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Prompted by the detection of stratospheric cloud layers by Cassini’s Composite Infrared Spectrometer (CIRS; see Anderson, C.M., Samuelson, R.E. [2011]. Icarus 212, 762–778), we have re-examined the observations made by the Descent Imager/Spectral Radiometer (DISR) in the atmosphere of Titan together with two constraints from measurements made outside the atmosphere. No evidence of thin layers (

Titan’s optical and near-IR spectra result primarily from the scattering of sunlight by haze and its absorption by methane. With a column abundance of 92 km amagat (11 times that of Earth), Titan’s atmosphere is optically thick and only ∼10% of the incident solar radiation reaches the surface, compared to 57% on Earth. Such a formidable atmosphere obstructs investigations of the moon’s lower troposphere and surface, which are highly sensitive to the radiative transfer treatment of methane absorption and haze scattering. The absorption and scattering characteristics of Titan’s atmosphere have been constrained by the Huygens Probe Descent Imager/Spectral Radiometer (DISR) experiment for conditions at the probe landing site (Tomasko, M.G., Bezard, B., Doose, L., Engel, S., Karkoschka, E. [2008a]. Planet. Space Sci. 56, 624–247; Tomasko, M.G. et al. [2008b]. Planet. Space Sci. 56, 669–707). Cassini’s Visual and Infrared Mapping Spectrometer (VIMS) data indicate that the rest of the atmosphere (except for the polar regions) can be understood with small perturbations in the high haze structure determined at the landing site (Penteado, P.F., Griffith, C.A., Tomasko, M.G., Engel, S., See, C., Doose, L., Baines, K.H., Brown, R.H., Buratti, B.J., Clark, R., Nicholson, P., Sotin, C. [2010]. Icarus 206, 352–365). However the in situ measurements were analyzed with a doubling and adding radiative transfer calculation that differs considerably from the discrete ordinates codes used to interpret remote data from Cassini and ground-based measurements. In addition, the calibration of the VIMS data with respect to the DISR data has not yet been tested. Here, VIMS data of the probe landing site are analyzed with the DISR radiative transfer method and the faster discrete ordinates radiative transfer calculation; both models are consistent (to within 0.3%) and reproduce the scattering and absorption characteristics derived from in situ measurements. Constraints on the atmospheric opacity at wavelengths outside those measured by DISR, that is from 1.6 to 5.0 μm, are derived using clouds as diffuse reflectors in order to derive Titan’s surface albedo to within a few percent error and cloud altitudes to within 5 km error. VIMS spectra of Titan at 2.6–3.2 μm indicate not only spectral features due to CH4 and CH3D (Rannou, P., Cours, T., Le Mouelic, S., Rodriguez, S., Sotin, C., Drossart, P., Brown, R. [2010]. Icarus 208, 850–867), but also a fairly uniform absorption of unknown source, equivalent to the effects of a darkening of the haze to a single scattering albedo of 0.63 ± 0.05. Titan’s 4.8 μm spectrum point to a haze optical depth of 0.2 at that wavelength. Cloud spectra at 2 μm indicate that the far wings of the Voigt profile extend 460 cm−1 from methane line centers. This paper releases the doubling and adding radiative transfer code developed by the DISR team, so that future studies of Titan’s atmosphere and surface are consistent with the findings by the Huygens Probe. We derive the surface albedo at eight spectral regions of the 8 × 12 km2 area surrounding the Huygens landing site. Within the 0.4–1.6 μm spectral region our surface albedos match DISR measurements, indicating that DISR and VIMS measurements are consistently calibrated. These values together with albedos at longer 1.9–5.0 μm wavelengths, not sampled by DISR, resemble a dark version of the spectrum of Ganymede’s icy leading hemisphere. The eight surface albedos of the landing site are consistent with, but not deterministic of, exposed water ice with dark impurities.

We determined Titan's reflectivity spectrum near the Huygens' landing site from observations taken with the Descent Imager/Spectral Radiometer below 500 m altitude, in particular the downward-looking photometer and spectrometers. We distinguish signal coming from illumination by sunlight and the lamp onboard Huygens based on their different spectral signatures. For the sunlight data before landing, we find that spatial variations of Titan's reflectivity were only ∼0.8%, aside from the phase angle dependence, indicating that the probed area within ∼100 m of the landing site was very homogeneous. Only the very last spectrum taken before landing gave a 3% brighter reflectivity, which probably was caused by one bright cobble inside its footprint. The contrast of the cobble was higher at 900 nm wavelength than at 600 nm. For the data from lamp illumination, we confirm that the phase function of Titan's surface displays a strong opposition effect as found by Schroder and Keller (2009. Planetary and Space Science 57, 1963–1974). We extend the phase function to even smaller phase angles (0.02°), which are among the smallest phase angles observed in the solar system. We also confirm the reflectivity spectrum of the dark terrain near the Huygens' landing site between 900 and 1600 nm wavelength by Schroder and Keller (2008. Planetary and Space Science 56, 753–769), but extend the spectrum down to 435 nm wavelength. The reflectivity at zero phase angle peaks at 0.45±0.06 around 750 nm wavelength and drops down to roughly 0.2 at both spectral ends. Our reflectivity of 0.45 is much higher than all previously reported values because our observations probe lower phase angles than others. The spectrum is very smooth except for a known absorption feature longward of 1350 nm. We did not detect any significant variation of the spectral shape along the slit for exposures after landing, probing a 25×4 cm2 area. However, the recorded spectral shape was slightly different for exposures before and after landing. This difference is similar to the spectral differences seen on scales of kilometers (Keller et al., 2008. Planetary and Space Science 56, 728–752), indicating that most observations may probe spatially variable contributions from two basic materials, such as a dark soil partially covered by bright cobbles. We used the methane absorption features to constrain the methane mixing ratio near the surface to 5.0±0.3%, in agreement with the 4.92±0.24% value measured in situ by Niemann et al. (2005. Nature 438, 779–784), but smaller than their revised value of 5.65±0.18% (Niemann et al., 2010. Journal of Geophysical Research 115, E12006). Our results were made possible by an in depth review of the calibration of the spectroscopic and photometric data.

We analyzed a unique, three-dimensional data set of Uranus acquired with the STIS Hubble spectrograph on August 19, 2002. The data covered a full afternoon hemisphere at 0.1 arc-sec spatial resolution between 300 and 1000 nm wavelength at 1 nm resolution. Navigation was accurate to 0.002 arc-sec and 0.02 nm. We tested our calibration with WFPC2 images of Uranus and found good agreement. We constrained the vertical aerosol structure with radiative transfer calculations. The standard types of models for Uranus with condensation cloud layers did not fit our data as well as models with an extended haze layer. The dark albedo of Uranus at near-infrared methane windows could be explained by methane absorption alone using conservatively scattering aerosols. Ultraviolet absorption from small aerosols in the stratosphere was strongest at high southern latitudes. The uppermost troposphere was almost clear, but showed a remarkable narrow spike of opacity centered on the equator to 0.2° accuracy. This feature may have been related to influx from ring material. At lower altitudes, the feature was centered at 1–2° latitude, suggesting an equatorial circulation toward the north. Below the 1.2 bar level, the aerosol opacity increased some 100 fold. A comparison of methane and hydrogen absorptions contradicted the standard interpretation of methane band images, which assumes that the methane mixing ratio is independent of latitude and attributes reflectivity variations to variations in the aerosol opacity. The opposite was true for the main contrast between brighter high latitudes and darker low latitudes, probing the 1–3 bar region. The methane mixing ratio varied between 0.014 and 0.032 from high to low southern latitudes, while the aerosol opacity varied only moderately with latitude, except for an enhancement at −45° latitude and a decrease north of the equator. The latitudinal variation of methane had a similar shape as that of ammonia probed by microwave observations at deeper levels. The variability of methane challenges our understanding of Uranus and requires reconsideration of previous investigations based on a faulty assumption. Below the 2 bar level, the haze was thinning somewhat. Our global radiative transfer models with 1° latitude sampling fit the observed reflectivities to 2% rms. The observed spectra of two discrete clouds could be modeled by using the background model of the appropriate latitude and adding small amounts of additional opacity at levels near 1.2 bar (southern cloud) and levels as high as 0.1 bar (northern cloud). These clouds may have been methane condensation clouds of low optical depth (∼0.2).

