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Soil organic carbon (SOC), total nitrogen (TN), and total phosphorus (TP) play a vital in plant growth, and their stoichiometric ratios (RCN, RCP, RNP, and RCNP) are important indicators of the elemental balance in the soil ecosystem. However, the effects of land-use change (from natural forest to high-intensity orchards) on dynamics of SOC, TN, TP, and their stoichiometric ratios along the deep soil profile remain poorly understood, especially in the red soil of Southeast China. Therefore, in the present study, we selected the high-intensity managed pomelo orchard systems (7-year-old and 20-year-old) of Pinghe County developed from the natural forest and investigated their soil nutrients distribution and stoichiometric ratios at a depth of 0–200 cm. We found that conversion of natural forest into highly managed pomelo orchard systems effectively increased the SOC (5.01 to 9.05%), TN (98.80 to 126.79%), and TP (507.50 to 1914.65%) contents in the depth of 0–20 cm. On the contrary, in this same depth, RCP and RNP consistently decreased with increasing planting years, while no significant differences were found in RCN between 7-year-old and 20-year-old pomelo orchards. Nonetheless, planting year affected the SOC, TN, RCN, and RCP in the deep soil at 0–200 cm, while TP and RNP at 0–80-cm soil depth. These findings strengthen our understanding of soil nutrients and stoichiometry changes as a result of land-use change and could also provide a vital resource for the evaluation of different land uses.

Benggang is one of the most serious soil erosion problems in tropical and subtropical areas in southern China. Little work has been reported on the surface properties of soil colloidal particle and its influence on soil swelling of different soil layers in collapsing wall of Benggang. In this present work, the effects of sodium concentration on soil swelling, and the correlations between soil swelling rates and soil colloidal surface properties were comprehensively evaluated by carefully examining soil physicochemical properties and soil colloidal surface properties of red, sandy and detritus soil layers from a collapsing wall. Our results showed that the soil swelling rates of red, sandy and detritus soil layers all exponentially decreased with increasing initial water contents. The relationship between soil swelling rate and the thickness of shear plane showed an extremely significant negative correlation for red soil layer and no correlation for sandy and detritus soil layers. Moreover, the elevating sodium concentrations reduced the thickness of shear plane from 39.69 to 0.76 nm for red soil layer, followed from 22.56 to 0.79 nm for sandy soil layer and from 18.61 to 0.64 nm for detritus soil layer. These findings indicated that the soil particle interactions played a crucial role in the development and occurrence of Benggang. This work will be helpful in understanding the mechanisms of soil mass loss on the gully head and collapsing wall of Benggang.

Collapsing gully erosion is a specific form of soil erosion that is widely distributed in the hilly granitic region of tropical and subtropical southern China and resulted in extremely rapid water and soil loss. The aim of this study was to investigate the correlations between soil physicochemical and shear properties and the clay mineralogical of different profiles of the non-eroded soils (without soil erosion) and collapsing gully soils in Changting County, Fujian Province, southeastern China. A total of 32 sampling soils collected from four pedons of non-eroded and collapsing gully soils were subjected to conventional soil analyses for physicochemical properties. The soil shear strength of collected soils was measured using a triaxial shear apparatus according to the unconsolidated-undrained (UU) method. The clay mineralogical of different profiles soils was examined with an X-ray diffraction (XRD) analysis. The results showed that non-eroded soils had superior physicochemical characteristics. The cohesive force of the non-eroded soils was generally greater than that of collapsing gully soils. The XRD patterns of the clay fraction indicated that kaolinite, illite, hydroxy-interlayered vermiculite (HIV), and gibbsite were the dominant clay minerals in the studied soils. Pearson’s correlation analysis showed that the cohesive force of the studied soils had significant and positive correlations with CEC, exchangeable Al3+ + H+, Fed, Ald, and Fet; the correlation coefficients (R value) for cohesive force were greater than those of internal friction angle. The stepwise multiple linear regression analyses indicated that exchangeable Al3+ + H+ and Ald were the dominant factors affecting cohesive force. Compared with collapsing gully soils, non-eroded soils had superior physicochemical and shear properties, indicating that non-eroded soils were better able to resist soil erosion. The findings obtained in the present study were of fundamental significance in understanding the correlation between shear strength and the soil physicochemical properties in the non-eroded soils and collapsing gully soils of tropical and subtropical China.

This study aimed to investigate the mechanism of lead (Pb) immobilization by hydroxyapatite (HAP) in a soil-rice system, a pot experiment was conducted using Pb-contaminated soil amended with various rates of HAP and planted with rice (Oryza sativa L.). The Pb species in the soil and rice roots were determined using Pb L3-edge X-ray absorption near edge structure (XANES). Application of HAP increased soil pH and induced the dissolution of phosphate, subsequently promoting the formation of chloropyromorphite, an insoluble Pb species, in the soil. Therefore, the acid soluble and DTPA-extractable Pb concentrations decreased significantly with increasing levels of applied HAP. HAP reduced the retention of Pb in the iron plaque on the root surface at maturity, thereby alleviating Pb uptake by rice roots. The amount of phosphate in roots were increased with increasing rate of application of HAP, but was negatively correlated with Pb in rice stems and leaves. Application of 32 g kg−1 of HAP triggered the precipitation of Pb5PO4Cl in roots, limiting Pb translocation from roots to shoots. In addition, HAP may induce the redistribution of Pb in rice nodes, lowering the transfer factor of Pb from the stem (or leaf) to rice grains. When the rate of application of HAP exceeds 4 g kg−1, the Pb concentration in brown rice could be reduced to less than the Chinese National Standard of 0.2 mg kg−1 (GB2762-2017).

General acid washing is commonly used to treat heavy metal-contaminated soils, but it is sometimes difficult to achieve remediation aims in severely polluted soils. If we expose the surfaces of Fe oxide minerals to reductive dissolution during washing treatment, more of the metals initially adsorbed to these surfaces will be liberated, which may encourage the removal of heavy metals. Initially, the metal extraction capabilities of nine chemical reductants were compared in ten soil samples polluted by Cr, Cu, Zn, and Ni. Sodium dithionite (Na2S2O4) and ferrous sulfate (FeSO4) were screened for subsequent intensive research. In summary, the Na2S2O4 solutions had higher Cr, Cu, and Zn removal rates than either the FeSO4 or acid solution. Application of dissolved organic carbon (DOC) further increased the removal of heavy metals by complexation. About 15%, 86%, 32%, and 52% of the Cr, Cu, Zn, and Ni, respectively, were removed from the representative soil (M-2) by two-stage washing using 0.2 M Na2S2O4 coupled with 1,500 mg L−1 DOC solution at pH 2.0. Meanwhile, most soil fertility was preserved: ammonium nitrogen was increased 3.9 times; the increase in exchangeable potassium was 33%; and the reduction in available P was only 10%.

