1. Characterization of Value-Added Non-Carbohydrate Compounds Solubilized during Acidic Hot Water Flowthrough Pretreatment of Poplar Wood
- Author
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Cuiying Hu, Xiao Zhou, Lishi Yan, Quan Bu, Liangzhi Li, Ruoshui Ma, and Yiwen Xu
- Subjects
0106 biological sciences ,Environmental Engineering ,Chromatography ,Chemistry ,Depolymerization ,lcsh:Biotechnology ,Vanillin ,Bioengineering ,Hot water ,Flowthrough ,Non-carbohydrate ,Lignin ,Reaction parameter ,010501 environmental sciences ,01 natural sciences ,Syringaldehyde ,Catalysis ,chemistry.chemical_compound ,lcsh:TP248.13-248.65 ,010608 biotechnology ,Selectivity ,Sugar ,Waste Management and Disposal ,0105 earth and related environmental sciences ,Coniferyl alcohol - Abstract
Acidic hot water flowthrough pretreatment (AHWF) is an attractive approach primarily because of its high efficiency for sugar recovery. However, a significant portion of carbon content in the solubilized fractions from lignin depolymerization and monosugar degradation has been studied to a lesser degree. Herein, we investigated the solubilized non-carbohydrate products from a series of flowthrough pretreatments of poplar wood by water-only or very dilute acid (0.05% to 0.1% w/w, H2SO4) at different temperatures (220 to 280 °C) and flow rates (10 to 62.5 mL/min). Results revealed that tailoring reaction parameters (temperature) and operational parameters of reactor (flow rate) without adding expensive catalysts can selectively produce specific non-carbohydrate compounds. Up to 50.9% selectivity of vanillin and 45.0% selectivity of syringaldehyde were obtained at 240 °C for water-only treatment with flow rates of 25 mL/min and 62.5 mL/min, respectively. Lower temperature (e.g., 220 °C) was favorable for the formation of coniferyl alcohol, with the highest selectivity of 36.2%. Higher temperature (e.g., 280 °C) or lower flow rate (e.g., 10 mL/min) led to the formation of varied other aromatic compounds and HMF. Adding very dilute acid (0.05% to 0.1% w/w, H2SO4) into the water-only system considerably enhanced the formation of HMF with up to 66.7% selectivity.
- Published
- 2016
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