We analyze observations taken with Cassini’s Visual and Infrared Mapping Spectrometer (VIMS), to determine the current methane and haze latitudinal distribution between 60°S and 40°N. The methane variation was measured primarily from its absorption band at 0.61 μm, which is optically thin enough to be sensitive to the methane abundance at 20–50 km altitude. Haze characteristics were determined from Titan’s 0.4–1.6 μm spectra, which sample Titan’s atmosphere from the surface to 200 km altitude. Radiative transfer models based on the haze properties and methane absorption profiles at the Huygens site reproduced the observed VIMS spectra and allowed us to retrieve latitude variations in the methane abundance and haze. We find the haze variations can be reproduced by varying only the density and single scattering albedo above 80 km altitude. There is an ambiguity between methane abundance and haze optical depth, because higher haze optical depth causes shallower methane bands; thus a family of solutions is allowed by the data. We find that haze variations alone, with a constant methane abundance, can reproduce the spatial variation in the methane bands if the haze density increases by 60% between 20°S and 10°S (roughly the sub-solar latitude) and single scattering absorption increases by 20% between 60°S and 40°N. On the other hand, a higher abundance of methane between 20 and 50 km in the summer hemisphere, as much as two times that of the winter hemisphere, is also possible, if the haze variations are minimized. The range of possible methane variations between 27°S and 19°N is consistent with condensation as a result of temperature variations of 0–1.5 K at 20–30 km. Our analysis indicates that the latitudinal variations in Titan’s visible to near-IR albedo, the north/south asymmetry (NSA), result primarily from variations in the thickness of the darker haze layer, detected by Huygens DISR, above 80 km altitude. If we assume little to no latitudinal methane variations we can reproduce the NSA wavelength signatures with the derived haze characteristics. We calculate the solar heating rate as a function of latitude and derive variations of ∼10–15% near the sub-solar latitude resulting from the NSA. Most of the latitudinal variations in the heating rate stem from changes in solar zenith angle rather than compositional variations.

We use 11 data sets of methane transmission measurements within 0.4–5.5 μm wavelength to model the methane transmission for temperature and pressure conditions in the jovian planets. Eight data sets are based on published laboratory measurements. Another two data sets come from two spectrometers onboard the Huygens probe that measured methane absorption inside Titan’s atmosphere ( Tomasko et al., 2008b, PSS 56, 624 ), and we provide a refined analysis. The last data set is a set of new Jupiter images by the Hubble Space Telescope to measure atmospheric transmission with Ganymede as the light source. Below 1000 nm wavelength, our resulting methane absorption coefficients are generally close to those by Karkoschka (1998, Icarus 133, 134) , but we add descriptions of temperature and pressure dependence. One remaining inconsistency occurs between 882 and 902 nm wavelength where laboratory data predict larger absorptions in the jovian atmospheres than observed. We present possible explanations. Above 1000 nm, our analysis of the Huygens data confirms methane absorption coefficients by Irwin et al. (2006, Icarus 181, 309) at their laboratory temperatures. Huygens data also confirm Irwin’s model of extrapolation to Titan’s lower pressures. However, their model of extrapolation to Titan’s lower temperatures predicts absorption coefficients up to 100 times lower than measured by Huygens. For each of ∼3700 wavelengths, we present a temperature dependence that is consistent with all laboratory data and the Huygens data. Since the Huygens data probe similar temperatures as many observations of Saturn, Uranus, Neptune, and Titan, our methane model will allow more reliable radiative transfer models for their atmospheres.

The Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens probe into the atmosphere of Titan yielded information on the size, shape, optical properties, and vertical distribution of haze aerosols in the atmosphere of Titan [Tomasko, M.G., Doose, L., Engel, S., Dafoe, L.E., West, R., Lemmon, M., Karkoschka, E., 2008. Planet. Space Sci. 56, 669–707] from photometric and spectroscopic measurements of sunlight in Titan’s atmosphere. This instrument also made measurements of the degree of linear polarization of sunlight in two spectral bands centered at 491 and 934 nm. Here we present the calibration and reduction of the polarization measurements and compare the polarization observations to models using fractal aggregate particles which have different sizes for the small dimension (monomer size) of which the aggregates are composed. We find that the Titan aerosols produce very large polarizations perpendicular to the scattering plane for scattering near 90° scattering angle. The size of the monomers is tightly constrained by the measurements to a radius of 0.04 ± 0.01 μm at altitudes from 150 km to the surface. The decrease in polarization with decreasing altitude observed in red and blue light is as expected by increasing dilution due to multiple scattering at decreasing altitudes. There is no indication of particles that produce small amounts of linear polarization at low altitudes.

The Descent Imager/Spectral Radiometer (DISR) of the Huygens probe was in an excellent position to view aspects of rain as it descended through Titan's atmosphere. Rain may play an important part of the methane cycle on Titan, similar to the water cycle on Earth, but rain has only been indirectly inferred in previous studies. DISR detected two dark atmospheric layers at 11 and 21 km altitude, which can be explained by a local increase in aerosol size by about 5–10%. These size variations are far smaller than those in rain clouds, where droplets grow some 1000-fold. No image revealed a rainbow, which implies that the optical depth of raindrops was less than ∼ 0.0002 / km . This upper limit excludes rain and constrains drizzle to extremely small rates of less than 0.0001 mm/h. However, a constant drizzle of that rate over several years would clear the troposphere of aerosols faster than it can be replenished by stratospheric aerosols. Hence, either the average yearly drizzle rate near the equator was even less ( 0.1 mm / yr ), or the observed aerosols came from somewhere else. The implied dry environment is consistent with ground-based imaging showing a lack of low-latitude clouds during the years before the Huygens descent. Features imaged on Titan's surface after landing, which might be interpreted as raindrop splashes, were not real, except for one case. This feature was a dewdrop falling from the outermost baffle of the DISR instrument. It can be explained by warm, methane-moist air rising along the bottom of the probe and condensing onto the cold baffle.

Our model [Dimitrov, V., Bar-Nun, A., 1999. A model of energy dependent agglomeration of hydrocarbon aerosol particles and implication to Titan's aerosol. J. Aerosol. Sci. 30(1), 35–49] describes the experimentally found polymerization of C2H2 and HCN to form aerosol embryos, their growth and adherence to form various aerosols objects [Bar-Nun, A., Kleinfeld, I., Ganor, E., 1988. Shape and optical properties of aerosols formed by photolysis of C2H2, C2H4 and HCN. J. Geophys. Res. 93, 8383–8387]. These loose fractal objects describe well the findings of DISR on the Huygens probe [Tomasko, M.G., Bezard, B., Doose, L., Engel, S., Karkoschka, E., 2008. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this issue, doi:10.1016/j.pss.2007]. These include (1) various regular objects of R=(0.035–0.064)×10−6 m, as compared with DISR's 0.05×10−6 m; (2) diverse low and high fractal structures composed of random combinations of various regular and irregular objects; (3) the number density of fractal particles is 6.9×106 m−3 at Z=100 km, as compared with DISR's finding of 5.0×106 m−3 at Z=80 km; (4) the number of structural units per higher fractals in the atmosphere at Z∼100 km is (2400–2700), as compared with DISR's 3000, and their size being of R=(5.4–6.4)×10−6 m will satisfy this value and (5) condensation of CH4 on the highly fractal structures could begin at the altitude where thin methane clouds were observed, filling somewhat the new open fractal structures.

The descent imager/spectral radiometer (DISR) instrument aboard the Huygens probe into the atmosphere of Titan measured the brightness of sunlight using a complement of spectrometers, photometers, and cameras that covered the spectral range from 350 to 1600 nm, looked both upward and downward, and made measurements at altitudes from 150 km to the surface. Measurements from the upward-looking visible and infrared spectrometers are described in Tomasko et al. [2008a. Measurements of methane absorption by the descent imager/spectral radiometer (DISR) during its descent through Titan's atmosphere. Planet. Space Sci., this volume]. Here, we very briefly review the measurements by the violet photometers, the downward-looking visible and infrared spectrometers, and the upward-looking solar aureole (SA) camera. Taken together, the DISR measurements constrain the vertical distribution and wavelength dependence of opacity, single-scattering albedo, and phase function of the aerosols in Titan's atmosphere. Comparison of the inferred aerosol properties with computations of scattering from fractal aggregate particles indicates the size and shape of the aerosols. We find that the aggregates require monomers of radius 0.05 μm or smaller and that the number of monomers in the loose aggregates is roughly 3000 above 60 km. The single-scattering albedo of the aerosols above 140 km altitude is similar to that predicted for some tholins measured in laboratory experiments, although we find that the single-scattering albedo of the aerosols increases with depth into the atmosphere between 140 and 80 km altitude, possibly due to condensation of other gases on the haze particles. The number density of aerosols is about 5/cm3 at 80 km altitude, and decreases with a scale height of 65 km to higher altitudes. The aerosol opacity above 80 km varies as the wavelength to the −2.34 power between 350 and 1600 nm. Between 80 and 30 km the cumulative aerosol opacity increases linearly with increasing depth in the atmosphere. The total aerosol opacity in this altitude range varies as the wavelength to the −1.41 power. The single-scattering phase function of the aerosols in this region is also consistent with the fractal particles found above 60 km. In the lower 30 km of the atmosphere, the wavelength dependence of the aerosol opacity varies as the wavelength to the −0.97 power, much less than at higher altitudes. This suggests that the aerosols here grow to still larger sizes, possibly by incorporation of methane into the aerosols. Here the cumulative opacity also increases linearly with depth, but at some wavelengths the rate is slightly different than above 30 km altitude. For purely fractal particles in the lowest few km, the intensity looking upward opposite to the azimuth of the sun decreases with increasing zenith angle faster than the observations in red light if the single-scattering albedo is assumed constant with altitude at these low altitudes. This discrepancy can be decreased if the single-scattering albedo decreases with altitude in this region. A possible explanation is that the brightest aerosols near 30 km altitude contain significant amounts of methane, and that the decreasing albedo at lower altitudes may reflect the evaporation of some of the methane as the aerosols fall into dryer layers of the atmosphere. An alternative explanation is that there may be spherical particles in the bottom few kilometers of the atmosphere.