Understanding rill erosion processes is important in the prediction of soil erosion and the prevention of soil loss. However, limited information is available concerning the impacts of rainfall on rill erosion on steep slopes. Colluvial deposits with steep slopes make up the packed material underlying the collapsing walls in benggang, which collapse due to hydraulic pressure and gravity. They contain loose materials and large amounts of coarse particles. The objectives of this study were to investigate the impacts of rainfall intensity and slope gradient on the rill erosion process, rill development and rill flow dynamic mechanisms on the steep slopes of colluvial deposits. The colluvial soils were subjected to simulated rainfall in a 5-m2 (5-m by 1-m) flume at heavy rainfall intensities (100, 120, and 140 mm h−1) and on five steep slopes (20, 25, 30, 35, and 40°). Rill erosion contributed significantly to colluvial slope erosion; on average, rills accounted for 61% of the soil loss, and the effects of slope gradient were greater than those of the rainfall intensity. After rill development, rill density, rill length, width, and depth all significantly increased. Correspondingly, the soil loss rate sharply raised and irregularly fluctuated. Moreover, the collapse of rill heads or sidewalls tended to increase the relative contribution to rill erosion and rill development. The rill flow was characterized by transitional and subcritical flow regimes. The rill flow velocity was the most sensitive hydraulic parameter, and the unit stream power provided the optimal hydrodynamic parameter to characterize the dynamic mechanisms of rill erosion on colluvial deposits. The collapse of rill heads or sidewalls could result in negative values for critical shear stress, critical stream power, and critical unit stream power of rill erosion, which were −19 Pa, −5.3 N m−1 s−1, and −0.09 m s−1, respectively. These results provide a better understanding of the mechanism of rill erosion on steep slopes.

This study focused on the effects and mechanisms of biochar amendment to Cd-contaminated soil on the uptake and translocation of Cd by rice under flooding conditions. Pot and batch experiments were conducted using Cd-contaminated soil collected from a field near an ore mining area and a cultivar of Oryza sativa ssp. indica. Biochar derived from rice straw under anaerobic conditions at 500 °C for 2 h was mixed with the soil at the rate of 0, 2.5, and 5%. The application of 5% biochar reduced CaCl2-extractable soil Cd by 34% but increased Cd concentration in brown rice by 451%. Biochar amendment decreased water-soluble Fe2+ in soils and formation of Fe plaques on roots and weakened the Fe2+-Cd2+ competition at adsorption sites on the root surface. Biochar increased water-soluble Cd in the soil and consequently Cd uptake by rice roots by releasing water-soluble Cl−. Biochar application also reduced the proportion of cell wall-bound Cd in the root, which caused easier Cd translocation from the cortex to the stele in the root and up to the shoot. Rice straw biochar (with high concentration of water-soluble Cl−) reduced CaCl2-extractable soil Cd but increased Cd concentration in rice under flooding condition.

Clay minerals significantly affect the physical, chemical, and biological processes of soils. They undergo spontaneous modification and transformation depending to the climatic conditions. Information concerning the compositions and transformation of clay minerals in nanoparticle colloids (NPs) (25–100 nm) is severely lacking. Studying clay mineral transformation is important approach to understand soil formation. This study was conducted to determine the transformation sequence of clay minerals in several zonal soil NPs. Four soils (Haplustalf, Alf-1; Hapludalf, Alf-2; Hapludults, Ult-1 and Ult-2) were collected from B horizons developed under three different climatic zones of China. Alf-1 (36° 05′ N and 117° 24′ E) was located under a warm temperate zone and Alf-2 (30° 38′ N and 115° 26′ E), Ult-1 (29° 13′ N and 113° 46′ E), and Ult-2 (19° 27′ N and 109° 17′ E) under a subtropical zone. The clay particles (

This study aimed to compare soil physicochemical properties and mineralogical compositions, including the cohesive force and internal friction angle, using direct shear tests with designed water contents and temperatures, between noncollapsible soil and collapsed gullies. Two pedons were collected from Longmen Town (Anxi County, Fujian Province) with severely collapsed gullies that developed from granitic rocks, and another two pedons were collected from metamorphic regions (Gande Town) without soil erosion. The samples were subjected to X-ray diffraction (XRD) analysis, and their soil physicochemical properties were compared. Noncollapsible soils had superior physicochemical characteristics, e.g., these soils contained higher amounts of cations, especially total iron oxides (Fet). Furthermore noncollapsible soils were able to resist shearing due to their greater cohesive force, and the internal friction angle did not differ considerably from that of the collapsed soils. Kaolinite, illite, hydroxy-interlayered vermiculite (HIV) and gibbsite were the dominant clay minerals in the noncollapsible soils. However, in the collapsed soils, kaolinite accounted for > 85% of the total clay mineral composition. The cohesive force and internal friction angle were significantly correlated with sesquioxides of all non-collapsible and collapsed pedons, such as Fed (free Fe-oxides, 0.762**, 0.637**) and total iron (Fet, 0.783**, 0.708**), as well as magnetic susceptibility (0.650**, 0.740**) (P

Inappropriate treatments for the effluents from semiconductor plants might cause the releases and wide distributions of selenium (Se) into the ecosystems. In this study, Al/Si and Fe/Si coprecipitates were selected as model adsorbents as they often formed during the wastewater coagulation process, and the removal efficiency of selenite (SeO3) and selenate (SeO4) onto the coprecipitates were systematically examined. The removal efficiency of SeO3 and SeO4 was highly related to surface properties of Al/Si and Fe/Si coprecipitates. The surface-attached Al shell of Al/Si coprecipitates shielded a portion of negative charges from the core SiO2, resulting in a higher point of zero charge than that of Fe/Si coprecipitates. Thus, adsorption of SeO3/SeO4 was favorable on the Al/Si coprecipitates. Adsorptions of both SeO3 and SeO4 on Al/Si coprecipitates were exothermic reactions. On Fe/Si coprecipitates, while SeO3 adsorption also showed the exothermic behavior, SeO4 adsorption occurred as an endothermic reaction. The kinetic adsorption data of SeO3/SeO4 on Al/Si and Fe/Si coprecipitates were described well by the pseudo-second-order kinetic model. SeO4 and SeO3 adsorption on Fe/Si or Al/Si were greatly inhibited by the strong PO4 ligand, whereas the weak ligand such as SO4 only significantly affected SeO4 adsorption. The weakest complex between SeO4 and Al was implied by the essentially SeO4 desorption as SeO4/PO4 molar ratios decreased from 0.5 to 0.2. These results were further confirmed by the less SeO4 desorption (41%) from Fe/Si coprecipitates than that from Al/Si coprecipitates (78%) while PO4 was added sequentially.

