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All-cellulose composites (ACCs) are manufactured using only cellulose as a raw material. Biobased materials are more sustainable alternatives to the petroleum-based composites that are used in many technical and life-science applications. In this study, an aquatic NaOH-urea solvent system was used to produce sustainable ACCs from wood-based woven textiles with and without the addition of TEMPO-oxidized nanocellulose (at 1 wt.-%). This study investigated the effects of dissolution time, temperature during hot press, and the addition of TEMPO-oxidized nanocellulose on the mechanical and thermal properties of the composites. The results showed a significant change in the tensile properties of the layered textile composite at dissolution times of 30 s and 1 min, while ACC elongation was the highest after 2 and 5 min. Changes in hot press temperature from 70 °C to 150 °C had a significant effect: with an increase in hot press temperature, the tensile strength increased and the elongation at break decreased. Incorporating TEMPO-oxidized nanocellulose into the interface of textile layers before partial dissolution improved tensile strength and, even more markedly, the elongation at break. According to thermal analyses, textile-based ACCs have a higher storage modulus (0.6 GPa) and thermal stabilization than ACCs with nanocellulose additives. This study highlights the important roles of process conditions and raw material characteristics on the structure and properties of ACCs.

Low density and poor mechanical performance often limit utilisation of sawn wood from fast-growing plantation forests. Thermo-hygro-mechanical modification (THM) of timber is one innovation for improving the properties of light-weight wood species. The objective of this study was to determine the effects of THM and subsequent thermal treatment on dry density, modulus of elasticity (MOE), compression strength, Brinell hardness, and swelling behaviour in immersion tests on two fast-growing Vietnamese species, acacia (Acacia mangium) and rubberwood (Hevea brasiliensis). Test boards were modified in an industrial kiln, in which a tangential thickness compression of 14% and 12% were aimed for acacia and rubberwood, respectively, either with or without subsequent thermal treatment at 210 °C. Dry density, MOE, Brinell hardness, compression strength, and dimensional changes in water immersion tests of specimens were measured from the modified and unmodified reference materials, the latter ones being kiln dried at 50 °C. The results showed that the responses of the mechanical properties were more evident for rubberwood than for acacia. In rubberwood, the MOE and compression strength of wood thermo-hygro-mechanically modified with or without thermal treatment were higher than those of kiln-dried reference specimens throughout the thickness profile. In case of acacia, similar differences between the modified and reference specimens were observed only in the surface layer. Density and Brinell hardness of thermo-hygro-mechanically modified rubberwood were higher than those of reference specimens, but after thermal treatment they did not differ from (acacia) or were lower (rubberwood) than those of THM specimens. Post-compression thermal treatment increased the hydrophobicity of THM specimens.

This article explores wood-fiber-based fabrics containing Lyocell yarn in the warp and Spinnova–Lyocell (60%/40%) yarn in the weft, which are used to form unidirectional all-cellulose composites (ACC) through partial dilution in a NaOH–urea solution. The aim is to investigate the role of the yarn orientation in composites, which was conducted by measuring the tensile properties in both the 0° and 90° directions. As a reference, thermoplastic biocomposites were prepared from the same fabrics, with biobased polypropylene (PP) as the matrix. We also compared the mechanical and thermal properties of the ACC and PP biocomposites. The following experiments were carried out: tensile test, TGA, DSC, DMA, water absorption test and SEM. The study found no significant difference in tensile strength regarding the Spinnova–Lyocell orientation between ACC and PP biocomposites, while the composite tensile strength was clearly higher in the warp (Lyocell) direction for both composite variants. Elongation at break doubled in ACC in the Lyocell direction compared with the other samples. Thermal analysis showed that mass reduction started at a lower temperature for ACC, but the thermal stability was higher compared with the PP biocomposites. Maximum thermal degradation temperature was measured as being 352 °C for ACC and 466 °C for neat PP, and the PP biocomposites had two peaks in the same temperature range (340–474 °C) as ACC and neat PP combined. ACCs absorbed 93% of their own dry weight in water in just one hour, whereas the PP biocomposites BC2 and BC4 absorbed only 10% and 6%, respectively. The study highlights the different properties of ACC and PP reference biocomposites that could lead to further development and research of commercial applications for ACC.