International audience; New low-temperature methane absorption coefficients pertinent to the Titan environment are presented as derived from the Huygens DISR spectral measurements combined with the in-situ measurements of the methane gas abundance profile measured by the Huygens Gas Chromatograph/Mass Spectrometer (GCMS). The visible and near-infrared spectrometers of the descent imager/spectral radiometer (DISR) instrument on the Huygens probe looked upward and downward covering wavelengths from 480 to 1620 nm at altitudes from 150 km to the surface during the descent to Titan's surface. The measurements at continuum wavelengths were used to determine the vertical distribution, single-scattering albedos, and phase functions of the aerosols. The gas chromatograph/mass spectrometer (GCMS) instrument on the probe measured the methane mixing ratio throughout the descent. The DISR measurements are the first direct measurements of the absorbing properties of methane gas made in the atmosphere of Titan at the pathlengths, pressures, and temperatures that occur there. Here we use the DISR spectral measurements to determine the relative methane absorptions at different wavelengths along the path from the probe to the sun throughout the descent. These transmissions as functions of methane path length are fit by exponential sums and used in a haze radiative transfer model to compare the results to the spectra measured by DISR. We also compare the recent laboratory measurements of methane absorption at low temperatures [Irwin et al., 2006. Improved near-infrared methane band models and k-distribution parameters from 2000 to 9500 cm -1 and implications for interpretation of outer planet spectra. Icarus 181, 309-319] with the DISR measurements. We find that the strong bands formed at low pressures on Titan act as if they have roughly half the absorption predicted by the laboratory measurements, while the weak absorption regions absorb considerably more than suggested by some extrapolations of warm measurements to the cold Titan temperatures. We give factors as a function of wavelength that can be used with the published methane coefficients between 830 and 1620 nm to give agreement with the DISR measurements. We also give exponential sum coefficients for methane absorptions that fit the DISR observations. We find the DISR observations of the weaker methane bands shortward of 830 nm agree with the methane coefficients given by Karkoschka [1994. Spectrophotometry of the jovian planets and Titan at 300- to 1000-nm wavelength: the methane spectrum. Icarus 111, 174-192]. Finally, we discuss the implications of our results for computations of methane absorption in the atmospheres of the outer planets.

The descent imager/spectral radiometer (DISR) onboard the Huygens probe investigated the radiation balance inside Titan's atmosphere and took hundreds of images and spectra of the ground during the descent. The scattering of the aerosols in the atmosphere and the absorption by methane strongly influence the irradiation reaching the surface and the signals received by the various instruments. The physical properties of the surface can only be assessed after the influence of the atmosphere has been taken into account and properly removed. In the broadband visible images (660 to 1000 nm) the contrast of surface features is strongly reduced by the aerosol scattering. Calculations show that for an image taken from an altitude of 14.5 km, the corrected contrast is about three times higher than in the raw image. Spectral information of the surface by the imaging spectrometers in the visible and near infrared range can only be retrieved in the methane absorption windows. Intensity ratios from the methane windows can be used to make false color maps. The elevated bright ‘land’ terrain is redder than the flat dark ‘lake bed’ terrain. The reflectance spectra of the land and lake bed area in the IR are derived, as well as the reflectance phase function in the limited range from 20 ∘ to 50 ∘ phase angle. An absorption feature at 1.55 μ m which may be attributed tentatively to water ice is found in the lake bed, but not in the land area. Otherwise the surface exhibits a featureless blue slope in the near-IR region (0.9– 1.6 μ m ). Brightness profiles perpendicular to the coast line show that the bottoms of the channels of the large scale flow pattern become darker the further they are away from the land area. This could be interpreted as sedimentation of the bright land material transported by the rivers into the lake bed area. The river beds in the deeply incised valleys need not to be covered by dark material. Their roughly 10% brightness decrease could be caused by the illumination as illustrated by a model calculation. The size distribution of cobbles seen in the images after landing is in agreement with a single major flooding of the area with a flow speed of about 1 m s - 1 .

Titan's vast equatorial fields of RADAR-dark longitudinal dunes seen in Cassini RADAR synthetic aperture images correlate with one of two dark surface units discriminated as “brown” and “blue” in Visible and Infrared Mapping Spectrometer (VIMS) color composites of short-wavelength infrared spectral cubes (RGB as 2.0, 1.6, 1.3 μm). In such composites bluer materials exhibit higher reflectance at 1.3 μm and lower at 1.6 and 2.0 μm. The dark brown unit is highly correlated with the RADAR-dark dunes. The dark brown unit shows less evidence of water ice suggesting that the saltating grains of the dunes are largely composed of hydrocarbons and/or nitriles. In general, the bright units also show less evidence of absorption due to water ice and are inferred to consist of deposits of bright fine precipitating tholin aerosol dust. Some set of chemical/mechanical processes may be converting the bright fine-grained aerosol deposits into the dark saltating hydrocarbon and/or nitrile grains. Alternatively the dark dune materials may be derived from a different type of air aerosol photochemical product than are the bright materials. In our model, both the bright aerosol and dark hydrocarbon dune deposits mantle the VIMS dark blue water ice-rich substrate. We postulate that the bright mantles are effectively invisible (transparent) in RADAR synthetic aperture radar (SAR) images leading to lack of correlation in the RADAR images with optically bright mantling units. RADAR images mostly show only dark dunes and the water ice substrate that varies in roughness, fracturing, and porosity. If the rate of deposition of bright aerosol is 0.001–0.01 μm/yr, the surface would be coated (to optical instruments) in hundreds-to-thousands of years unless cleansing processes are active. The dark dunes must be mobile on this very short timescale to prevent the accumulation of bright coatings. Huygens landed in a region of the VIMS bright and dark blue materials and about 30 km south of the nearest occurrence of dunes visible in the RADAR SAR images. Fluvial/pluvial processes, every few centuries or millennia, must be cleansing the dark floors of the incised channels and scouring the dark plains at the Huygens landing site both imaged by Descent Imager/Spectral Radiometer (DISR).

The Descent Imager/Spectral Radiometer (DISR) provided 376 images during the descent to Titan and 224 images after landing. Images of the surface had scales between 150 m/pixel and 0.4 mm/pixel, all of which we assembled into a mosaic. The analysis of the surface and haze features in these images and of other data gave tight constraints on the geometry of the descent, particularly the trajectory, the tip and tilt, and the rotation of the Huygens probe. Huygens moved on average in the direction of 2ring operator north of east from 145 to 50 km altitude, turning to 5ring operator south of east between 30 and 20 km altitude, before turning back to east. At 6.5 km altitude, it reversed to WNW, before reversing back to SE at 0.7 km altitude. At first, Huygens was tilting slowly by up to 15ring operator as expected for a descent through layers of changing wind speeds. As the winds calmed, tilts decreased. Tilts were approximately retrieved throughout the main-parachute phase, but only for 160 specific times afterwards. Average swing rates were 5ring operator/s at high and low altitudes, but 13ring operator/s between 110 and 30 km altitude. Maximum swing rates were often above 40ring operator/s, far above the design limit of 6ring operator/s, but they caused problems only for a single component of DISR, the Sun Sensor. The excitation of such high swing rates on the stabilizer parachute is not fully understood. Before the parachute exchange, the rotational rate of Huygens smoothly approached the expected equilibrium value of 3 rotations per vertical kilometer, although clockwise instead of counterclockwise. Starting at 40 s after the parachute exchange until landing, Huygens rotated erratically. Long-term averages of the rotational rate varied between 2.0 and 4.5 rotations/km. On time scales shorter than a minute, some 100 strong rotational accelerations or decelerations created azimuthal irregularities of up to 180ring operator, which caused DISR to take most exposures at random azimuths instead of pre-selected azimuths. Nevertheless, we reconstructed the azimuths throughout the 360 rotations during the descent and for each of some 3500 DISR exposures with a typical accuracy near 2ring operator. Within seconds after landing, the parachute moved into the field of view of one of the spectrometers. The observed light curve indicated a motion of the parachute of 0.3 m/s toward the SSE. DISR images indicated that the probe did not penetrate into the surface, assuming a level ground. This impact of Huygens must have occurred on major rocks or some elevated area. The unexpected raised height increases ice-rock sizes by 40% with respect to estimations made in 2005 [Tomasko, M.G., Archinal, B., Becker, T., Bezard, B., Bushroe, M., Combes, M., Cook, D., Coustenis, A., de Bergh, C., Dafoe, L.E., Doose, L., Doute, S., Eibl, A., Engel, S., Gliem, F., Grieger, B., Holso, K., Howington-Kraus, E., Karkoschka, E., Keller, H.U., Kirk, R., Kramm, R., Kuppers, M., Lanagan, P., Lellouch, E., Lemmon, M., Lunine, J., McFarlane, E., Moores, J., Prout, G.M., Rizk, B., Rosiek, M., Rueffer, P., Schroder, S.E., Schmitt, B., See, C., Smith, P., Soderblom, L., Thomas, N., West, R., 2005. Rain, winds and haze during the Huygens probe's descent to Titan's surface. Nature 438, 765–778]. During the 70-min surface phase, the tilt of Huygens was 3ring operator, changing by a small fraction of a degree. The apparent horizon looking south to SSW from the landing site was 1–2ring operator above the theoretical horizon, sloping by 1ring operator up to the left (east). Our best guess puts the horizon as a 1–2 m high hill in 30–50 m distance. We detected the refraction from warm, rising air bubbles above our illuminated spot. Bright, elongated, cm-sized objects appear occasionally on the surface. If real, they could be rain drop splashes or fluffy particles blown across Titan's surface.