Mulching is an effective soil conservation practice for permanent gullies in southern China. Knowledge of the sediment characteristics that occur in mulched soils of colluvial deposits could improve the utility of mulching for soil conservation. A rainfall simulation experiment was designed to evaluate the effects of mulch on the runoff, erosion, and particle size distribution of eroded sediments. Straw mulch coverage of 0, 25, 50, 75, and 95% was tested with simulated rainfall. The effective particle size distribution of the sediment was compared with the ultimate particle size distribution to investigate the detachment and transport mechanisms involved in sediment mobilization. Mulching delayed the runoff initiation time and reduced the average runoff rate. Compared with bare soil, the increased mulch coverage decreased the soil loss rate by 13.0 to 90.3%. Moreover, the peak sediment concentration decreased from 80 to 200 g L− 1 under the different mulch coverage conditions. The optimal straw application rate was 1.5 to 3.0 Mg ha− 1 in the permanent gully's deposits. The relationship between instantaneous kinetic energy of rainfall and the proportion of effective clay- and sand-sized particles was well represented using an exponential equation. The effective clay-sized sediments under the different mulch coverage conditions were 2 to 4 times more common than those of the original soil, although there were only 13.9% sand-sized particles in the sediment when the mulch coverage was 95%. The silt-sized sediment was transported as primary particles under the different mulch coverage conditions. The effective to ultimate ratio of silt-sized particles fluctuated around 1. There were depletions of clay and silt in the colluvial deposit soil with mulch cover, and the enrichment ratios of clay and silt were larger than 1 while most of the enrichment ratios for sand were

Information on phosphorus (P) adsorption and its impacts on the redistribution of the P fraction in soil profiles are important for environmental management under intensive agricultural practices. To clarify the dominant factors influencing soil phosphorus adsorption in an Entisol (locally known as purple soil), P adsorption experiments were conducted in Sichuan Basin of southwestern China for cropland and woodland soils with acidic, neutral and calcareous origins throughout their profile. After various doses of P were added during incubation experiments, soil P fractions were also analyzed. The results showed that there were no significant differences in Fe-oxides and P adsorption along the vertical gradients. Agricultural practices and lower pH conditions reduced the P adsorption capacity of purple soils throughout the soil profiles. For acidic and neutral purple soil profiles, the P adsorption capability was mainly influenced by Fe-oxides and soil texture. Ca-bound P and Fe-Al-bound P represented the majority of the total inorganic P of calcareous soils. There was a saturation of adsorption capacity by sesquioxide and a high risk of dissoluble reactive P (NH4Cl-P) being released out of the soil profile in acidic and neutral purple soils after the greatest P addition, indicated by the higher proportions of NH4Cl-P (over 40%) and decreasing Fe-Al-P fraction. P fractions migrated with greater difficulty in calcareous purple soil profiles as Ca-P fraction peaked over 65% when adding a P dose at or greater than 80 g P kg-1, indicating the high potential of P adsorption. The X-Ray Diffraction analysis also verified the formation of brushite. Adaptive management practices should be designed to alleviate P losses for acidic and neutral purple soils.

Colluvial deposits with loose, coarse material are easily erodible in permanent gullies, but the mechanisms of erosion and sedimentation during overland flow remain obscure. Hence, the processes and mechanisms of the transportation of soil particles by overland flow were investigated in this study. Experiments were carried out in a 5.0 m long by 1.0 m wide flume using colluvial deposits. The slope gradient varied from 36 to 84%, and the flow rate ranged from 0.72 L m − 2 min − 1 to 2.88 L m − 2 min − 1 . The runoff rate and sediment yield rapidly increased with increasing overland duration. Runoff and sediment were highly variable when the flume was treated with a high flow rate compared with a low flow rate, with the fluctuation of sediment concentration under the high flow rate usually reaching 500 g L − 1 . The slope gradient and overland flow rate have strong impacts on sediment transport capacity. The mean flow velocity and the unit stream power can be an optimal composite force predictor for estimating sediment transport capacity. Experimental results also revealed that the percentage of gravel-sized particles increased with increasing flow rate and slope gradient, but silt and clay fractions observed opposite trend. The average enrichment ratio (ER) of gravel was usually 2.16 L m − 2 min − 1 , the bed load transport became an important mechanism; however, the simulation model overestimated these values.

Past studies have shown that dissolved organic carbon (DOC) washing can effectively remove heavy metals from contaminated soil. In this study, we used alkaline DOC solutions for remediation of arse...

A Gram-stain-positive, rod-shaped, endospore-forming, aerobic bacterium, designated strain FJAT-25547T, was isolated from the purplish paddy soil collected from Linshan Township, Yanting Prefecture of Sichuan Province in PR China (31° 16′ N 105° 27′ E). Growth was achieved aerobically at temperatures between 15 and 40 °C (optimum 30 °C), with between 0 and 10.0 % NaCl (w/v) (optimum 4 %) and in the range of pH 5.0–12.0 (optimum pH 9.0). The cell-wall peptidoglycan contained meso-diaminopimelic acid, and the main isoprenoid quinone was MK-7. The major fatty acids were iso-C15 : 0 (55.4 %), anteiso-C15 : 0 (22.2 %), iso-C16 : 0 (5.1 %) and iso-C14 : 0 (6.5 %). The main polar lipids were diphosphatidylglycerol, phosphatidylglycerol and phosphatidylethanolamine. Phylogenetic analyses based on 16S rRNA gene sequences showed that strain FJAT-25547T was a member of the genus Bacillus and was most closely related to Bacillus horneckiae DSM 23495T (97.7 % similarity), Bacillus eiseniae A1-2T (97.5 %), Bacillus mesophilum IITR-54T (97.2 %) and Bacillus kochii WCC 4582T (97.0 %). The average nucleotide identity value between strain FJAT-25547T and the type strain of the most closely related species, B. horneckiae DSM 23495T, was 77.7 %, less than the proposed cut-off value of 96.0 % for differentiating species within the genus. The in silico DNA–DNA hybridization value of strain FJAT-25547T with the most closely related species was 22.7 %

Soil aggregates consist of sand, silt, and clay size particles. Many of the clay size particles in soils are clay minerals, which actively influence soil behavior. The properties of clay minerals may change significantly as soil particle size decreases to the nanoscale; however, little information is available about these properties for the Ultisols in China. In the present study, the clay mineral components and structural characteristics of four particle-size fractions (i.e.