The behaviour of industrially modified wood has not been systematically evaluated in controlled exposure conditions. The objective of this study was to assess the equilibrium moisture content (EMC), dimensions, and Brinell hardness of thermally modified wood in different conditions of temperature and relative humidity (RH). Tested materials consisted of European ash (Fraxinus excelsior L.), Norway spruce (Picea abies (L.) Karst.), and Scots pine (Pinus sylvestris L.) that were thermally modified according to ThermoWood industrial processes into the classes Thermo-S and Thermo-D. The properties were measured at the following conditions: 20 °C and 65% RH, 10 °C and 90% RH, and 30 °C and 30% RH. The results show that the reduction of EMC and the improvement in dimensional stability are dependent on the degree of thermal modification. Thermal modification was more resistant to moisture absorption at 20 °C and 65% RH than at 10 °C and 90% RH and 30 °C and 30% RH, and the more severe modification decreased the difference among different exposure conditions. The tangential–radial ratio of swelling and shrinkage was higher for thermally modified wood than for nonmodified wood. Brinell hardness of modified Scots pine and Norway spruce did not differ significantly from that of nonmodified wood in normal and dry conditions, but the more humid conditions increased the difference by 12%–17%.

Ways to long-term storage of carbon molecules captured as CO2 from atmosphere are looked for. Timber structures act as carbon storages and timber construction is sometimes claimed as a solution to ...

Thermally modified wood (TMW) is widely used in outdoor applications due to its advanced properties towards weathering stresses. Although the structure changes of TMW from weather factors have been reported, investigation of the quantitative analysis of water states and cell wall structure of TMW after weathering is limited. In this work, the amount of bound water, fiber saturation point (FSP), cell wall pores, and free water distribution of thermally modified Scots pine, Norway spruce, and European ash were measured before and after a 2-year natural weathering via NMR relaxometry, cryoporometry, and magnetic resonance imaging. The results show that weathering increased T2 relaxation time of lumens, indicating the degradation of tracheids and vessels, especially in TMW compared to unmodified wood. The amounts of bound water, FSP value, and cell wall pores were increased after weathering; however, an increase in thermal modification intensity resulted in lower FSP and limited the increase in number of pores. In summary, TMW showed better performance than unmodified wood after weathering.

The process of thermal modification can increase the dimensional stability and fungal resistance of wood, thus improving its performance in outdoor applications. This paper investigates the chemical and structural changes in thermally modified and unmodified Scots pine (Pinus sylvestris L.) and Norway spruce (Picea abies (L.) Karst.) wood caused by long-term soaking, with a focus on the dynamics of the timber surface properties. Fourier transform infrared spectroscopy, pH measurements and microscopy analysis were conducted in 2-week intervals for 14–20 weeks. The main chemical degradation of the wood, which was attributed to the changes in hemicelluloses and cellulose, was identified by the decreased carboxyl signal and the increased intensity of C–O stretching after soaking. The crystallinity and hygroscopicity of the wood were also affected by soaking. The pH level of the modified wood did not change markedly during soaking. However, the initially low pH values of the thermally modified wood, combined with the effect of water, probably facilitated the wood degradation processes, thus leading to an increased number of cracks and holes, especially in the outer parts of the cell walls.

In Siberian larch, shear strength (SS) is lower in sapwood (sW) than in mature heartwood (hW) despite the similarity of their cell structures. In sW, SS was not correlated with other properties, not even with density. The aim of the present study was to find the parameters affecting the SS in sW. The diameters of earlywood (EW) and latewood (LW) tracheid lumens [radial diameter (RD)], as well as their double wall thicknesses (2CWTs), were measured from different wood types. The 2CWT beside the resin canals was measured and rays were counted. The wall:lumen ratio of tracheids was calculated. None of the measured and calculated characteristics significantly correlated with SS in hW, while a high 2CWT and wall:lumen ratio of EW increased the SS and a large RD decreased the SS in sW. Tracheids of sW were larger and their walls were thicker than those of mature hW. The EW of sW sheared through tracheids, but practically never through rays, while in the EW of mature hW, both rays and tracheids could be sheared. It is suggested that change in viscoelastic properties, occurring in cell walls during the transformation from sW to hW, improves wood shear properties.

