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Fluid flow through fractured rock systems is governed in large part by the distribution, interconnectivity, and size of fracture apertures. In-situ stress is one of the primary factors controlling fracture aperture, and one that is altered significantly during high-pressure fluid injections or extractions. Interactions between stress, pore pressure, aperture, and fluid flow can result in complex and evolving poroelastic behavior with significant implications regarding the predictability and risk involved with developing and managing deep subsurface reservoirs (geothermal, fossil energy, and geologic carbon sequestration). In saturated rocks, bulk electrical conductivity is sensitive to both primary and secondary porosity (i.e., matrix porosity and fractures), and therefore to fracture aperture size and distribution. We demonstrate the use of time-lapse 3D electrical resistivity tomography for remotely monitoring stress induced changes in aperture distribution during high pressure injections into a dense fractured rock system at a scale of tens of meters. Results reveal a complex and continuously evolving stress field involving aperture dilations in the natural fracture system and aperture contractions in adjacent zones of shadow stress. Results provide information about the spatiotemporal changes in the system behavior and point to the potential of electrical imaging for autonomously and remotely monitoring evolving stress conditions by proxy through changes in bulk electrical conductivity.

The final version of the above article was posted prematurely on 16 July 2021, owing to a technical error. The final, corrected version of record will be made fully available at a later date.

The EGS Collab project, supported by the US Department of Energy, is addressing challenges in implementing enhanced geothermal systems (EGS). This includes improving understanding of the stimulation of crystalline rock to create appropriate flow pathways, and the ability to effectively simulate both the stimulation and the flow and transport processes in the resulting fracture network. The project is performing intensively monitored rock stimulation and flow tests at the 10-m scale in an underground research laboratory. Data and observations from the field test are compared to simulations to understand processes and to build confidence in numerical modeling of the processes. In Experiment 1, we examined hydraulic fracturing an underground test bed at the Sanford Underground Research Facility (SURF) in Lead, South Dakota, at a depth of approximately 1.5 km. We drilled eight sub-horizontal boreholes in a well-characterized phyllite. Six of the boreholes were instrumented with many sensor types to allow careful monitoring of stimulation events and flow tests, and the other two boreholes were used for water injection and production. We performed a number of stimulations and flow tests in the testbed. Our monitoring systems allowed detailed observations and collection of numerous data sets of processes occurring during stimulation and during dynamic flow tests. Long-term ambient temperature and chilled water flow tests were performed in addition to many tracer tests to examine system behavior. Data were rapidly analyzed, allowing adaptive control of the tests. Numerical simulation was used to answer key experimental design questions, to forecast fracture propagation trajectories and extents, and to analyze and evaluate results. Many simulations were performed in near-real-time in conjunction with the field experiments, with more detailed process study simulations performed on a longer timeframe. Experiment 2 will examine hydraulic shearing in a test bed being built at the SURF at a depth of about 1.25 km in amphibolite under a different set of stress and fracture conditions than Experiment 1. Five sets of fracture orientations were considered in design, and three orientations seem to be consistently observed.

Enhanced Geothermal Systems could provide a substantial contribution to the global energy demand if their implementation could overcome inherent challenges. Examples are insufficient created permeability, early thermal breakthrough, and unacceptable induced seismicity. Here we report on the seismic response of a mesoscale hydraulic fracturing experiment performed at 1.5-km depth at the Sanford Underground Research Facility. We have measured the seismic activity by utilizing a 100-kHz, continuous seismic monitoring system deployed in six 60-m length monitoring boreholes surrounding the experimental domain in 3-D. The achieved location uncertainty was on the order of 1m and limited by the signal-to-noise ratio of detected events. These uncertainties were corroborated by detections of fracture intersections at the monitoring boreholes. Three intervals of the dedicated injection borehole were hydraulically stimulated by water injection at pressures up to 33MPa and flow rates up to 5L/min. We located 1,933 seismic events during several injection periods. The recorded seismicity delineates a complex fracture network comprised of multistrand hydraulic fractures and shear-reactivated, preexisting planes of weakness that grew unilaterally from the point of initiation. We find that heterogeneity of stress dictates the seismic outcome of hydraulic stimulations, even when relying on theoretically well-behaved hydraulic fractures. Once hydraulic fractures intersected boreholes, the boreholes acted as a pressure relief and fracture propagation ceased. In order to create an efficient subsurface heat exchanger, production boreholes should not be drilled before the end of hydraulic stimulations.

We investigate the influence of foliation orientation and fine-scale folding on the static and dynamic elastic properties and unconfined strength of the Poorman schist. Measurements from triaxial and uniaxial laboratory experiments reveal a significant amount of variability in the static and dynamic Young’s modulus depending on the sample orientation relative to the foliation plane. Dynamic P-wave modulus and S-wave modulus are stiffer in the direction parallel to the foliation plane as expected for transversely isotropic mediums with average Thomsen parameters values 0.133 and 0.119 for epsilon and gamma, respectively. Static Young’s modulus varies significantly between 21 and 117 GPa, and a peculiar trend is observed where some foliated sample groups show an anomalous decrease in the static Young’s modulus when the symmetry axis (x3-axis) is oriented obliquely to the direction of loading. Utilizing stress and strain relationships for transversely isotropic medium, we derive the analytical expression for Young’s modulus as a function of the elastic moduli E1, E3, ν31, and G13 and sample orientation to fit the static Young’s modulus measurements. Regression of the equation to the Young’s modulus data reveals that the decrease in static Young’s modulus at oblique symmetry axis orientations is directly influenced by a low shear modulus, G13, which we attribute to shear sliding along foliation planes during static deformation that occurs as soon as the foliation is subject to shear stress. We argue that such difference between dynamic and static anisotropy is a characteristic of near-zero porosity anisotropic rocks. The uniaxial compressive strength also shows significant variability ranging from 21.9 to 194.6MPa across the five sample locations and is the lowest when the symmetry axis is oriented 45° or 60° from the direction of loading, also a result of shear sliding along foliation planes during static deformation.