The objectives of this research were to study the effects of Na2SiO3 application on the uptake, translocation, and accumulation of Pb in rice and to investigate the mechanisms of Pb immobilization by Na2SiO3 in paddy rice soils and rice plants. Pot experiments were conducted using a Cd-Pb-Zn-polluted soil and Oryza sativa L. ssp. indica cv. Donglian 5. L3-edge X-ray absorption spectroscopy was used to identify Pb species in soils and roots. The results showed that the application of Na2SiO3 increased soil pH and available soil Si but decreased DTPA-extractable Pb in the soil. High dose of Na2SiO3 (12.5 g/kg) reduced the Pb level in brown rice as it inhibited Pb transfer from soil to rice grains, especially Pb transfer from the root to the stem. The Pb X-ray absorption near-edge spectroscopic analysis revealed that application of high dose of Na2SiO3 increased Pb-ferrihydrite and PbSiO3 precipitates in the soil and in the root while it reduced Pb-humic acids (Pb-HAs) in the soil and Pb-pectin in the root. The decrease in Pb availability in the soil can be partly attributed to increase the precipitation of PbSiO3 and the association of Pb2+ with Fe oxides in the soil. The inhibition of the root-to-stem translocation of Pb was partially due to the precipitation of PbSiO3 on the root surfaces or inside the roots.

In pursuit of highyield, blind application of a large number of nitrogen fertilizer in tea plantation has not only seriously affected the quality of tea, but also resulted in environmental degradat...

Phosphorus recovery in the form of struvite has been aroused in recent decades for its dual advantages in eutrophication control and resource protection. The usage of the struvite products is normally determined by the size which is largely depended on the hydrodynamics. In this study, flow behavior of struvite pellets was simulated by means of Eulerian-Eulerian two-fluid model combining with kinetic theory of granular flow in a liquid-solid fluidized bed reactor (FBR). A parametric study including the mesh size, time step, discretization strategy, turbulent model and drag model was first developed, followed by the evaluations of crucial operational conditions, particle characteristics and reactor shapes. The results showed that a cold model with the mesh resolution of 16×240, default time step of 0.001sec and first order discretization scheme was accurate enough to describe the fluidization. The struvite holdup profile using Syamlal-O'Brien drag model was best fitted to the experimental data as compared with other drag models and the empirical Richardson-Zaki equation. Regarding the model evaluation, it showed that liquid velocity and particle size played important roles on both solid holdups and velocities. The reactor diameter only influenced the solid velocity while the static bed height almost took no effect. These results are direct and can be applied to guide the operation and process control of the struvite fluidization. Moreover, the model parameters can also be used as the basic settings in further crystallization simulations.

Increasing temperature and nitrogen (N) deposition are major drivers of global change that will influence plant-soil systems. We aimed to understand how plant stoichiometry and nutrient limiting types could change with continued warming and N inputs in subtropical regions. In 2014, the experiments were established in 30 mini-plots (2 × 2 m) with the following treatments: control, high N addition, low N addition, warming, warming + high N addition, and warming + low N addition. We sampled the leaf and root of Cunninghamia lanceolata and soils to assess their elemental and stoichiometric variables and δ15N under all six conditions. Both experimental warming and N fertilization consistently induced an increase in fine-root N, P, and N:P. The N:P ratio of the mature green-leaf and soil was 7.24–11.63 and 4.79–6.56, respectively. On average, C. lanceolata showed higher proportional P resorption, but lower N resorption. The δ15N enrichment factor significantly increased in the warming and N addition treatments. N addition decrease leaf N content, and increased the plant growth, which was due to the effect of the N dilution of C. lanceolata. In subtropical regions, N-limitation affects the growth of C. lanceolata, and the concurrent increase in warming and N fertilization should help relieve N-limiting conditions.

The suitability of an agent for washing heavy metal contaminated soils depends not only on the efficiency of heavy metal removal but also on the persistence of the washing effect, especially for agricultural soil. Redistribution of residual heavy metals in washed soil from inert pools to labile pools can reverse the initial washing effect. In order to study the redistribution of residual Pb in Pb-contaminated soils washed with citric acid (CA), ethylenediaminetetraacetic acid (EDTA), FeCl3, and HCl solutions, washed soils were incubated under both flood and 70% field water capacity (FWC) conditions for 180 days. The Pb availability in CA-, EDTA-, FeCl3-, and HCl-washed soils varied with incubation time. Diethylenetriaminepentaacetic acid (DTPA)-Pb generally increased with incubation time, except in CA-washed soil under flood incubation condition. Pb associated with the exchangeable/acid extractable fraction (F1) increased, whereas Pb in the easily reducible fraction (F2) decreased over time, for all washed soils under flood incubation condition; the changes in the amount of Pb associated with each fraction were much smaller under 70% FWC incubation. The transformation of Pb from F2 to F1 during flood incubation was largely caused by the mobilization of Fe and Mn oxides. The mobility factors (MF) of Pb for samples under flood incubation increased with increasing incubation time while those for samples under 70% FWC incubation changed only slightly, which implies increasing environmental risks of Pb from washed soils that are flooded. Therefore, the redistribution and potential environmental risks posed by heavy metals in washed soils, especially in paddy rice soils, should be taken into account when the suitability of a washing agent is evaluated. In the present study, CA was found to be unsuitable for washing Pb-contaminated agricultural soil, whereas the FeCl3 solution was the most stable washing agent tested, as it had high removal efficiency and low release of Pb after washing.

Mainly located in the Sichuan Basin, known as the ‘Land of Plenty’, purple soils (developed from purple sandstone and shale) have been long noted as highly productive in spite of their rocky texture. However, information on the physicochemical properties (including mineral properties) of purple soils remained obscure for the scientific community. For example, it is not clear what causes the purple color of the soils. In this study, eight soil profiles of the Jiufeng (JF, acidic), Shibao (SB, neutral), and Yanting (YT, calcareous) areas, representing the three most widely distributed purple soils in Sichuan Basin, were individually sampled under both cropland and forestland, and then analyzed using common chemical analysis and conventional X-ray diffraction to clarify the effects of clay mineral and anthropogenic influences on the typical soils. The results show that considerable variability of soil pH and cation-exchange capacity (CEC) exists between soil types (p

Fluidized bed reactor (FBR) has been applied in phosphorus recovery from wastewater due to its ability on producing struvite pellets with large size, high crushing strength and purity. However, the fine struvite crystals (fines) can be flushed out of the reactor, which may result in undesirable and variable phosphorus recovery efficiencies. In this study, the influences of key factors with respect to phosphorus recovery and product quality in a FBR were investigated for the treatment of swine wastewater. The effects of process parameters were first evaluated using response surface methodology (RSM), and later, long-term pilot-scale operations were tested. Results showed that fines retention was directly related to the in-reactor saturation index (SI) and upflow velocity (vup). Decreasing SI (from 2.42 to 1.65) or vup (from 75 to 25 mm s− 1) will reduce the fines entrainment and improve the phosphorus recovery profile by 14.9 and 18.5%, respectively. Moreover, these two factors governed the quality of the struvite pellets in the pilot-scale investigations—SI showed more crucial effect to size distribution, crushing strength and morphology than vup. As to the composition, struvite (35.5–95.3% of mass fraction) and CaCO3 (2.8 to 51.4% of mass fraction) were the two major components in the pellets. Decreasing SI or increasing vup and pellet size can enhance the struvite purity. Therefore, phosphorus recovery and pellet quality can be simultaneously improved by SI and vup control without additional trapping devices or reagents. The finding is constructive for FBR system set-up and operation in either pilot- or full-scale applications, where different phosphorus recovery rates and product qualities are required.