Air-coupled ultrasound and electrical impedance spectroscopy are non-destructive measurement methods, which can be used, for example for quality assessment of sawn timber. Both methods may be used in through-transmission and one-sided reflection mode to measure internal properties and detect defects in wood materials. The ultrasound method is based on mechanical waves and is mainly affected by the mechanical properties of wood. Density affects both methods, and the electrical impedance method is especially affected by moisture content and the chemical properties of wood. In this study, the relations between the methods and the bending properties of air dried and modified aspen (Populus tremula L.) specimens were examined. The modification method was a combination of compression and thermal modification. According to the study, electrical impedance spectroscopy combined with air-coupled ultrasound measured across the grain is a potential non-destructive technique for the strength estimation of aspen wood.

This paper investigates and models the effects of pruning season and tool on wound occlusion with varying tree and branch characteristics of silver birch (Betula pendula Roth) stems at the pruning height of 0−4 metres. Dates of eight secateurs prunings, three saw prunings and two sticks prunings as well as unpruned control were tested in permanent plots on four sites. Knot occlusion and discolouration in stemwood were measured from about 1600 studied knots of 112 sample trees felled five to six years after pruning in 2010. Knot occlusion rate was modelled according to pruning tool, date, tree growth, and branch characteristics. The occlusion was the fastest in trees pruned in spring or early summer, and the slowest in trees pruned in autumn. Stubs of living branches occluded faster than the dead ones with the same diameter. Saw pruning resulted in clearly better occlusion rates than secateurs pruning, caused by the shorter knot stubs after saw pruning. Hitting dead branches away with a stick resulted in the worst occlusion status. The colour defects spread more often upward from the knot than downward. Discolouration in stemwood was detected more frequently near to the pruned branches than the unpruned ones, and more widely near to the stubs of dead branches than the living ones. Most saw and secateurs pruned branches were completely occluded during the experiment, so these prunings were suitable for all branches under 20 mm in diameter, and for living branches even up to 30 mm in fast-growing trees.

Understanding the state of market for modified wood as well as the forces that affect its future development will be essential for those seeking to enter the Russian market. Information on modified wood from websites of companies, research and development organisations, woodworking-oriented magazines and forums, and official Russian statistics were explored, and finally verified by personal contacts with experts. A number of modification methods have been either researched, developed or pre-commercialised during the past 15 years, but only few of them have been adopted by users. Mostly, the modification methods have been copied, further developed and commercialised from variations of thermal modification originally introduced in Western Europe. Modified wood products are still considered premium goods among Russian consumers. Political initiatives aim at increasing the share of wood in construction and renovation but also at import minimisation, which reduces the penetration of foreign producers i...