We analyzed 134 images of Saturn taken by the Hubble Space Telescope between 1991 and 2004. The images cover wavelengths between 231 and 2370 nm in 30 filters. We combined some 10 million calibrated reflectivity measurements into 18,000 center-to-limb curves. We used the method of principal component analysis to find the main latitudinal and temporal variations in Saturn's atmosphere and their spectral characteristics. The first principal variation is a strong latitudinal variation of the aerosol optical depth in the upper troposphere. This structure shifts with Saturn's seasons, but the structure on small scales of latitude stays constant. The second principal variation is a variable optical depth of stratospheric aerosols. The optical depth is large at the poles and small at mid- and low latitudes with a steep gradient in-between. This structure remains essentially constant in time. The third principal variation is a variation in the tropospheric aerosol size, which has only shallow gradients with latitude, but large seasonal variations. Thus, aerosol sizes and their phase functions inferred at a particular season are not representative of Saturn's atmosphere at other seasons. Aerosols are largest in the summer and smallest in the winter. The fourth principal variation is a feature of the tropospheric aerosols with irregular latitudinal structure and fast variability, on the time scale of months. Spherical aerosols do not display the spectral characteristic of that feature. We suspect that variations in the shape of aerosols may play a role. We found a spectral feature of the imaginary index of aerosols, which darkens them near 400 nm wavelength. While we can describe Saturn's variations quite accurately, our presented model of Saturn's average atmosphere is still uncertain due to possible systematic offsets in methane absorption data and limitations of the knowledge about the shape of aerosols. In order to compare our results with those from comparable investigations, which used less than 30 filters, we fit models to spectral subsets of our data. We found very different best-fitting models, depending on the subset of filters, indicating a high sensitivity of results on the spectral sampling.

Low-latitude near-infrared spectral images of Titan reveal what are probably dark liquid lakes of methane. Saturn's moon Titan has a 'methane cycle' that is similar, in principle, to Earth's water cycle, although surface liquid seems relatively scarce on Titan, being detected mainly at high latitudes. The fact that Titan can supply its atmosphere with methane — together with signs of surface water erosion around the Huygens probe landing site in what seems to be an otherwise arid region of the tropics — suggests that there may be more surface liquid to be discovered. This paper reports near-infrared spectral images of an area in the tropics that reveal a dark region, which could indicate the presence of liquid methane on the moon's surface, supplied by subterranean sources. Titan has clouds, rain and lakes—like Earth—but composed of methane rather than water. Unlike Earth, most of the condensable methane (the equivalent of 5 m depth globally averaged1) lies in the atmosphere. Liquid detected on the surface (about 2 m deep) has been found by radar images only poleward of 50° latitude2,3, while dune fields pervade the tropics4. General circulation models explain this dichotomy, predicting that methane efficiently migrates to the poles from these lower latitudes5,6,7. Here we report an analysis of near-infrared spectral images8 of the region between 20° N and 20° S latitude. The data reveal that the lowest fluxes in seven wavelength bands that probe Titan's surface occur in an oval region of about 60 × 40 km2, which has been observed repeatedly since 2004. Radiative transfer analyses demonstrate that the resulting spectrum is consistent with a black surface, indicative of liquid methane on the surface. Enduring low-latitude lakes are best explained as supplied by subterranean sources (within the last 10,000 years), which may be responsible for Titan’s methane, the continual photochemical depletion of which furnishes Titan's organic chemistry9.

The payload of the Huygens Probe into the atmosphere of Titan includes the Descent Imager/Spectral Radiometer (DISR). This instrument includes an integrated package of several optical instruments built around a silicon charge coupled device (CCD) detector, a pair of linear InGaAs array detectors, and several individual silicon detectors. Fiber optics are used extensively to feed these detectors with light collected from three frame imagers, an upward and downward-looking visible spectrometer, an upward and downward looking near-infrared spectrometer, upward and downward looking violet phtotometers, a four-channel solar aerole camera, and a sun sensor that determines the azimuth and zenith angle of the sun and measures the flux in the direct solar beam at 940 nm. An onboard optical calibration system uses a small lamp and fiber optics to track the relative sensitivity of the different optical instruments relative to each other during the seven year cruise to Titan. A 20 watt lamp and collimator are used to provide spectrally continuous illumination of the surface during the last 100 m of the descent for measurements of the reflection spectrum of the surface. The instrument contains software and hardware data compressors to permit measurements of upward and downward direct and diffuse solar flux between 350 and 1700 nm in some 330 spectral bands at approximately 2 km vertical resolution from an alititude of 160 km to the surface. The solar aureole camera measures the brightness of a 6° wide strip of the sky from 25 to 75° zenith angle near and opposite the azimuth of the sun in two passbands near 500 and 935 nm using vertical and horizontal polarizers in each spectral channel at a similar vertical resolution. The downward-looking spectrometers provide the reflection spectrum of the surface at a total of some 600 locations between 850 and 1700 nm and at more than 3000 locations between 480 and 960 nm. Some 500 individual images of the surface are expected which can be assembled into about a dozen panoramic mosaics covering nadir angles from 6° to 96° at all azimuths. The spatial resolution of the images varies from 300 m at 160 km altitude to some 20 cm in the last frames. The scientific objectives of the experiment fall into four areas including (1) measurement of the solar heating profile for studies of the thermal balance of Titan; (2) imaging and spectral reflection measurements of the surface for studies of the composition, topography, and physical processes which form the surface as well as for direct measurements of the wind profile during the descent; (3) measurements of the brightness and degree of linear polarization of scattered sunlight including the solar aureole together with measurements of the extinction optical depth of the aerosols as a function of wavelength and altitude to study the size, shape, vertical distribution, optical properties, sources and sinks of aerosols in Titan’s atmosphere; and (4) measurements of the spectrum of downward solar flux to study the composition of the atmosphere, especially the mixing ratio profile of methane throughout the descent. We briefly outline the methods by which the flight instrument was calibrated for absolute response, relative spectral response, and field of view over a very wide temperature range. We also give several examples of data collected in the Earth’s atmosphere using a spare instrument including images obtained from a helicopter flight program, reflection spectra of various types of terrain, solar aureole measurements including the determination of aerosol size, and measurements of the downward flux of violet, visible, and near infrared sunlight. The extinction optical depths measured as a function of wavelength are compared to models of the Earth’s atmosphere and are divided into contributions from molecular scattering, aerosol extinction, and molecular absorption. The test observations during simulated descents with mountain and rooftop venues in the Earth’s atmosphere are very important for driving out problems in the calibration and interpretion of the observations to permit rapid analysis of the observations after Titan entry.

Remote observations of the atmospheric water vapour from the Mars orbit were usually carried out to study its global distribution and variability. Measurements of the water vapour abundance onboard the landers have recently become an important complement to the orbital sounding. Narrow-band filter photometry and spectroscopy of the solar radiation from the surface of the planet proved to be a powerful tool in the study of atmospheric water. The Imager for Mars Pathfinder (IMP) was the first instrument to measure its amount from the surface. The Surface Stereo Imager (SSI) onboard the Mars Polar Lander (MPL) was to follow but the spacecraft was lost at landing. Nevertheless significant expertise in the optical measurements of atmospheric H2O was gained during these missions. This paper summarizes this experience emphasizing the radiative transfer aspects of the problem. The results of this study could be of importance for future missions to Mars.