The composition, structure and transformation characteristics of clay minerals in various size particles ( 100 nm) were an important mineral source of nanoparticles, and the 1:1 clay minerals were mainly inherited from the minerals in larger particles and transformed from 2:1 clay minerals into nanoparticles.

The sediment transport capacity (Tc) is an important parameter for analysing and controlling soil erosion processes. However, few studies have investigated the Tc of soils containing gravel (grain sizes of >2 mm) on steep slopes. Colluvial deposits on steep slopes in benggang are composed of loose materials with large amounts of gravel. This study aimed to investigate the effects of gravel content on the Tc of overland flow using colluvial deposits with a range of slope gradients and flow discharges in a nonerodible flume (4 m long, 0.12 m wide and 0.1 m high). The experiments were carried out using six gravel mass contents (0, 10, 20, 30, 40, and 50%), four slope gradients (18, 36, 57, and 84%), and four flow discharges (0. 56, 1.11, 2.22, and 4.44 × 10-3 m2 s−1). The experimental results revealed that the measured Tc increased linearly as the gravel content increased. The effects of the slope gradient, flow discharge and gravel content on Tc were significant (p

Hydrotalcite (HT) is a layered double hydroxide (LDH), which is considered as a potential adsorbent to remove anion contaminants. In this study, adsorption of chromate (CrO4) and phosphate (PO4) on HT was conducted at various pH and temperatures. Related adsorption mechanisms were determined via the isotherm, kinetic, and competitive adsorption studies as well as the Cr K-edge X-ray absorption fine-structure (XAFS) spectroscopy. The maximum adsorption capacities for CrO4 and PO4 on HT were 0.16 and 0.23 mmol g−1. Regarding adsorption kinetics, CrO4 and PO4 adsorption on HT could be well described by the second order model, and the rate coefficient of CrO4 and PO4 on HT decreased significantly with the increasing pH from 5 to 9. The adsorption kinetics for CrO4 and PO4 were divided into fast and slow stages with the boundary at 15 min. This biphasic adsorption behavior might be partially attributed to multiple reactive pathways including anion exchange and surface complexation. Fitting results of Cr K-edge EXAFS analysis showed a direct bonding between CrO4 and Al on HT surfaces. Such a surface complexation appeared to be the rate-limiting step for CrO4 adsorption on HT. By contrast, the diffusion through the hydrated interlayer space of HT was the major rate-limiting step for PO4. This study determined the adsorption behaviors of CrO4 and PO4 on HT, including the initial transfer process and the subsequent adsorption mechanisms. Such information could improve the strategy to use HT as the potential adsorbent for the remediation of anionic pollutants.

A Gram-stain-positive, rod-shaped, endospore-forming, aerobic bacterium (FJAT-14571T) was isolated from a soil sample in Taiwan. Strain FJAT-14571T grew at 20–40 °C (optimum 35 °C), pH 6–10 (optimum pH 8) and 0–2 % (w/v) NaCl (optimum 0 %). Phylogenetic analyses based on 16S rRNA gene sequences showed that strain FJAT-14571T was a member of the genus Bacillus and was most closely related to Bacillus oceanisediminis DSM 24771T (96.2 %). DNA–DNA relatedness between strain FJAT-14571T and B. oceanisediminis DSM 24771T was low (32.0 % ± 0.88 %). The diagnostic diamino acid of the peptidoglycan of strain FJAT-14571T was meso-diaminopimelic acid and the predominant menaquinone was MK-7 (96.6 %). The major cellular fatty acids were iso-C15 : 0 (46.4 %), anteiso-C15 : 0 (7.6 %), iso-C17 : 0 (8.2 %) and iso-C16 : 0 (10.0 %) and the DNA G+C content was 40.8 mol%. Phenotypic, chemotaxonomic and genotypic properties clearly indicated that strain FJAT-14571T represents a novel species within the genus Bacillus, for which the name Bacillus taiwanensis sp. nov. is proposed. The type strain is FJAT-14571T ( = DSM 27845T = CGMCC1.1 2698T).

The effectiveness of four different washing extractants--HCl, FeCl3, citric acid, and EDTA--in removing Cd, Pb, and Zn from polluted soil was studied. The removal of these metals, their redistribution between fractions, and the potential risks posed by them, in soils washed with the tested extractants, were examined. Although all the rounds of washing removed Cd, Pb, and Zn from soil, the first round removed more metals than subsequent rounds. Each of the four extractants had different effects on the removal of the metals. At the end of the first round of washing, HCl, EDTA, and FeCl3 were the most effective in removing Zn, Pb, and Cd, respectively. Both the single round and five successive rounds of washing with various extractants resulted in significant increases in Pb in the exchangeable/acid extractable fraction. Washing with HCl, EDTA, and FeCl3 significantly reduced potential risks (calculated as the Potential Risk Index, PRI) posed by Cd in washed soil. The first round of washing, using all extractants, increased the risks posed by Pb and Zn. However, five successive rounds of washing with FeCl3 and EDTA reduced the risk posed by Pb, and washing with citric acid and FeCl3 increased the risks posed by Zn. EDTA and HCl were better for reducing Zn risks, and successive washing with EDTA and FeCl3 were more effective in reducing Pb risks than the other extractants. Finally, five successive rounds of washing, with all the extractants, effectively reduced the potential risks posed by Cd. Among the four reagents, EDTA was advised to be the alternative of the washing reagent by significantly reducing the PRI values of Cd, Pb, and Zn.

Removal of arsenic (As) from water supplies is needed to reduce As exposure through drinking water and food consumption in many regions of the world. Magnetite nanoparticles (MNPs) are promising and novel adsorbents for As removal because of their great adsorption capacity for As and easy separation. This study aimed to investigate the adsorption mechanism of arsenate, As(V), and arsenite, As(III), on MNPs by macroscopic adsorption experiments in combination with thermodynamic calculation and microspectroscopic characterization using synchrotron-radiation-based X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS). Adsorption reactions are favorable endothermic processes as evidenced by increased adsorption with increasing temperatures, and high positive enthalpy change. EXAFS spectra suggested predominant formation of bidentate binuclear corner-sharing complexes ((2)C) for As(V), and tridentate hexanuclear corner-sharing ((3)C) complexes for As(III) on MNP surfaces. The macroscopic and microscopic data conclusively identified the formation of inner-sphere complexes between As and MNP surfaces. More intriguingly, XANES and XPS results revealed complex redox transformation of the adsorbed As on MNPs exposed to air: Concomitant with the oxidation of MNPs, the oxidation of As(III) and MNPs was expected, but the observed As(V) reduction was surprising because of the role played by the reactive Fe(II).