In order to survive, the wood degrading microbes need a moisture content of wood exceeding the fibre saturation point, i.e. , 26%–32%, depending on the species. Maintaining wood moisture content below this level effectively prevents biodegradation. This can be achieved either by preventing wood's exposure to liquid water or increasing the hydrophobicity of wood by some impregnation or modification treatment. The objective of the study was to define the dimensional stability in changing environmental conditions, as well as the water absorption and desorption behaviour of untreated, copper-chromium impregnated and pine oil treated glulam. Scots pine was used for pressure impregnated and pine oil impregnated beams while the reference beams were made of Norway spruce, which is the most commonly used species for glulam production nowadays. The 6 inner lamellae of the glulam beams originated from small-sized logs, whereas the surface lamellae were made of larger logs. Beams with 44 × 200 mm cross cut dimensions were glued using melamine-urea-formaldehyde resin, and divided into three treatment groups. Treatment 1 was not impregnated (Norway spruce), treatment 2 (Scots pine) was impregnated with copper-chromium based preservative in commercial pressure impregnation process, and treatment 3 (Scots pine) was impregnated with pine oil using the process of Ekopine Ltd. After the treatments, 20 glulam specimens with dimensions of 44 × 200 × 170 mm (thickness–width–length) were produced from each treatment group. The cross-cut surfaces of the specimens were sealed using waterproof varnish to ensure that the water movement took place only through the side surfaces of the specimens. The air-dry specimens (MC 7.7–12.6%) were immersed into water for 6 weeks, during which period they were weighed repeatedly. After the immersion treatment, they were brought to a standard climate (65% RH, 20 °C temperature). Again, their mass was recorded until it did not change anymore. Then the same specimens were taken into a weather chamber where they were subjected to four 2-week-long test cycles with varying temperature and relative humidity, totalling 8 weeks of artificial weather exposure. Pine oil impregnated specimens resisted the water absorption significantly better than the untreated and pressure impregnated specimens. Due to the low initial MC after the absorption period, pine oil impregnated specimens also dried rapidly below 20% MC, while the drying of untreated and pressure impregnated glulam to the same level took 3–4 weeks in standard climate. The pine oil impregnated specimens had clearly better dimensional stability in the weather chamber, compared with the untreated and pressure impregnated specimens. Also the mass variation of pine oil impregnated specimens was significantly reduced in comparison to the other two treatment groups, indicating lower hygroscopicity for the pine oil treated specimens. To conclude, the pine oil impregnation of wood can be considered as an effective preservation method against moisture exposure. It appears to be a promising method to prevent biodegradation by maintaining the moisture content of wood below the level that enables mould and fungal growth.

Present in high concentrations in the heartwood of Larix species, water-soluble arabinogalactans affect the density, moisture content and processing properties of larch wood. The aim of this study was to chart arabinogalactan concentration (AC) and to define the relations between arabinogalactans, and density and shear strength at different axial and radial locations in Larix sibirica Ledeb. trunks. In addition, growth rate (ring width, fibre dimensions) was compared with AC to determine the link between them. Although quite low AC levels were observed, values differed significantly between sapwood and heartwood, with a slight increasing trend from pith to mature heartwood. Variation in growth rate affected AC levels in juvenile wood only. In conclusion, AC levels were clearly lower in the studied cultivated, fast-grown Siberian larches than those measured earlier in trees of natural origin. AC had a weak correlation with growth rate and shear strength.

The purpose of this study was to determine the effective refractive index of thermally modified Scots pine (Pinus sylvestris L.) wood specimens as a quantitative measure regarding the change of wood density which is due to the thermal modification. The refractive index of thermally modified Scots pine wood was obtained by introducing pine wood powder into an immersion liquid and measuring light backscattering with a homebuilt multifunction spectrophotometer. The present method provides useful information that in principle can be applied, for example, in the optimization of the thermal modification process and inspection of the quality of thermally modified wood.

Mechanical properties are very important in structural uses of wood. In the case of larch wood, shear strength (SS) may be a limiting property, because the wood is brittle and it splinters easily. In this study, SS of Siberian larch (Larix sibirica) wood was studied in relation to its axial and radial location and to some other wood properties in the part of the trunk that produces logs of good carpentry quality. SS increased by 21–23% from the pith to the outer heartwood at each studied height (butt, 4.5 and 9 m), and it was at its most approximately 7% higher at the butt than at the other studied heights. The main reason for the radial increase in SS was the increase in density caused by wood maturation, but other factors also affected SS, depending on the grouping mode (combined material, radial/axial location). An exception was sapwood, for which no factors affecting SS could be identified. Thus, sapwood may behave differently from heartwood regarding use, even unexpectedly. The results sugge...