The Imager for Mars Pathfinder (IMP) returned sequences of images of the Martian sky characterizing the size distribution, optical constants, and nature of the aerosols suspended in the atmosphere of Mars. These sequences were executed when the solar elevation angle was approximately 15° and consisted of images near the elevation of the Sun, spanning a range in azimuth from about 4° to 180° from the Sun. Images were obtained at four wavelengths from 444 to 965 nm. From one sequence of observations, results are shown from a comparison of absolute photometry of the Martian sky with multiple scattering models. Results include the following. (1) The geometric cross-section-weighted mean particle radius is 1.6 ± 0.15 μm almost independent of the assumed width (variance) of the size distribution. (2) The imaginary refractive index shows a steep increase with wavelength from 670 nm to shorter wavelengths, and a shallow increase toward longer wavelengths, consistent with the reflection spectrum observed by IMP for Martian soil. (3) For each assumed variance, two parameters governing the slope and curvature of the portion of the phase function due to internally transmitted light are found uniquely as functions of wavelength. (4) The variance of the gamma size distribution is difficult to constrain from these observations alone. The shape of the single scattering phase functions derived from the IMP observations is compared to laboratory measurements of powder samples. One sample of irregular particles has a single scattering phase function quite similar to that derived for Mars. Overall, the results for the mean cross-section-weighted size and imaginary refractive index as a function of wavelength are in remarkably good agreement with the revised analysis by Pollack et al. [1995] of the observations made by the Viking lander 20 years earlier.

The Imager for Mars Pathfinder (IMP) was the first instrument to measure the atmospheric water on Mars from its surface. It took the images of the Sun through the Martian atmosphere in five narrowband filters, two in the 0.94 μm H2O band and three in the continuum around it. The observations were carried out in the mornings and in the evenings when the Sun was between 3° and 8° above the horizon. The absorption due to the atmospheric water vapor did not exceed 2%. An average column density of 6±4 precipitated microns (pr μm) was derived from the IMP data. The dependence of the observed H2O transmittance on Sun elevation tentatively implies that the water vapor is not uniformly mixed in the atmosphere but is rather confined to a layer 1–3 km thick near the surface. IMP observations also indicate a horizontal inhomogeneity of the layer but show no significant morning-to-evening variations of the water vapor amount.

The Galileo probe net flux radiometer (NFR) measured radiation fluxes in Jupiter's atmosphere from about 0.44 to 14 bars, using five spectral channels to separate solar and thermal components. Onboard calibration results confirm that the NFR responded to radiation approximately as expected. NFR channels also responded to a superimposed thermal perturbation, which can be approximately removed using blind channel measurements and physical constraints. Evidence for the expected NH3 cloud was seen in the spectral character of spin-induced modulations of the direct solar beam signals. These results are consistent with an overlying cloud of small NH3 ice particles (0.5-0.75 microns in radius) of optical depth 1.5-2 at 0.5 microns. Such a cloud would have so little effect on thermal fluxes that NFR thermal channels provide no additional constraints on its properties. However, evidence for heating near 0.45 bar in the NFR thermal channels would seem to require either an additional opacity source beyond this small-particle cloud, implying a heterogeneous cloud structure to avoid conflicts with solar modulation results, or a change in temperature lapse rate just above the probe measurements. The large thermal flux levels imply water vapor mixing ratios that are only 6% of solar at 10 bars, but possibly increasing with depth, and significantly subsaturated ammonia at pressures less than 3 bars. If deep NH3 mixing ratios at the probe entry site are 3-4 times ground-based inferences, as suggested by probe radio signal attenuation, then only half as much water is needed to match NFR observations. No evidence of a water cloud was seen near the 5-bar level. The 5-microns thermal channel detected the presumed NH4SH cloud base near 1.35 bars. Effects of this cloud were also seen in the solar channel upflux measurements but not in the solar net fluxes, implying that the cloud is a conservative scatterer of sunlight. The minor thermal signature of this cloud is compatible with particle radii near 3 gm, but it cannot rule out smaller particles. Deeper than about 3 bars, solar channels indicate unexpectedly large absorption of sunlight at wavelengths longer than 0.6 microns, which might be due to unaccounted-for absorption by NH3 between 0.65 and 1.5 microns.

Images of the martian surface returned by the Imager for Mars Pathfinder (IMP) show a complex surface of ridges and troughs covered by rocks that have been transported and modified by fluvial, aeolian, and impact processes. Analysis of the spectral signatures in the scene (at 440- to 1000-nanometer wavelength) reveal three types of rock and four classes of soil. Upward-looking IMP images of the predawn sky show thin, bluish clouds that probably represent water ice forming on local atmospheric haze (opacity ∼0.5). Haze particles are about 1 micrometer in radius and the water vapor column abundance is about 10 precipitable micrometers.

With the goal of improving our understanding of how small mineral dust particles scatter light at visible and near-infrared wafelengths we measured the scattering phase function and linear polarization of small mineral dust particles over the scattering angle range 15 to 170 at three wavelengths (0.47, 0.652,and 0.937 m).

Spectra from 1.7 to 3.3 μm acquired at the NASA Kuiper Airborne Observatory include two of Saturn's near-IR atmospheric transmission windows that are at least partially obscured by telluric H2O and CO2absorptions at ground-based telescopes. This entire spectral region was fitted to a model that included gaseous absorption by H2, CH4, NH3, and PH3and the effects of multiple scattering by haze. The objectives were to determine accurate elemental abundance ratios (e.g., C/H, P/H, etc.) and to characterize the size, distribution, and composition of the haze particles in Saturn's atmosphere. The results for C/H and P/H are 8.5 × 10−4and 4.3 × 10−7, respectively. No evidence of gaseous NH3was found. The upper limit to the NH3mixing ratio at Saturn's radiative-convective boundary is ≊10−9. Ammonia is decidedly undersaturated at atmospheric pressures lower than ≊1 bar. The upper limit to gaseous NH3at 3 μm is extremely low compared to detected amounts derived from observations at visible, mid-IR, and microwave wavelengths. These differences can be reconciled on the basis of different mechanisms for spectral line formation in these disparate spectral regions. A search for solid phase NH3was also negative. From thermochemical arguments it has been widely assumed that NH3ice crystals comprise the upper clouds on Saturn, although no incontrovertible spectroscopic proof has ever been presented. Strong bands of solid NH3at 3 μm therefore offer an important test of this assumption. Saturn's observed spectrum was placed on an absolute reflectivity scale which then could be compared with synthesized spectra of candidate haze particles. The calculations demonstrated that the reflectances of pure, polydisperse NH3ice crystals with effective radii ranging from 0.1 to 2.25 μm are not compatible with Saturn's 3-μm spectrum. A reasonable fit to Saturn's continuum spectrum can only be achieved by usingbright, micron-sized scattering haze particles mixed in with H2, CH4, and PH3in Saturn's middle and upper troposphere.

The imager for Mars Pathfinder (IMP), a stereoscopic, multispectral camera, is described in terms of its capabilities for studying the Martian environment. The camera's two eyes, separated by 15.0 cm, provide the camera with range-finding ability. Each eye illuminates half of a single CCD detector with a field of view of 14.4×14.0° and has 12 selectable filters. The ƒ/18 optics have a large depth of field, and no focussing mechanism is required; a mechanical shutter is avoided by using the frame transfer capability of the 512×512 CCD. The resolving power of the camera, 0.98 mrad/pixel, is approximately the same as the Viking Lander cameras; however, the signal-to-noise ratio for IMP greatly exceeds Viking, approaching 350. This feature along with the stable calibration of the filters between 440 and 1000 nm distinguishes IMP from Viking. Specially designed targets are positioned on the Lander; they provide information on the magnetic properties of wind-blown dust, measure the wind vectors, and provide radiometric standard reflectors for calibration. Also, eight low-transmission filters are included for imaging the Sun directly at multiple wavelengths, giving IMP the ability to measure dust opacity and potentially the water vapor content. Several experiments beyond the requisite color panorama are described in detail: contour mapping of the local terrain, multispectral imaging of the surrounding rock and soil to study local mineralogy, viewing of three wind socks, measuring atmospheric opacity and water vapor content, and estimating the magnetic properties of wind-blown dust. This paper is intended to serve as a guide to understanding the scientific integrity of the IMP data that will be returned from Mars starting on July 4, 1997.

The Galileo probe net flux radiometer measured radiation within Jupiter's atmosphere over the 125-kilometer altitude range between pressures of 0.44 bar and 14 bars. Evidence for the expected ammonia cloud was seen in solar and thermal channels down to 0.5 to 0.6 bar. Between 0.6 and 10 bars large thermal fluxes imply very low gaseous opacities and provide no evidence for a deep water cloud. Near 8 bars the water vapor abundance appears to be about 10 percent of what would be expected for a solar abundance of oxygen. Below 8 bars, measurements suggest an increasing water abundance with depth or a deep cloud layer. Ammonia appears to follow a significantly subsaturated profile above 3 bars. Unexpectedly high absorption of sunlight was found at wavelengths greater than 600 nanometers.