Eroded sediment is an important feature of permanent gully's development; however, obtaining the specific characteristics of the sediment transport in the gully can be difficult. Thus, a composite fingerprinting technique, incorporating uncertainty analysis, has been employed to investigate the mean relative contribution of sediment sources in permanent gullies. In this study, 31 tracers were measured at 62 different sampling sites from three layers of a gully wall [surface layer (SL), sandy soil layer (SSL), and semi-weathering rock layer (SWL)] and 36 sediment samples from the slumping deposit and alluvial fan of the gullies. The sediment source tracing procedure was therefore used to assess the relative contribution of each source. The mean relative contribution from the SL to the sediment of the slumping deposit is higher in the active gully (G1), and is relatively lower in the potentially stable (G2) and stable gullies (G3); thus there was no obvious gully bank retreat in G2 and G3. In different places of the G1 alluvial fan, the mean relative contribution of the SL, SSL and SWL ranged from 9–11, 36–43 and 46–55%, respectively. However, the sediment contribution of the SL increased in G2 and G3 due to the changes in the erosion type. The mean relative contributions of the SL were 33 ± 5 (G2) and 30 ± 3% (G3). These findings have important implications for the establishment of a scientific basis for permanent gully sediment transport management and control policies.

The relationships between the basic properties and trace elements in soil argillans and corresponding matrix soils were studied by sampling from the B horizons of 26 Alfisols in croplands of the subtropical area in Central China. The soil elements (K, Na, Ca, Mg, Mn, Co, Cu, Cr, Cd, Li, Mo, Ni, Pb, Ti, V, and Zn) were extracted by acid digestion and their contents were measured using inductively coupled plasma optical emission spectrometry (ICP-OES). The mean contents of clay and organic matter in the argillans were approximately 1.1 and 1.3 times greater than those in the matrix soils, respectively. The pH values and the contents of P2O5 and bases (K2O, Na2O, CaO, and MgO) in the argillans were higher than those in the corresponding matrix soils. Cu, Cd, Ti, and V were enriched in the argillans. Correlation coefficients and factor analyses showed that Co, Cu, Li, and Zn were bound with phyllosilicates and manganese oxides (Mn-oxides) in the argillans. Cr and Pb were mainly associated with iron oxides (Fe-oxides), while Ni was bound with Mn-oxides. Cd, Ti, and V were chiefly associated with phyllosilicates, but Cr and Mo were rarely enriched in the argillans. In contrast, in the matrix soils, Co and Zn were associated with organic matter and Fe-oxides, Cr existed in phyllosilicates, and Mo was bound to Fe-oxides. Cd, Ti, and V were associated with organic matter. The results of this study suggest that clays, organic matter, and minerals in the argillans dominate the illuviation of trace elements in Alfisols. Argillans might be the active interfaces of elemental exchange and nutrient supply in cropland soils in Central China.

Forest thinning is an important method for managing forests, changing forest structure, biological diversity and community. This study examined forest thinning effects on macrofungal diversity and the environmental factors affecting fruiting and community structure. Field surveys were conducted from 2006 to 2010 in 35-year-old Cryptomeria japonica plantations in central Taiwan. Thinning was completed in October 2007 and included control, 25% thinning, and 50% thinning treatments. Each treatment had four replications. Forest thinning and time affected macrofungal species richness observed but not abundance. Thinning influenced macrofungal community compositions; however, the difference between the two thinning intensities was not significant. The macrofungal community showed significant differences between communities of eastern and northern aspect. A redundancy analysis indicated that macrofungal communities in the C. japonica plantations were significantly affected by relative humidity, light, canopy cover, soil water content, soil temperature, soil pH value and soil texture. The fruiting of a dominant coral fungal species, Scytinopogon sp., was affected by thinning and light. The fruiting bodies of this species decreased in the 25% thinning plots and disappeared in 50% thinning plots in the first two years post-thinning, but were recorded in the third year post-thinning. After thinning, macrofungal species richness observed decreased, the community changed, and changes were associated with environmental conditions. Forest thinning decreased observable macrofungal diversity and changed the community structure, and these changes were associated with environmental variation after thinning.

Soil clays (< 2,000 nm) (SC) and soil nanoclays (< 100 nm) (SNC) were used as adsorbents for removal of Cu(II) from aqueous solution. The experiments were conducted with variables including pH, interaction time, concentration of Cu(II) and temperature. Four kinetic models have been employed to investigate adsorption mechanisms, and the experimental data more closely resemble a second-order process of the kinetic model. Adsorption studies on soil nanoclays have been shown to be highly effective in removing of Cu(II) from aqueous solution. This adsorbent is widely available as a natural material, is mechanically stable and, most importantly, it is environmentally appealing. The maximum Cu(II) adsorption capacity of soil nanoclays (31.7 mg/g) is more than three times higher than natural soil clays (10.2 mg/g). Our study demonstrates that soil nanoclays can be used effectively for removal of Cu(II) from aqueous systems to achieve environmental cleaning purposes.

Wine-processing waste sludge and alkaline substances, including KOH, NaOH, Ca(OH) 2 , and Mg(OH) 2 , were employed to prepare various dissolved organic carbon (DOC) solutions for remediating a Pb-contaminated cropland by soil washing. The Pb concentrations were 5340 and 4920 mg kg − 1 in the topsoil and subsoil, respectively. Aqueous solution treatment , general DOC treatment , and enhanced DOC treatment were proposed as treatments for the reclamation and determination of the factors affecting the removal of Pb, such as pH, initial concentration of the DOC solution, temperature, and washing frequency. The aqueous solution treatment could not remove sufficient Pb and therefore failed in the reclamation. Approximately 86.5% Pb was removed from the topsoil at pH 2.0 by the general DOC treatment undergoing two wash cycles. However, over 90% Pb was removed from the subsoil under the same conditions; only the final Pb concentration in the subsoil met the control standard, 500 mg kg − 1 . About 93% Pb in the topsoil could be removed at pH 3.0 by the enhanced DOC treatment, which was performed using a 2500 mg L − 1 DOC solution containing abundant Ca 2 + and Mg 2 + at an 80:1 liquid/soil ratio (v/v) at 40 °C for 60 min. Meanwhile, organic matter, cation exchange capacity, NH 4 + -N, as well as exchangeable K, Ca, and Mg contents increased by 125%, 22.6%, 107%, 577%, 55.3%, and 306%, respectively, and the pH in the topsoil decreased to 3.7. The use of Ca(OH) 2 and Mg(OH) 2 not only prevented washing losses of the exchangeable Ca and Mg but also increased Pb removal by 20%. However, its use decreased the availability of P in the soil.