Growing markets for chopped firewood have created alternative uses for the by-products of sawmills. Based on empirical data and simulated results, the potential of birch (Betula pendula Roth, Betula pubescens Ehrh.) from commercial thinnings for combined industrial production of sawn timber and firewood billets was investigated. In the simulations, different sawing patterns were used for logs intended to combine production of sawn timber and billets for chopped firewood (‘sawlogs’), and for logs intended only to firewood production (‘firewood logs’). Finally, economical feasibility analysis was done concerning the differences between the sawmills’ traditional business concept and the novel concept combining sawn wood and firewood production. The bucking results for the volume yield of different timber assortments varied only slightly between the different bucking options, i.e. the combinations of timber assortments. The main differences in the volumes of timber assortments were due to the stand t...

The Brinell hardness and equilibrium moisture content (EMC) were measured from thinning-aged silver birch wood. Wood material both from the trees harvested in the first commercial thinning and from trees remaining on site after the thinning was included. The average Brinell hardness was 19.40 MPa. It correlated significantly with the basic density of wood. With respect to the distance from the pith, the Brinell hardness of air-dried wood was higher than that of artificially dried wood. The average EMC of the conditioned (20°C, 65% relative humidity) wood was 12.0%. The EMC of the wood also varied, with the EMC being higher for air-dried wood than for kiln-dried wood. EMC was the highest at a distance of 30–40 mm from the pith, decreasing towards both pith and log surface. Seasonal variation in both the Brinell hardness and the EMC of the wood was found. It was presumed to be a consequence of season-dependent physiological changes in trees.

In the future, the building industries will need predictable, homogeneous and cost-competitive wood products with structural safety in increasing quantity and quality. This can be provided by, e.g., breaking solid wood and reconstructing the structure in a way that the degrading influence of knots, cracks, decay and other natural irregularities in wood will be eliminated. Beams, panels or boards made by this principle are called the engineered wood products (EWP). The purpose of this study was to investigate the possibilities to utilize small-diameter Scots pine and birch timber for production of EWPs that are reconstituted of strands. The wood technological characteristics of the tree species used in these products worldwide were studied based on the literature, and the findings were compared to the characteristics of domestic woods. In addition, test specimens were manufactured from domestic raw materials of Scots pine and birch species, and tested in order to examine the differences between wo...

The purpose of this study was to determine the modulus of elasticity (MOE) and the modulus of rupture (MOR) in the radial bending test for small, clear specimens of Finnish birch (Betula pendula Roth and B. pubescens Ehrh) wood originating from mature trees. The dependency of MOE and MOR on the specific gravity of birch wood was studied, and the relationship between MOE and MOR was modelled at the different heights and at the different distances from the pith of the tree. For B. pendula, the mean values for MOE and MOR were 14.5 GPa and 114 MPa, whereas B. pubescens had means of 13.2 GPa and 104 MPa, respectively. At the corresponding specific gravity, the bending stiffness and strength values did not differ between the two species. The results indicated a linear relationship between the MOE and MOR, irrespective of the birch species or the within-stem location. Both MOE and MOR increased clearly from the pith towards the surface of the tree and decreased slightly from the base to the top of the tree. It seems that if products with as high stiffness and bending strength as possible are wanted, sorting of raw materials into different grades according to their within-tree origin can be of value.

