A novel imaging mode, neutron dark field imaging, extends the capability of neutron imaging to enable one to measure the microstructure, that is length scales from the nm to µm. The dark field is a measure of the pair correlation function, which is linked to conventional small angle. Neutron dark field images of lithium-ion batteries provide spatially resolved measurements (with resolution ~100 µm) of the particle distribution along the path of the neutron beam. We applied neutron dark-field imaging to commercial lithium-ion batteries with different capacities, states of charge, and wear. The images probed length scales from 100 nm to 3 µm. We observed a uniform dark field signal across the fresh battery in both charge states which is contrasted with the worn batteries, which show clear inhomogeneities in the dark field signal, which indicates that the underlying electrode structures have changed in a non-uniform fashion.