Background Clay minerals especially organoclays modified by the introduction of organic molecules into the mineral structure show much promise for environmental remediation applications. Application of organic attapulgite (O-APG) and organic montmorillonite (O-MMT) as soil amendments to bind polychlorinated biphenyl (PCB) in contaminated soils and observe PCBs accumulated in the ryegrass shoots and roots was investigated. Results Pot experiments in greenhouse indicated that organoclays could significantly fix the PCB in soils and reduce its contents in ryegrass shoots and roots. Compared with the control, the migration of concentrations of PCB into the environment in contaminated soils is reduced by about 28.5 and 44.1%, and concentrations of PCB in ryegrass roots and shoots were reduced within the range from 57.0 to 63.0% and 49.6 to 56.5%, respectively, through addition of 6% organic attapulgite and montmorillonite. There was a negative correlation between the accumulation of PCB in ryegrass and the amount of organoclay addition. The accumulations of PCB in ryegrass roots were significantly higher than those in the ryegrass shoots. Conclusions The two organoclays had been proved effective as environmental amendments for reducing the mobility and bioavailability of PCB in contaminated soils. The results of this study provided an efficient method for the remediation of PCB contaminated soils.

The soil carbon reservoir is the largest carbon reservoir in terrestrial ecosystems and consists of soil organic and inorganic carbon stocks. Previous studies have mainly focused on the soil organic carbon (SOC) stock, and limited information is available about the soil inorganic carbon (SIC) stock. The Chinese Loess Plateau (CLP), which is located in the arid and semi-arid region of China, is an important inorganic carbon reservoir, with a thick soil layer that is rich in calcium carbonate. However, there are few reports on the SIC stock and its spatial distribution in this region. In the current study, the SIC densities and stocks for various soil types and land use patterns were evaluated based on 495 profiles with 2470 soil samples across the CLP, which were collected from the Chinese Second National Soil Survey. The results showed that in the top 1 m of soil across the CLP, the average SIC density is 17.04 kg/m(2), and the total SIC stock is approximately 10.20 Pg C (1 Pg = 10(15) g). The SIC stock of the CLP accounts for approximately 18.4% of the total SIC stock throughout China. The average values of the SIC stock in the 0-20, 20-50 and 50-100 cm depths of the CLP are 2.39, 2.92 and 4.89 Pg, respectively. Under different land use patterns, the order of the average SIC density is farmland approximate to grassland > forest in all soil layers. For the various soil types, the SIC density in the 0-100 cm layer is the highest in alkaline soil and lowest in subalpine meadow soil, whereas the SIC stock is highest in loessial soil, eolian sandy soil and sierozem, and the lowest in subalpine meadow soil. These differences are largely a result of the area occupied by each soil type and the climate conditions. The results of this study provide basic information about carbon reservoir in China and contribute to our understanding of the SIC stock on the CLP as it relates to the carbon balance of terrestrial ecosystems. (C) 2014 Elsevier B.V. All rights reserved.

The release of silicon (Si) from and the structural changes to clay minerals (i.e., kaolinite, montmorillonite (Mt), and illite) were investigated after being batch incubated with low-molecular-mass organic acids (i.e., oxalic and citric acids, LMMOA) of varying concentrations (0–0.5 mol L − 1 ) at 25 °C. Two mineral acids (i.e., HCl and H 2 SO 4 ) with varying concentrations were also reacted with Ca-montmorillonite (Ca 2 + -Mt). With increasing reaction time, the Si released from kaolinite and illite reached its maximum level after incubation with the varying LMMOA concentrations for 15 days. Quantities of Si released from the clay minerals with the LMMOA ranged from 0.22 to 114.01 μg mL − 1 (Si). Quantity of Si released with oxalic acid was higher than that with citric acid. The Si released from the clay minerals increased with increasing organic acid concentrations. More Si was released from Mt than from kaolinite and illite when incubated with the same LMMOA concentration. With increasing organic acid concentrations, the X-ray diffraction (XRD) reflection intensities of the Mt weakened, and this trend was more remarkable in the clay treated with oxalic acid than citric acid. However, no relationship between the XRD reflection intensity and the acid concentrations was noticeable in the incubated kaolinite and illite. While incubating with hydrochloric acid (HCl) and sulfate acid (H 2 SO 4 ) for 15 day incubation, amounts of Si released from Ca 2 + -Mt were generally higher than those reacting with organic acids, and more Si was released in the H 2 SO 4 treatment than that of HCl. But the XRD reflection intensities of the Ca 2 + -Mt had no distinctly change compared with those treated with the organic acids.

Rainfall intensity and slope gradient are important factors that affect soil erosion; however, contradictory observations have been made due to different experimental conditions and materials. Colluvial deposits with loose, coarse material and steep slopes are easily erodible, but the erosion mechanism of colluvial deposition remains obscure. This work investigated the effects of heavy and storm rainfall intensity and steep slope gradients on the infiltration, runoff, and soil loss of colluvial soil. The rainfall intensity ranged from 1.00 to 2.33 mm min⁻¹, and the slope gradient ranged from 36 to 84%. The infiltration rates declined sharply in the initial stage, whereas an opposite trend was observed for runoff rates until a steady state was reached after 5 min. Single- and multiple-peak models illustrated the two types of changes for the sediment yield process. The infiltration volume and the coefficient increased with increasing rainfall intensity and decreased with increasing slope, whereas the runoff coefficient decreased with increasing rainfall intensity and increased with increasing slope. Runoff volume and sediment yield increased with increasing rainfall intensity but had a critical slope gradient of 58% and >47%. The sediment concentration increased with increasing rainfall intensity, and first increased and then decreased with increasing slope gradients at rainfall intensities of 1.00 and 1.33 mm min⁻¹ but increased at rainfall intensities of 1.67, 2.00, and 2.33 mm min⁻¹. The findings of this study can be used to clarify the erosion mechanisms in disturbed soils with high coarse particle content.

Separation and collection of environmental nanoparticles (ENPs) in natural systems are of paramount importance in research on their nature and physicochemical properties for understanding their associated properties of adsorbing or binding to organic and trace metal contaminants. However, efficient separation and collection of ENPs in nature system remain obscure. This study aimed to use an automated ultrafiltration device (AUD) to demonstrate efficient collection of ENPs from highly weathered red soils. Synchrotron and conventional X-ray diffraction (XRD) with oriented and random powder specimens were employed to identify the composition of clay minerals with various particle-size fractions (PSFs

This study investigates biogeochemical reductive release of arsenate from beudantite into solution in a crater area in northern Taiwan, using a combination of X-ray absorption near-edge structure (XANES) and atomic absorption spectrometry. Total arsenic (As) concentrations in the soil were more than 200 mg/kg. Over four months of laboratory experiments, less than 0.8% As was released into solution after reduction experiments. The 71% to 83% As was chemically reduced into arsenite (As(III)) and partially weathering into the soluble phase. The kinetic dissolution and re-precipitation of As, Fe, Pb and sulfate in this area of paddy soils merits further study.

