Search

In this work, we report on the fabrication of an hybrid material based on a porous silicon (PSi) layer infiltrated by an amino functionalized poly(e-caprolattone) (PCL-NH2). The organic–inorganic structure has been characterized by variable angle spectroscopic ellipsometry, optical reflectometry and water contact angle measurements. A polymer coated PSi layer, 3 μm thick, shows improved wettability and chemical stability against long lasting, up to 18 min, exposure to an alkaline environment. Even after basic treatment, the structure still retains a very good quality optical response, so that it may be proposed as a high performance platform for biochemical sensing applications.

Porous silicon based one-dimensional photonic crystals, such as Bragg mirror and optical microcavity, has been modified by infiltration of a new biocompatible polymer, an amino functionalized poly(e-caprolactone) (PCL-NH2), and characterized as optical biochemical sensors. The entrapped polymer adds strong chemical stability to the nanocrystalline matrix on exposure to alkaline solutions preserving the device sensing abilities in monitoring volatile substances and chemical compounds. On the basis of these results, these hybrid structures can be proposed as a high performance platform for biochemical applications.