1. Features of styrene copolymerization with sodium p-styrenesulfonate in solvents of different polarities
- Author
-
V. P. Zubov, M. G. D’yakova, V. A. Tverskoy, E. V. Prokhorova, and N. V. Shevlyakova
- Subjects
Polymers and Plastics ,Polarity (physics) ,Solvation ,Styrene ,Solvent ,chemistry.chemical_compound ,Monomer ,chemistry ,Polymer chemistry ,Materials Chemistry ,Ceramics and Composites ,Copolymer ,Polystyrene ,Dissolution - Abstract
The copolymerization of sodium p-styrenesulfonate with styrene is studied in solvents that form homogeneous solutions with mixtures of these monomers and differ in polarity: DMFA, a mixture of 1,4-dioxane with DMF, DMSO, and a DMSO-water mixture. It is shown that the diagrams of the copolymer composition depend on the type of solvent and that their shapes do not obey the Mayo-Lewis model. The copolymers become substantially enriched with styrene units during an increase in the solvent polarity. The main cause of deviation from the classical scheme of binary copolymerization is the selective solvation of growing macroradicals with styrene. This effect becomes more pronounced during an increase in the solvent polarity and a decrease in its dissolving ability with respect to polystyrene and during polymer separation into a heterophase. This conclusion is confirmed by the dependence of the copolymer composition on the initiator concentration.
- Published
- 2014