Copyright 2019 ARMA, American Rock Mechanics Association. The EGS (Enhanced Geothermal Systems) Collab project is performing stimulation and flow experiments in highly-monitored and well-characterized intermediate-scale (approximately10 to 20 meter) field test beds at a depth of approximately 1,500 meters in the Sanford Underground Research Facility (SURF) in the Black Hills of South Dakota. Our fracture stimulation and interwell flow tests are performed to better understand processes that control formation of effective subsurface heat exchangers that are critical to the development and success of EGS. Different EGS Collab stimulations will be performed under dissimilar stress conditions to produce data for model comparisons that better differentiate stimulation mechanisms and the evolution of permeability enhancement in crystalline rock. EGS Collab experiments provide a means of testing tools, concepts, and strategies that could later be employed under geothermal reservoir conditions at DOE’s Frontier Observatory for Research in Geothermal Energy (FORGE) and other enhanced geothermal systems. Key to the project is using numerical simulations in the experiment design and interpretation of

The sediment record from Lake Victoria is an important archive of regional environmental and climatic conditions, reaching back more than 15,000 cal. years before present (15 ka BP). As the largest lake by area in East Africa, its evolution is key to understanding regional palaeohydrological change during the late Pleistocene and Holocene, including controls on the Nile River flow. As well as important palaeoenvironmental proxies, the lake contains a unique record of explosive volcanism from the central Kenyan Rift, in the form of fine-grained volcanic ash (tephra) layers, interpreted as airfall deposits. In the V95-1P core, collected from the central northern basin of the lake, tephra layers vary in concentration from 10s to 10s of 1000s of glass shards per gram of sediment. None of the tephra are visible to the naked eye, and have only been revealed through careful laboratory processing. Compositional analyses of tephra glass shards has allowed the tephra layers to be correlated to previously unrecognized eruptions of Eburru volcano around 1.2 and 3.8 ka, and Olkaria volcano, prior to 15 ka. These volcanoes lie ~300 km east of the core site in the Kenyan Rift. Our results highlight the potential for developing cryptotephra analysis as a key tool in East African palaeolimnological research. Tephra layers offer opportunities for precise correlation of palaeoenvironmental sequences, as well as windows into the eruption frequency of regional volcanoes and the dispersal of volcanic ash.

Tephrochronology is a widely applied method recognized for its exceptional precision in geologic dating and stratigraphic correlation. Tephra from the ~7.6 kyr B.P. Mount Mazama caldera-forming (”climactic”) eruption have been widely identified and applied as stratigraphic isochrons sediments of northwestern North America, as well as in the Greenland ice core records. Recent findings of a microscopic tephra accumulation, or cryptotephra, from Mazama in Newfoundland indicated that this horizon should also be found in Lake Superior sediments. We present findings that confirm the presence of Mazama ash in two sediment cores from the Lake Superior basin, which indicates its likely presence in the rest of the Laurentian Great Lakes and in deposits throughout much of eastern North America and beyond. The ubiquity of this stratigraphic horizon should be applicable to a higher resolution evaluation of climatological, ecological, and archaeological events during the early- to mid-Holocene thermal maximum throughout much of North America.

© 2017 by The Society of Exploration Geophysicists. Fracture systems are important pathways for fluid and solute transport and exert a critical influence on the hydraulic properties of aquifers and reservoirs. Therefore, detailed knowledge of fracture locations, connections, and evolution is crucial for both groundwater and energy applications (e.g., enhanced geothermal, oil and gas recovery, carbon sequestration, and wastewater injection). The innovative combination of distributed acoustic sensing (DAS) and ambient seismic noise techniques has the potential to detect and characterize fracture systems at high-spatial and temporal resolution without an active source. To test this, we conducted a multiphysics field experiment at Blue Canyon Dome, New Mexico. A novel energetic material developed by Sandia National Laboratories was used to generate fractures in two separate stimulations. Ambient noise was recorded before and after each stimulation using fiber-optic cables installed in the outer annulus of four boreholes surrounding the stimulation hole at a radius of 1.2 m. The Python package MSNoise was used to compute crosscorrelations and measure changes in velocity between each time period relative to the initial (prestimulation) time period. The majority of channel pairs showed a velocity reduction (average â'3% relative velocity change) following both stimulations. We used a 3D Bayesian tomography approach to resolve spatial variations by utilizing differences between channel pairs. Results showed that the greatest velocity reduction was concentrated near the center of the test area and suggested the presence of a near-vertical fracture, oriented northeast to southwest for depths >19 m below ground surface and extending slightly to the southwest corner. These results were generally consistent with crosshole seismic tomography time-lapse images. DAS technology provides valuable sensing capability and-when used with a passive seismic approach-shows great promise for monitoring and characterization of fractured-rock systems.

Heteroaromatic nitriles are important compounds in drug discovery, both for their prevalence in the clinic and due to the diverse range of transformations they can undergo. As such, efficient and reliable methods to access them have the potential for far‐reaching impact across synthetic chemistry and the biomedical sciences. Herein, we report an approach to heteroaromatic C−H cyanation through triflic anhydride activation, nucleophilic addition of cyanide, followed by elimination of trifluoromethanesulfinate to regenerate the cyanated heteroaromatic ring. This one‐pot protocol is simple to perform, is applicable to a broad range of decorated 6‐ring N‐containing heterocycles, and has been shown to be suitable for late‐stage functionalization of complex drug‐like architectures.