Recent observations demonstrate that near-infrared spectroscopy can probe Titan's surface through its haze. In a 5-week period during September and October 1993 we observed Titan's methane windows at 1.1, 1.3, 1.6, and 2 μm. At 1.1 and 1.3 μm observations were consistent with observations in 1992 at the same phases reported by Lemmon et al. (1993, Icarus 103, 329-332). Our new observations indicate that Titan was brighter near eastern elongation than near western elongation by 23 ± 2% at 1.6 μn and 32 ± 3% at 2 μn. With almost daily observations at 2 μn during one orbit, we observed Titan to be dark near western elongation, to brighten as it approached eastern elongation, and to darken as it returned to western elongation. We determine that the observed light-curve is due to surface albedo variations and Titan's rotational period is 15.950 ± 0.025 days. By considering the work of other observers we constrain the rotational period to be 15.949 ± 0.006 days; this constraint is consistent with synchronous rotation. Models of Titan's surface reflectivity are inconsistent with the presence of a strong 2-μm water ice absorption feature and do not require the presence of any surface absorption features; however, we cannot rule out models of the surface as dirty water ice or silicates that have been suggested by others.

We observed Saturn with the Hubble Space Telescope at wavelengths 0.30-0.89 μm for the purpose of determining the distribution of hazes. In the stratosphere, haze optical depths in the ultraviolet are essentially zero for midnorthern latitudes, are small (∼0.2) at low latitudes and mid-southern latitudes, but large (almost unity) above 70° north. The optical depth falls off sharply in the visible due to the small radii of the stratospheric aerosols (∼0.15 μm). The latitudinal distribution of tropospheric haze was found mostly consistent with previous investigations. It is completely different from the distribution of stratospheric haze since optical depths in the troposphere strongly increase from the north pole to the equator. In the ultraviolet, the stratospheric aerosols are darker than tropospheric aerosols. Latitudinal albedo and color variations in the visible, defining Saturn's belt and zone structure, can be explained by variations in the size of tropospheric aerosols (radii 1-2 μm). The unusual blue-green color of mid-southern latitudes in 1991 may be due to smaller radii (∼0.5 μm) in the troposphere. At wavelength 0.30 μm we found an indication of a gaseous absorption of ∼0.02 optical depth in the upper part of the stratosphere.

We have detected time variation in Titan's geometric albedo in methane windows at 0.94, 1.08, and 1.28 μm, relative to its albedo in adjacent methane bands, of 8 ± 5%, 14 ± 3%, and 22 ± 3%, respectively. We attribute these changes to a surface feature or a feature near the surface. Our observations are consistent with synchronous rotation and can be explained by a higher surface albedo by 0.1 on Titan's leading hemisphere.

A new apparatus for the growth of clouds of ammonia and water ice has been developed which represents an improvement over the one constructed by Holmes (1981). Better thermal control of the cloud chamber has been achieved so that colder temperature relevant to the outer planets' atmospheres could be reached. The angular resolution of the scattering measurements has been improved from 10 deg to about 2 deg. A rotating filter wheel combined with a much larger computer allows a complete data set to be collected in three colors once per second. This capability is important in monitoring cloud properties as they change with time and in collecting data on larger crystals which can fall through the beam in a few seconds.

This work describes observations of Saturn's atmosphere in the visible and near-infrared (460–940 nm) including 4 hydrogen quadrupole lines, 17 methane absorption bands ranging over 3 orders of magnitude in absorption strength, an ammonia absorption band, and the absolute calibrated continuum spectrum. All observations have complete coverage of Saturn's disk, in latitude as well as in center-to-limb position. A new method describing center-to-limb information is presented. The accuracy of the data is comparable to or better than that of previous data. This data set gives a quite complete description of Saturn's atmosphere in the visible and near infrared at the spatial resolution of ground-based observations. While the main data were acquired in 1988, small changes between 1986 and 1989 were determined also. Weak absorption features of hydrogen, methane, and ammonia show a significant enhancement in the North Polar Region compared to the rest of the planet. An atmospheric model is given which fits all observations within estimated errors. It has clear gas at the top of the atmosphere, an extended haze layer, and a reflective cloud at the bottom. Pressure levels and the haze optical depth were determined as a function of latitude. The single-scattering albedo spectrum of the particles (most likely ammonia ice crystals) is also given for each latitude. The methane mixing ratio is (3.0 ± 0.6) × 10−3, the ammonia mixing ratio is (1.2 + 0.8/−0.6) × 10−3 below the ammonia condensation level. A cold temperature methane absorption spectrum is determined under the assumption that methane band strengths are temperature invariant. It indicates that the absorption coefficients in band centers are typically 20–30% stronger than at room temperature. This spectrum should be useful in the interpretation of methane observations of all the giant planets and Titan.

A comparison of images of Titan obtained by the HST in August, 1990 with Voyager 1 and 2 images respectively obtained 10 and 9 years earlier has indicated a reversal of the seasonal hemispheric brightness asymmetry near 440 and 550 nm wavelengths; the northern hemisphere is in the more recent observations the brighter of the two, by about 10 percent. Titan's albedo pattern is therefore adequately explained by a seasonal model.

Remote sensing instruments aboard the Cassini spacecraft have been observed the surface of Titan globally in the infrared and radar wavelength ranges as well as locally by the Huygens instruments revealing a wealth of new morphological features indicating a geologically active surface. We present a summary of mapping products of Titan's surface derived from data of the remote sensing instruments onboard the Cassini spacecraft (ISS, VIMS, RADAR) as well as the Huygens probe (DISR) that were achieved during the nominal Cassini mission including an overview of Titan's recent nomenclature.

The surface of Titan has been revealed globally, if incompletely, by Cassini observations at infrared and radar wavelengths as well as locally by the instruments on the Huygens probe. Extended dune fields, lakes, mountainous terrain, dendritic erosion patterns and erosional remnants indicate dynamic surface processes. Valleys, small-scale gullies and rounded cobbles such as those observed at the Huygens landing site require erosion by energetic flow of a liquid. There is strong evidence that liquid hydrocarbons are ponded on the surface in high-latitude lakes, predominantly, but not exclusively, at high northern latitudes. A variety of features including extensive flows and caldera-like constructs are interpreted to be cryovolcanic in origin. Chains and isolated blocks of rugged terrain rising from smoother areas are best described as mountains and might be related to tectonic processes. Finally, impact craters are observed but their small numbers indicate that the crater retention age is very young overall. In general, Titan exhibits a geologically active surface indicating significant endogenic and exogenic processes, with diverse geophysical and atmospheric processes reminiscent of those on Earth.

The Huygens Probe returned the first in situ data on Titan's surface composition in January 2005. Although Huygens landed on a dry plain, the Gas Chromatograph Mass Spectrometer (GCMS) showed evidence of methane moisture in the near subsurface suggesting methane precipitation at some time in the past. Heavier organic molecules were not found to be abundant in the atmosphere or at the surface, but the GCMS surface results did show ethane to be present and tentatively identified cyanogen, benzene, and carbon dioxide. During descent, aerosol particles were processed with the Aerosol Collector and Pyroliser; results suggested that the aerosols contain both nitriles and hydrocarbons. The Descent Imager/Spectral Radiometer (DISR also carried by the probe) measured the visible and near-infrared spectral reflectance of the dark plain surface at the landing site. Those data suggest a mixture of water ice, tholin-like materials, and dark neutral material with a blue slope in the near infrared; identification of water ice is suggested but inconclusive. Most remarkably DISR did not detect spectral features, beyond those for methane, for a wide range of spectrally active hydrocarbon and nitrile compounds that had been expected to be present on the surface.

Aerosols in Titan's atmosphere play important roles in the transfer of solar and thermal radiation, in Titan's heat balance, in forcing atmospheric dynamics, and as a sink for photochemical reactions. In this chapter we briefly summarize the history of our knowledge of their distribution and optical properties before concentrating in greater detail on current knowledge of their properties and roles in the physics and chemistry in Titan's atmosphere. We discuss the size, shape, optical properties, and the vertical distribution of Titan's aerosols. We discuss variations of the optical properties of the aerosols with wavelength, variations of the distribution of the aerosols over the disk of Titan, and the seasonal and long-term variations in structure. We discuss the visible and thermal opacity of the aerosols, and their roles in Titan's heat balance. We summarize the history and current state of laboratory simulations of these particles, and present our understanding of their formation and life cycles in one and two-dimensional microphysical models. We also discuss the presence, location, and variations in condensation clouds over Titan's disk. Finally, we indicate the prospects for further progress in understanding the origin, distribution, and properties of Titan's aerosols in the future.

