Search

This paper illustrates a land consumption map for Italy (year 2017) at a scale 1:1,300,000, and the assessment of its changes (2012–2017). We define land consumption as the replacement of a non-artificial land cover to an artificial land cover, both permanent and no-permanent. The maps are a 10 m spatial resolution raster, produced by photointerpretation of very high resolution images and semiautomatic classification of high resolution remote sensing images. An overall accuracy of 97.7% for the map of 2012 and of 99.66% for the map of 2017 was obtained. The results suggest that the method proposed is appropriate to detect land consumption, both for the urban densification and for the sprawling phenomena, from national to local level. Furthermore, because of the high spatial resolution and the classification scheme adopted, it is suitable for an effective monitoring system, compared to other existing classification systems or monitoring programs.

This paper illustrates a land consumption map for Italy (year 2017) at a scale 1:1,300,000, and the assessment of its changes (2012–2017). We define land consumption as the replacement of a non-artificial land cover to an artificial land cover, both permanent and no-permanent. The maps are a 10 m spatial resolution raster, produced by photointerpretation of very high resolution images and semiautomatic classification of high resolution remote sensing images. An overall accuracy of 97.7% for the map of 2012 and of 99.66% for the map of 2017 was obtained. The results suggest that the method proposed is appropriate to detect land consumption, both for the urban densification and for the sprawling phenomena, from national to local level. Furthermore, because of the high spatial resolution and the classification scheme adopted, it is suitable for an effective monitoring system, compared to other existing classification systems or monitoring programs.

Additional file 1.1H NMR spectra of HO2CC1MImCl (Figure S1) and HO2CC1MImNTf2 (Figure S3). 13 C NMR spectra of HO2CC1MImCl (Figure S2) and HO2CC1MImNTf2 (Figure S4). Thickness determination by SEM for CHT and CHT/BTA (Figure S5). ATR-FTIR spectra of CHT/BTA coating on bronze disk before and after 12 h of accelerated corrosion treatment (Figure S6).

Additional file 1.1H NMR spectra of HO2CC1MImCl (Figure S1) and HO2CC1MImNTf2 (Figure S3). 13 C NMR spectra of HO2CC1MImCl (Figure S2) and HO2CC1MImNTf2 (Figure S4). Thickness determination by SEM for CHT and CHT/BTA (Figure S5). ATR-FTIR spectra of CHT/BTA coating on bronze disk before and after 12 h of accelerated corrosion treatment (Figure S6).

The aim of this study was to develop smart materials with stimuli-responsive properties for the long-term protection of steel. The idea was to obtain a tailored and controlled release of protective agents in response to the environment stimuli. First, the protective efficacy of three inhibitors containing a carboxylic moiety, such as p-aminobenzoic (pAB), succinic (SA), and caffeic (CA) acids, was investigated in alkaline chloride solutions. The results revealed that pAB is the most effective protective agent, significantly better than SA and CA. It is surprising that the steel surface in the pAB solution remains unchanged even after 5 months of corrosion treatment, whereas the formation of degradation products in the SA and CA solutions was observed after only 6 days. Based on these findings, pAB was selected and used for the functionalization of silica nanoparticles and layered double hydroxides (LDHs) that can act as delivery vehicles and as an inhibitor reservoir. Specifically, pAB was chemisorbed on silica amino groups via an amide bond, and this makes possible a gradual inhibitor release induced by an alkaline environment. The intercalation of pAB in its anionic form into the LDHs structure is responsible for a completely different behavior since the release is induced by chloride ions and occurs by an anionic exchange reaction. Thus, these materials play a dual role by acting as an inhibitor reservoir and by capturing chlorides. These findings reveal that it is possible to create a reservoir of corrosion inhibitors gradually released on demand based on the chemical environment. The stimuli-responsive properties and the complementary protective action of inhibitor-loaded silica and LDHs make them attractive for the long-term protection of steel and open the way for innovative solutions in the preservation of concrete cultural heritage.

The photodegradation kinetics of 2‐mercaptobenzothiazole (MBT), a corrosion inhibitor for copper‐based alloys, is studied in high amorphous polyvinyl alcohol coatings subjected to either UV irradiation or indoor light exposure. The photodegradation process proceeds rapidly, thus compromising the anticorrosion ability of the coating. The encapsulation of MBT into layered double hydroxide (LDH) nanocarriers slows down its decomposition kinetics by a factor of three. Besides preserving the corrosion inhibitor, such a strategy allows a controlled release of MBT triggered by corrosion‐related stimuli, for example, presence of chloride species and acid pH. The developed coating guarantees long‐lasting corrosion protection even at low amounts of inhibitor‐loaded LDH nanocarriers (ca. 5 wt %). This also reflects in a high transparency, which makes the protective coating suitable for demanding applications, such as the conservation of high‐value metal works of art.

The attractive physicochemical properties of chitosan make its derived materials promising candidates for the reliable and sustainable corrosion protection of metallic substrates. In this work, chitosan-based coatings embedding different corrosion inhibitors, i.e. benzotriazole (BTA) and mercaptobenzothiazole (MBT), were investigated for the protection of copper-based alloys, with the aim to extend their application to the preservation of works of art exposed to indoor atmosphere. The composition of the formulations was optimized paying particular attention to their potential application in the field of cultural heritage. To assess the efficacy of the coatings, tailored accelerated corrosion tests were carried out on bare and coated bronze substrates. Coated and uncoated alloy disks were characterized before and after corrosion treatments by optical microscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy. Moreover, an image analysis protocol was defined to evaluate the extent of surface modifications after degradation treatments. The obtained results revealed that the chitosan-based coatings containing BTA and MBT fulfil the aesthetic criteria required in the field of cultural heritage and are able to inhibit the corrosion of bronze alloys. It is worth noting that a synergic effect between the chemical protection provided by the inhibitors and the physical one provided by the polymer matrix was observed. Our findings demonstrate that the developed systems are suitable for a reliable and more sustainable protection of indoor bronze artefacts, thus representing a promising alternative to commercial products and particularly taking advantage from the use of non-harmful solvents for their application and removal.