1. Superconducting-insulating quantum phase transition associated with valence change in compressed perovskite bismuth-oxides
- Author
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Han, Jinyu, Zhu, Xiangde, Zhang, Jianfeng, Cai, Shu, Guo, Jing, Zhou, Yazhou, Zhao, Jinyu, Wang, Pengyu, Wang, Lihua, Wei, Xiangjun, Jiang, Sheng, Yang, Ke, Gong, Yu, Li, Yanchun, Li, Xiaodong, Cao, Lixin, Tian, Mingliang, Wu, Qi, Xiang, Tao, and Sun, Liling
- Subjects
Superconductivity (cond-mat.supr-con) ,Condensed Matter - Superconductivity ,FOS: Physical sciences - Abstract
Searching for a universal trend by the same tuning method in different high-temperature superconductors with a similar crystal structure is a common strategy to find clues for a better understanding of the superconducting mechanism in a unified way. It is known that the hole-doped bismuth-oxide Ba1-xKxBiO3 possesses a similar perovskite structure to that of the hole-doped copper-oxide (cuprate) superconductors but also holds a comparatively high superconducting transition temperature. In this study, we report the first observation of the pressure-induced quantum phase transition (QPT) from superconducting to insulating states in a series of Ba1-xKxBiO3 single-crystal samples. A similar QPT has also been observed recently in the compressed cuprate superconductors1. Significantly, we found that the QPT observed in Ba1-xKxBiO3 is intriguingly associated with the valence change of the Bi ions in the material. These results lead us to propose that the pressure-induced valence change from Bi3+ to Bi5+ destroys the hole-doping effect on stabilizing the conductivity and corresponding superconductivity. By comparing the high-pressure behaviors observed in these two kinds of oxides, we identified another prominent feature shared by them - the more the hole-doping concentration, the higher the critical pressure required for driving the QPT., Comment: 20 pages and 4 figures
- Published
- 2023
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