1. Multilayer Mo2N-Ag/SiNx films for demanding applications: Morphology, structure and temperature-cycling tribological properties
- Author
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Ju, Hongbo, Zhou, Rui, Luan, Jing, Yu, Lihua, Xu, Junhua, Zuo, Bin, Yang, Junfeng, Geng, Yaoxiang, Zhao, Lijun, Fernandes, Filipe, and Repositório Científico do Instituto Politécnico do Porto
- Subjects
Tribological properties ,Modulation period ,Mechanics of Materials ,Mechanical Engineering ,Temperature-cycling tribology ,General Materials Science ,Mo2N-Ag/SiNx multilayer films ,Magnetron sputtering - Abstract
Nowadays there is the need to avoid the excessive consumption of liquid lubricant oils, as they are harmful to the environment and hard to disposal. Self-lubricant films have been seen as the sustainable solution to achieve a long-term lubrication under high temperature-cycling conditions. In this manuscript, multilayer Mo2N-Ag/SiNx films with a fixed modulation ratio (thickness of Mo2N-Ag to SiNx) of 3:1, with changing modulation period (Λ, thickness of Mo2N-Ag and SiNx) from 8 to 200 nm were produced to achieve an effective balance between the lubricious phase diffusion control and the adequate formation of the low friction tribo-layers. Results showed that a dual-phase of fcc-Mo2N and fcc-Ag co-existed in Mo2N-Ag layers, while the SiNx layer exhibited an amorphous character. Both room temperature (RT) lubricant and wear-resistance properties of the films were improved by increasing Λ from 8 to 64 nm, while a further increase of Λ degraded the wear-resistance properties. The multilayer film at Λ = 64 nm exhibited an excellent RT-500 °C temperature-cycling tribological properties. Mechanical properties and the synergistic effect of both modulation layers were the cause for the improvement of the tribological properties., Supported by the National Natural Science Foundation of China, China (51801081, 52071159, 52171071, 52172090); Portugal National Funds through FCT project, Portugal (2021.04115); Outstanding University Young Teachers of ‘‘Qing Lan Project” of Jiangsu Province, China; Excellent Talents of ‘‘Shenlan Project” of Jiangsu University of Science and Technology, China; China Merchants Marine Scientific Research and Innovation Fund, China. Filipe Fernandes acknowledges the funding received in the aim of the projects: MCTool21 - ref. ‘‘POCI-01-0247- FEDER-045940”, CEMMPRE – ref. ‘‘UIDB/00285/2020” and SMARTLUB – ref. ‘‘POCI- 01-0145-FEDER-031807”.
- Published
- 2022