIST and NMIJ reviewed their experimental conditions, results and/or uncertainty calculations for IDMS. According to the additional evaluation and investigation, the variances between the revised results became smaller than the original one, the revised results were overlapping between IDMS measurements of S content at the k=2 level. It is not possible to calculate a KCRV with values being modified after submission. It was concluded that this KC does not support S measurements. Accounting for relative expanded uncertainty, comparability of measurement results for each of Na, Ca, K, Mg and P was successfully demonstrated by the participating NMIs or DIs. It is expected that sodium, calcium, potassium, magnesium and phosphorus at mass fractions greater than approximately 0.1 mg/kg, 0.1 mg/kg, 0.05 mg/kg, 0.05 mg/kg and 0.1 mg/kg respectively in biodiesel fuel and similar matrices (fuels and oils etc.) can be determined by each participant using the same technique(s) employed for this key comparison to achieve similar uncertainties mentioned in the present report. Furthermore, the results of this key comparison can be utilized along with the IAWG core capability approach.
- Published
- 2017
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