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1. Oxygen And Proton Reduction By Decamethylferrocene In Non-Aqueous Acidic Media

Author

Su, Bin, Hatay, Imren, Ge, Pei Yu, Mendez, Manuel, Corminboeuf, Clemence, Samec, Zdenek, Ersoz, Mustafa, and Girault, Hubert

Subjects
Oxygen reduction
Abstract

Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH(+), as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.

Published
2010

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