This article reports the impacts of three different drying treatments on selected physical and mechanical properties of European (Populus tremula L.) and hybrid (P. tremula × tremuloides) aspen wood. The material originates from 5 European aspen stands and 7 hybrid aspen stands in southern and central Finland. After processing the logs at a saw mill, sawn timber samples were dried using 1) conventional warm air drying, 2) press drying, or 3) heat treatment into Thermo-S grade by the Finnish Thermowood® method. Finally, small clearwood specimens were manufactured from different within-stem positions for the measurements of physical and mechanical properties. Both press dried and heat treated specimens absorbed water at significantly slower pace than the conventionally dried specimens. In normal climate, the conventionally dried, press dried and heat treated specimens conditioned at equilibrium moisture contents of 12.2, 8.7, and 8.9 per cent, respectively. It appears that the butt logs between 2–6 metres contain the lightest and, thus, weakest wood in aspen stems. Radial compression strength was at its highest in heat treated specimens, whereas conventionally and press dried specimens did not differ from each other. Press dried specimens had the highest longitudinal compression strength, also heat treated specimens showed higher values than the conventionally dried ones. Radial Brinell hardness of press dried specimens was higher than that of conventionally dried or heat treated specimens. Both modulus of elasticity and modulus of rupture were at their highest in press dried specimens. Irrespective of the drying treatment, the tangential shear strength of European aspen specimens was approximately 5% higher than that of hybrid aspen. Heat treated specimens indicated significantly lower tangential shear strength values than the conventionally dried ones. In case of both aspen species, the longitudinal tensile strengths of heat treated specimens were significantly lower than those of conventionally and press dried specimens. Heat treated specimens had the highest variability among the results. The inherent flaws in aspen wood material, e.g., wetwood and density fluctuations, increase especially the property variability of heat treated wood.

Seloste artikkelista: Influence of saw and secateur pruning on stem discolouration, wound cicatrisation and diameter growth of Betula pendula. Silva Fennica 42 (2008) : 2, s. 295-305.

The aim of this case study was to compare the impacts of saw and secateur pruning on silver birch (Betula pendula Roth). Data were collected from two saw pruned stands in 2005, and one secateur pruned stand in 2003. All the stands were located in southern Finland. The sample stems were felled, and their butt logs were sawn into flitches, whose knot features and colour defects were measured. In addition, discs were sawn from each stem in order to study the annual ring widths. In this material, pruning with secateurs appeared to cause less colour defects than pruning with a saw. Irrespective of the pruning method used, the colour defects in the stem wood were at their largest in cases where the basal knob or the stem bark appeared to be damaged by pruning. Colour defects spread mainly towards the pith, only in a few cases towards the stem surface. The cicatrisation time of the knots as well as the length of the bark stick remaining inside the stem did not show significant differences between the two pruning methods. Pruning of the lowest living branches appears to have no effect on the diameter growth of silver birch trees.

Tutkimuksen tavoitteena oli määrittää ohileikkaavilla oksasaksilla tehtävän rauduskoivun pystykarsinnan aiheuttamien väri- ja lahovikojen määrää ja analysoida esimerkkilaskelmin pystykarsintatyön kannattavuutta metsänomistajan ja koivutukkia käyttävän teollisuuden kannalta. Tutkimuksen aineistona käytettiin kolmea pystykarsittua metsikköä sekä kolmea näitä ominaisuuksiltaan vastaavaa pystykarsimatonta vertailumetsikköä Vammalasta, Jämsänkoskelta ja Keiteleeltä. Kannattavuutta tutkittiin empiirisen aineiston perusteella saatujen tulosten laskennallisena sovelluksena. Kannattavuuden tunnuslukuina olivat investoinnin nettonykyarvo ja sisäinen korkokanta. Mittaukset osoittivat aineistossa olleen vähemmän väri- ja lahovikoja kuin aiemmissa tutkimuksissa, joissa karsintavälineenä on käytetty oksasahaa. Alle 20 mm:n läpimittaisten oksien karsinnan aiheuttama värivikaantumisriski oli vähäinen. Rauduskoivun kasvu ei taannu elävienkään oksien karsinnan seurauksena, jos elävää latvusta säilytetään suositellut 50 % puun pituudesta. Pystykarsinta parantaa tyvitukkien laatua ja lisää esimerkkilaskelmien perusteella päätehakkuun kantorahatuloja. Ulkopuolisellakin työvoimalla tehdylle pystykarsintasijoitukselle voi saada 5–6 %:n sisäisen koron. Myös vaneri- ja viiluteollisuuden kannattaa maksaa keskimääräistä korkeampaa hintaa pystykarsituista koivikoista. Pystykarsinta lisää tyvitukeista saatavan viilun arvoa n. 20–30 prosentilla.