1. High-temperature corrosion behavior of selected thermally sprayed coatings in corrosive aggressive environment
- Author
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Zdeněk Česánek, František Lukáč, and Šárka Houdková
- Subjects
Materials science ,Polymers and Plastics ,Scanning electron microscope ,02 engineering and technology ,engineering.material ,01 natural sciences ,Cr3C2-25% NiCr ,odolnost proti korozi ,Corrosion ,Carbide ,Biomaterials ,hastelloy C-276 ,Coating ,thermally sprayed coating ,0103 physical sciences ,Nichrome ,Thermal spraying ,010302 applied physics ,corrosion resistance ,tepelně rozstřikovaný povlak ,High-temperature corrosion ,molten salts ,Metallurgy ,Metals and Alloys ,stellite 6 ,roztavené soli ,021001 nanoscience & nanotechnology ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Stellite ,engineering ,0210 nano-technology - Abstract
Cílem článku je zhodnotit a porovnat korozní odolnost povlaku Hastelloy C-276 s povlakem Stellite 6 a Cr3C2-NiCr, deponovaných technologií HP/HVOF. Koroze byla testována pomocí směsi agresivních solí 40%Na2SO4-60% V2O5, simulujících prostředí spalovacích kotlů. Bylo realizováno 50 cyklů při teplotě 750°C a následné schlazení na pokojovou teplotu po dobu 20 min.Zkorodované vzorky byly testovány pomocí elektronového mikroskopu, a EDS analýz. V porovnání s Cr3C2-NiCr, povlaky Hastelloy a Stellite poskytly lepší ochranu. Korozní mechanismus Hastelloy C-276 je založen na tvorbě ochranné oxidické vrstvy, která brání dalšímu prnikání korozního média. Povlak Stellite 6 korodoval pohranicích jednotlivých splatů, což vedlo k jejich postupnému odloupávání. V případě povlaku Cr3C2-NiCr byla korozně napadena matrice, což vedlo k postupnému uvolňování karbidů a destrukci povlaku. The aim of this paper is to evaluate and compare the corrosion resistance of Hastelloy C-276 coating with Stellite 6 and Cr3C2%-25% NiCr coatings. The coatings were deposited usingHP/HVOF(High Pressure/High Velocity Oxygen Fuel) thermal spraying technology. The corrosion test was conducted in the corrosive-aggressive environment of molten salts mixture in the composition of 40% Na2SO4–60%V2O5, simulating the corrosion environment of boilers for residual fuel oils. The corrosion test under cyclic conditions included 50 cycles at the temperature of 750 °Cand subsequent cooling at the room temperature for 20 min. The corroded specimens were analyzed using scanning electron microscope (SEM) and elemental analysis (EDS). In comparison with Cr3C2-25% NiCr coating, both Stellite 6 and Hastelloy C-276 coatings provided the substrate material with sufficient protection against high-temperature corrosion. The corrosion mechanism of Hastelloy C-276 coating was based on the formation of protective oxide layer which prevented further penetration of corrosive media. Stellite 6 coating exhibited the corrosion attack along splat boundaries resulting in spat delaminating into the build-up. The corrosion mechanism of Cr3C2-25% NiCr coating included the attack on NiCr matrix resulting in gradual separation of carbide phases into the corrosive environment.
- Published
- 2018
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