Scalar and vector radiative transfer and microphysical models are presently constructed from photometrically and geometrically corrected Voyager images of Uranus defining spatially-resolved intensities over a range of phase angles for two latitude bands. The methane ice cloud occupying 1.2-1.3 bar is of 0.7 optical depth at 22.5 deg S, rising to 2.4 at 65 deg S; the volume absorption coefficient of the cloud particles is 50 percent greater at the low latitude than at the high, assuming constant mean cloud particle size. The scattering model also includes photochemically-produced stratospheric hydrocarbon ices in the upper troposphere and stratosphere, as well as an optically thick hydrogen sulfide cloud.

The Descent Imager/Spectral Radiometer (DISR) aboard the Huygens Probe took several hundred visible-light images with its three cameras on approach to the surface of Titan. Several sets of stereo image pairs were collected during the descent. The digital terrain models constructed from those images show rugged topography, in places approaching the angle of repose, adjacent to flatter darker plains. Brighter regions north of the landing site display two styles of drainage patterns: (1) bright highlands with rough topography and deeply incised branching dendritic drainage networks (up to fourth order) with dark-floored valleys that are suggestive of erosion by methane rainfall and (2) short, stubby low-order drainages that follow linear fault patterns forming canyon-like features suggestive of methane spring-sapping. The topographic data show that the bright highland terrains are extremely rugged; slopes of order of 30° appear common. These systems drain into adjacent relatively flat, dark lowland terrains. A stereo model for part of the dark plains region to the east of the landing site suggests surface scour across this plain flowing from west to east leaving ∼100-m-high bright ridges. Tectonic patterns are evident in (1) controlling the rectilinear, low-order, stubby drainages and (2) the “coastline” at the highland–lowland boundary with numerous straight and angular margins. In addition to flow from the highlands drainages, the lowland area shows evidence for more prolific flow parallel to the highland–lowland boundary leaving bright outliers resembling terrestrial sandbars. This implies major west to east floods across the plains where the probe landed with flow parallel to the highland–lowland boundary; the primary source of these flows is evidently not the dendritic channels in the bright highlands to the north.

The Descent Imager/Spectral Radiometer (DISR) camera aboard the Huygens Probe to Saturn's moon Titan used a single frame transfer loral CCD to acquire image and radiometric data from nine individual optical sub-systems. The CCD was especially designed for DISR and was a German contribution to the DISR instrument established at the University of Arizona. Cassini/Huygens was launched in 1997, and the Huygens probe descended in 2005 through the atmosphere of Titan. DISR returned exciting pictures and spectra during descent and even after landing for more than 3 hours.

International audience; The irreversible conversion of methane into higher hydrocarbons in Titan's stratosphere implies a surface or subsurface methane reservoir. Recent measurements from the cameras aboard the Cassini orbiter fail to see a global reservoir, but the methane and smog in Titan's atmosphere impedes the search for hydrocarbons on the surface. Here we report spectra and high-resolution images obtained by the Huygens Probe Descent Imager/Spectral Radiometer instrument in Titan's atmosphere. Although these images do not show liquid hydrocarbon pools on the surface, they do reveal the traces of once flowing liquid. Surprisingly like Earth, the brighter highland regions show complex systems draining into flat, dark lowlands. Images taken after landing are of a dry riverbed. The infrared reflectance spectrum measured for the surface is unlike any other in the Solar System; there is a red slope in the optical range that is consistent with an organic material such as tholins, and absorption from water ice is seen. However, a blue slope in the near-infrared suggests another, unknown constituent. The number density of haze particles increases by a factor of just a few from an altitude of 150 km to the surface, with no clear space below the tropopause. The methane relative humidity near the surface is 50 per cent.

Mars Pathfinder successfully landed at Ares Vallis on July 4, 1997, deployed and navigated a small rover about 100 m clockwise around the lander, and collected data from three science instruments and ten technology experiments. The mission operated for three months and returned 2.3 Gbits of data, including over 16,500 lander and 550 rover images, 16 chemical analyses of rocks and soil, and 8.5 million individual temperature, pressure and wind measurements. Path-finder is the best known location on Mars, having been clearly identified with respect to other features on the surface by correlating five prominent horizon features and two small craters in lander images with those in high-resolution orbiter images and in inertial space from two-way ranging and Doppler tracking. Tracking of the lander has fixed the spin pole of Mars, determined the precession rate since Viking 20 years ago, and indicates a polar moment of inertia, which constrains a central metallic core to be between 1300 and ∼2000 km in radius. Dark rocks appear to be high in silica and geochemically similar to anorogenic andesites; lighter rocks are richer in sulfur and lower in silica, consistent with being coated with various amounts of dust. Rover and lander images show rocks with a variety of morphologies, fabrics and textures, suggesting a variety of rock types are present. Rounded pebbles and cobbles on the surface as well as rounded bumps and pits on some rocks indicate these rocks may be conglomerates (although other explanations are also possible), which almost definitely require liquid water to form and a warmer and wetter past. Air-borne dust is composed of composite silicate particles with a small fraction of a highly magnetic mineral, interpreted to be most likely maghemite; explanations suggest iron was dissolved from crustal materials during an active hydrologic cycle with maghemite freeze dried onto silicate dust grains. Remote sensing data at a scale of a kilometer or greater and an Earth analog correctly predicted a rocky plain safe for landing and roving with a variety of rocks deposited by catstrophic floods, which are relatively dust free. The surface appears to have changed little since it formed billions of years ago, with the exception that eolian activity may have deflated the surface by ∼3–7 cm, sculpted wind tails, collected sand into dunes, and eroded ventifacts (fluted and grooved rocks). Pathfinder found a dusty lower atmosphere, early morning water ice clouds, and morning near-surface air temperatures that changed abruptly with time and height. Small scale vortices, interpreted to be dust devils, were observed repeatedly in the afternoon by the meteorology instruments and have been imaged.

The Huygen's probe of the atmosphere of Saturn's moon Titan includes one optical instrument sensitive to the wavelengths of solar radiation. The goals of this investigation fall into four broad areas: 1) the measurement of the profile of solar heating to support an improved understanding of the thermal balance of Titan and the role of the greenhouse effect in maintaining Titan's temperature structure; 2) the measurement of the size, vertical distribution, and optical properties of the aerosol and cloud particles in Titan's atmosphere to support studies of the origin, chemistry, life cycles, and role in the radiation balance of Titan played by these particles; 3) the composition of the atmosphere, particularly the vertical profile of the mixing ratio of methane, a condensable constituent in Titan's atmosphere; and 4) the physical state, composition, topography, and physical processes at work in determining the nature of the surface of Titan and its interaction with Titan's atmosphere. In order to accomplish these objectives, the Descent Imager/Spectral Radiometer (DISR) instrument makes extensive use of fiber optics to bring the light from several different sets of foreoptics to a silicon CCD detector, to a pair of InGaAs linear array detectors, and to three silicon photometers. Together these detectors permit DISR to make panoramic images of the clouds and surface of Titan, to measure the spectrum of upward and downward streaming sunlight from 350 to 1700 nm at a resolving power of about 200, to measure the reflection spectrum of >= 3000 locations on the surface, to measure the brightness and polarization of the solar aureole between 4 and 30 degrees from the sun at 500 and 935 nm, to separate the direct and diffuse downward solar flux at each wavelength measured, and to measure the continuous reflection spectrum of the ground between 850 and 1600 nm using an onboard lamp in the last 100 m of the descent.© (1996) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

An imaging photopolarimeter aboard Pioneer 11, including a 2.5-centimeter telescope, was used for 2 weeks continuously in August and September 1979 for imaging, photometry, and polarimetry observations of Saturn, its rings, and Titan. A new ring of optical depth2 x 10(-3) was discovered at 2.33 Saturn radii and is provisionally named the F ring; it is separated from the A ring by the provisionally named Pioneer division. A division between the B and C rings, a gap near the center of the Cassini division, and detail in the A, B, and C rings have been seen; the nomenclature of divisions and gaps is redefined. The width of the Encke gap is 876 +/- 35 kilometers. The intensity profile and colors are given for the light transmitted by the rings. A mean particle size less, similar 15 meters is indicated; this estimate is model-dependent. The D ring was not seen in any viewing geometry and its existence is doubtful. A satellite, 1979 S 1, was found at 2.53 +/- 0.01 Saturn radii; the same object was observed approximately 16 hours later by other experiments on Pioneer 11. The equatorial radius of Saturn is 60,000 +/- 500 kilometers, and the ratio of the polar to the equatorial radius is 0.912 +/- 0.006. A sample of polarimetric data is compared with models of the vertical structure of Saturn's atmosphere. The variation of the polarization from the center of the disk to the limb in blue light at 88 degrees phase indicates that the density of cloud particles decreases as a function of altitude with a scale height about one-fourth that of the gas. The pressure level at which an optical depth of 1 is reached in the clouds depends on the single-scattering polarizing properties of the clouds; a value similar to that found for the Jovian clouds yields an optical depth of 1 at about 750 millibars.