The products of Al hydrolysis play significant roles in terrestrial and aquatic environments, particularly through their binding of nutrients and pollutants. However, the effect of catechins on the crystallization of Al precipitates and the resultant surface alteration of Al transformation products on their kinetics and mechanisms of adsorption of Cd still remain to be uncovered. The objective of this paper was to investigate the kinetics of Cd adsorption on the Al precipitates formed under the influence of catechin. The experiments were conducted with initial catechin/Al molar ratios, interaction time, concentration of Cd ions, and temperature as the variables. Six kinetic models were employed to investigate adsorption mechanisms, and data resembled more closely a second-order process. The structural perturbation of Al precipitates by catechin, resulting in the development of their microporosity and alteration of surface and charge properties, substantially enhanced the rate constants of both fast and sl...

This study aimed to determine effects of rice straw biochar on Pb sequestration in a soil-rice system. Pot experiments were conducted with rice plants in Pb-contaminated paddy soils that had been amended with 0, 2.5, and 5% (w/w) biochar. Compared to the control treatment, amendment with 5% biochar resulted in 54 and 94% decreases in the acid soluble and CaCl2-extractable Pb, respectively, in soils containing rice plants at the maturity stage. The amount of Fe-plaque on root surfaces and the Pb concentrations of the Fe-plaque were also reduced in biochar amended soils. Furthermore, lead species in rice roots were determined using Pb L3-edge X-ray absorption near edge structure (XANES), and although Pb-ferrihydrite complexes dominated Pb inventories, increasing amounts of organic complexes like Pb-pectins and Pb-cysteine were found in roots from the 5% biochar treatments. Such organic complexes might impede Pb translocation from root to shoot and subsequently reduce Pb accumulation in rice with biochar amendment.

Soil is a vital biological habitat, which is of primary importance in determining and regulating biological activity and biodiversity. Therefore, it is Earth’s most important resource in sustaining both belowground and aboveground biological activities. Biodiversity versus landscape diversity and land use practices in multifunctional landscapes have been addressed. Humans have so manipulated nature that few locations in the world remain without human influence, causing unforeseen changes in ecosystem continuously and biodiversity. Among the environmental compartments, about 90 % of environmental pollutants are bound with soil particles. The soil-bound pollutants may be released to the soil solution through physical, chemical and biological interfacial interactions and pose a threat to biodiversity and ecosystem integrity. These interfacial interactions are especially important in the rhizosphere, where the kinds and concentrations of biomolecules are different from the bulk soil because of intense biological activity. These biomolecules affect biogeochemical processes, soil microbial ecology, nutrient and contaminant dynamics, abiotic and biotic factors, and soil biodiversity through allelopathic interactions. Soil interfacial interactions under different pedogenic processes and anthropogenic activity in relation to belowground biodiversity and the impact on aboveground biodiversity, productivity and integrity should be an important and exciting area of science for years to come.

Wine processing waste sludge (WPWS) has been shown to be an effective sorbent for sorption of nickel, lead, and chromium, but the sorption of copper (Cu) in aqueous solution by WPWS has not been conducted. The objective of this study was to explore the sorption mechanism of WPWS for copper. Infrared analysis revealed carboxyl was the major functional group inWPWS. The WPWS sorption isotherms of copper were only well described by Langmuir sorption isotherm. The maximum adsorption capacity (Qm) was 14.26 mg/g at 50 8C. A pseudo- second-order sorption kinetic model successfully described the kinetics of copper sorption onto WPWS. The Gibb free energies (DG8) ranged from � 20.69 to � 24.29 kJ mol -1 , and the DH8 and DS8 were 5.048 kJ mol -1 and 91.05 J mol -1 K -1 , respectively. The trend of the intra-particular diffusion rate is the opposite of the adsorption constant of the pseudo- second-order equation. Water Environ. Res., 84, 733 (2012).

This study examined the change in the speciation of cadmium (Cd) in contaminated rice paddy soils with prolonged submergence. Three Changhua soils (CH1, CH2, and CH3) from central Taiwan and three Taoyuan red soils (TY1, TY2, and TY3) from northern Taiwan with different levels of heavy metal contamination were selected for the study. The Cd, Fe, Mn, soil pH, and Eh in soil solutions were determined as a function of submerging time. During submergence, the Fe and Mn concentration increased, while the SO4 2− concentration decreased. The concentrations of Cd immediately increased in the soil solutions after a short submerging time and then decreased with further submergence. The sequential extraction showed that the exchangeable fraction decreased and the oxide-bound fraction increased after submergence. According to preliminary calculations of the MinteqA2 program, sulfate cannot be reduced to sulfite or sulfide under the soil Eh and pH values observed for the soils after prolonged submergence. Thus, the observed decreases of sulfate concentration may result from sulfate reduction in the micro-environments, which cannot be accounted for by the thermodynamic calculation. The reduction of sulfate to sulfide may subsequently result in the formation of CdS precipitate, which attributes to the decreases of Cd concentrations in the soil solutions after prolonged submergence.

Sewage sludge (SS) is used on sloping land, as a soil amendment, because of its organic matter (OM) and nutrient content. However, the presence of nitrogen (N), in acidic soils amended with sludge, and its transport in runoff can lead to eutrophication of downstream surface water. This study assesses the effects of different application methods on N transport, via runoff from plots amended with SS (0 and 120 Mg ha−1). A lateritic red soil (pH 5.2) was selected for this study, using simulated rainfall conditions. When sludge was broadcasted and mixed with surface soils (BM), the concentrations and mass losses of total N in the mixed sample (MTN), total N in the settled sample (STN), total particulate N (TPN), total suspended N (TSN), total dissolved N (TDN) and NH4+-N, in runoff water, were highest at 1 or 18 d after application. BM treatments showed initial pollution risks to surface waters, which diminished gradually with time. Whereas the concentrations and mass losses of NO3−-N, in all sludge plots, appeared to have a declining trend, after an initial ascent. Hole-application (HA) and broadcast application with hay mulch (BH) treatments prevented N loss effectively, the runoff losses coefficient of MTN increased in the order BM (0.43%) > HA (0.15%) > BH (0.03%). For sludge treatments, N was largely lost in dissolved species, while a large portion of NH4+-N was lost in particulate fraction. Nitrogen (N) losses in runoff were greatly affected by the transformation of sludge N in the soil and the modification of soil properties, induced by sludge amendment. The risk associated with the application of sludge to sloping fields, in areas of acidic soil, is an important research subject that merits further study.