Pioneer 11 measurements of Titan's limb darkening and polarization at red and blue wavelengths are refined, and the integrated disk brightness measurements at phase angles from 22 to 96 deg, over which Titan's phase coefficient averages about 0.014 magnitudes/deg in both colors, are reduced. Comparisons of the data with vertically homogeneous multiple scattering models indicate that the single-scattering phase functions of the aerosols in both colors are flat at scattering angles between 80 and 150 deg, with a small peak at larger scattering angles. Although a vertically homogeneous model in which particles are assumed to scatter as spheres cannot simultaneously match the polarization observations of both colors for any refractive index, observed polarizations are most sensitive to the particle properties near optical depth 1/2 in each color. Models based on single scattering by spheres can therefore be successful over a range of refractive indices, if the size of the particles increases with depth and if the cross section of the particles increases sufficiently rapidly with decreasing wavelength.

Spectroscopic observations of H2 in specific longitude regions of Jupiter as they rotate from limb to limb are reported. Data obtained in the 3-0 S(0) and S(1) lines using a CCD detector and a spectrograph with either echelle or plane gratings at the Cassegrain focus of the 24-inch telescope at Whipple Observatory during April-June 1983 are presented in extensive tables and graphs and analyzed in detail, modeling spatial and temporal variations at seven latitudes. An east-to-west increase in the equivalent line widths is attributed to the combined action of internal and solar heating of a convective layer, resulting in diurnal changes in the vertical cloud structure. It is inferred that the hydrogen observed is mainly in an equilibrium thermodynamic state, with small amounts of nonequilibrium hydrogen at high altitudes.

A line at 1280 A, due to Raman scattering of solar Lyman alpha (Ly-alpha) in the atmosphere of Uranus, has been detected by the Voyager Ultraviolet Spectrometer. The measured intensity of 40 + or - 20 R implies that 200 R to 500 R of the measured 1500 R Ly-alpha intensity at the subsolar point is due to Rayleigh scattering of the solar line. The presence of Rayleigh and Raman scattering at 1216 A suggests that the Uranian atmosphere is largely devoid of absorbing hydrocarbons above the 0.5 mbar level. The most natural explanation of this depletion is very weak vertical mixing equivalent to an eddy coefficient on the order of 200 sq cm/sec between 0.5 mbar and 100 mbar.

We have used a number of models to analyze Voyager images of Uranus obtained at several high phase angles to derive physical and chemical properties of particulate matter present in the planet's lower stratosphere. These models include a multiple‐scattering algorithm for plane parallel atmospheres, a spherical atmosphere code for performing limb inversions, a microphysical model of aerosol formation, growth, and sedimentation, and a photochemical model of methane photolysis. We obtain definitive evidence for the presence of aerosols at pressure levels ranging from a few millibars to about 100 mbar. There are two possible sets of particle properties that can fit radiances observed close to but somewhat interior to the limb at several phase angles in four visible wavelength bands. The low‐density solution is characterized by particles having a modal radius and number density equal to 0.13 ± 0.02 µm and 2 ± 1 particles/cm³, respectively, at a pressure level of 44 mbar. The alternative, high‐density solution is characterized by particles having a modal radius that is 0.6–0.7 times that of the low‐density solution at the reference level and a density that is 2 orders of magnitude larger. Since the high‐density solution implies a mass production rate for the stratospheric aerosols that is much larger than those that can plausibly be supplied by photochemically produced gases that condense, whereas the low‐density solution does not, we favor the low‐density solution. Inversion of narrow‐angle, high‐resolution images of the limb provides a definition of a variable that provides a measure of the amount of aerosol scattering at high phase angles. The vertical profile of this variable shows a decrease of several orders of magnitude from pressure levels of tens to a few millibars. This decrease is due chiefly to the particle size of the aerosols becoming small compared to a wavelength. Above the base of the stratosphere the aerosol optical depth is approximately 0.01 in the mid‐visible. A major source for the stratospheric aerosols is the condensation of ethane, acetylene, and diacetylene gas species at pressure levels of approximately 14, 2.5, and 0.1 mbar, respectively. These gases are produced at much higher altitudes by solar UV photolysis of methane and diffuse to the lower stratosphere, where they condense. In addition, diacetylene is also produced photochemically within its condensation region. Condensation of locally produced diacetylene may represent a significant fraction of the total hydrocarbon condensation. Such a local source of condensation may be required by the inversions to the limb profiles, which indicate that at least half of the ice condensation occurs at altitudes above the 5‐mbar level. The hypothesis that the stratospheric particles are made of hydrocarbon ices is supported by the approximate agreement between the total ice condensation rate predicted by the methane photochemical model and the aerosol mass production rate derived for the low‐density solution of the Voyager data. The aerosol mass production rate derived from the Voyager data is equal to 2–15 × 10−17 g/cm²/s. Additional but weaker support for this hypothesis is provided by the Voyager radio occultation temperature profiles. It is suggested that solar UV radiation promotes solid state chemistry within the lower order hydrocarbon ices, resulting in the production of polymers capable of absorbing at visible wavelengths. Thus this altered material could play a key role in the planet's heat budget. Ethane, acetylene, and diacetylene ices evaporate at approximately the 600‐, 900‐, and 3000‐mbar levels of the upper troposphere. The polymeric material is expected to evaporate at pressures in excess of the evaporation level for diacetylene.

The Imaging Photopolarimeter (IPP) experiment aboard the Pioneer spacecraft measured the linear polarization of red and blue sunlight scattered from Saturn's atmosphere at phase angles from 9 to 150°. This paper presents the observations, discusses their reduction, and summarizes the reduced data. Detailed tables are given for a bright zone (7°S–11°S), a darker belt (15°S–17°S) and a north-south scan. In blue light the minimum polarization on the disk rises from near zero at small phase to a maximum of > 10% near 100° phase in the zone (> 20% in the belt) and decreases toward zero at larger phase, suggestive of Rayleigh scattering. In red light the polarization is small and positive (maximum electric vector perpendicular to scattering plane) at small and large phase, and negative (maximum electric vector parallel to scattering phase) at intermediate phase angles in both regions, suggesting dominance by relatively large cloud particles. In both colors the polarization at all latitudes increases steeply from the center of the map toward both limb and terminator at phase angles near 90°. The data in the belt and zone have been compared with multiple scattering models containing a single type of cloud particle with various single-scattering phase matrices and vertical distributions in Rayleigh scattering gas. Unless there is some minimum optical depth of positively polarizing material (such as the gas) above a negatively polarizing or nonpolarizing cloud, the steep increase in polarization toward the limb is not reproduced. If the gas optical depth above the cloud top is too great, the cloud particles must be extremely negatively polarizing to compensate—unlike aboratory measurements of ammonia crystals. Models in which the cloud top ( τ = 0.4 level) is located at a pressure level of 150 ± 50 mb in the zone and 270 ± 80 mb in the belt fit the blue data with a relatively nonpolarizing base cloud. These cloud-top locations are consistent with scattering models in methane absorption bands for a CH 4 /H 2 mixing ratio of 2.5 × 10 −3 . Assuming the single-scattering properties of the cloud particles are similar at other locations, the variation in cloud-top pressure has been derived for latitudes from 25°S to 55°N from the blue polarimetry. Near the equator, the cloud top rises to ∼150 mb, while at latitudes > 20° the cloud top falls to pressures as great as ∼400 mb. This variation in cloud height is also seen qualitatively in the methane band data, and the higher cloud top at equatorial latitudes coincides with the high-speed equatorial jet seen by Voyager. The steep increase in polarization toward the limb in red light requires an additional optical depth of ∼0.02 of small, highly polarizing aerosols (probably photochemically produced) above both the belt and zone clouds. If these aerosols have radii of ∼0.1 μm, they do not strongly affect the blue polarimetry, while they can provide an absorption optical depth of a few tenths at pressure levels of 70 mb or less as required by Voyager observations in the ultraviolet.

The imaging photopolarimeter aboard Pioneer 10 produced hundreds of red and blue images of Jupiter covering a wide range of phase angles and having good linearity and signal-to-noise characteristics. In this preliminary analysis the limb darkening across two of the red images (at phase angles of about 34 and 109 deg) in both a prominent dark belt and a bright zone are compared with multiple-scattering models. Of the simple models tried, the smallest deviations from the observations result for ones consisting of a thin absorbing layer above a semiinfinite atmosphere of particles scattering according to the Henyey-Greenstein phase function. The asymmetry parameter for the best fits to both the belt and the zone data is in the range g = 0 to 0.25, corresponding to particles small in comparison with the wavelength of red light. The phase integral derived from the models lies in the range of about 1.5 to 1.6, implying a substantial internal heat source for Jupiter.