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The ability to infer past temperatures from ice core records has in the past relied on the assumption that after precipitation, the stable water isotopic composition of the snow surface layer is not modified before being buried deeper into the snowpack and transformed into ice. However, in extremely dry environments, such as the East Antarctic plateau, the precipitation is so sparse that the surface is exposed to the atmosphere for significant time before burial. During that exposure, several processes have been recently identified as impacting the snow isotopic composition after snowfall: (1) exchanges with the atmosphere (i.e. sublimation/condensation cycles), (2) wind effects (i.e. redistribution and pumping) and (3) exchanges with the firn below (i.e. metamorphism and diffusion).Here we present the data over several seasons and years of the atmospheric water vapor and snow surface isotopic composition at Dome C, East Antarctica. To understand the link between these two elements, we investigate the moisture fluxes at the surface of the ice sheet, at the snow-air interface. No eddy-covariance measurements are available for the recent years, we therefore make use of the available primary meteorological parameters measured continuously on site to estimate the surface moisture fluxes using the bulk method. We estimate that the cumulative effect of the moisture fluxes is positive: about 12% of the mean annual accumulation is sublimated away. Alongside, we see an enrichment in d18O in the snow surface during the summer months, when most of the moisture fluxes are taking place. The snow d-excess is also affected and evolving in anti-phase with d18O. This indicates occurrence of fractionation during sublimation in line with previous field and laboratory studies. The moisture fluxes could be a key driver of changes in the snow isotopic composition between precipitation events influencing the climate signal stored in the isotopic record of ice cores.

The water isotope composition of snow precipitations, archived in the Antarctic ice sheet every year, is an important proxy of climatic conditions. This signal depends on several parameters such as local temperature, altitude, moisture source areas and air mass pathways.However, especially in areas where snow accumulation is very low (as on the East Antarctic Plateau), the isotopic composition is affected by additional spatial variability induced by the interactions between the atmosphere and snow surface, and the pristine signal may be modified through isotopic exchanges, sublimation processes and mechanical mixing originated from wind action.Here, we present the isotopic composition (δD and δ18O) and the second-order parameter d-excess of surface snow and snowpit samples collected during the Italian-French campaign in Antarctica (2019-2020). The sampling sites cover the area from Dumont D'Urville to Concordia Station and from Concordia Station towards the South Pole (EAIIST – East Antarctic International Ice Sheet Traverse). These data, compared with a previous dataset of Antarctic surface snow isotopic composition (Masson-Delmotte et al. 2008), are analyzed to determine the variability of the spatial relationship between precipitation isotopic composition and local temperature in relation to geographical parameters (latitude, distance from the coast and elevation). The interpretation of these factors determining the isotope signature is the base to better define the amount of the effects caused by subsequent interaction between atmosphere and surface snow, and by the wind action.Understanding the spatial variability of this proxy, which strongly decreases the signal-to-noise ratio, could permit to improve the use of the “isotopic thermometer” to quantify past changes in temperature based on the stable isotopic record of deep ice cores.

Thinning of the deep ice core layers must be considered when the water isotopic composition of the Oldest Ice Core is to be analyzed. From an experimental point of view, a novel instrument combining a micro-destructive cold femtosecond - Laser Ablation (LA) sampling system, that provides high spatial resolution together with minimal usage of ice sample, and a Cavity Ring Down Spectrometer is being built for high-quality water isotope measurements. Laser ablation results in crater formation and its morphology depends on the laser parameters used. Optical images that show crater morphology under different experimental conditions allow crater characterization towards an efficient cold LA sampling. An ablation chamber and a transfer line are both the connecting parts between the LA system and the CRDS instrument. They are to be designed and constructed in the optimal size and shape to collect the ablated mass and guarantee its smooth delivery to the CRDS analyzer with minimum disturbance. Coupling a Laser Ablation system with a CRDS analyzer has already been achieved using a laser operating at the nanosecond regime and a cryo-cell as the ablation chamber. Comparison of the two Laser Ablation systems, by the means of ice sampling and collection of the ablated material, will be of great importance to understand the ablation mechanism and post-ablation processes on ice and further develop a system dedicated to water isotope measurements.

Water isotope ratios of ice cores are a key source of information on past temperatures. Through fractionation within the hydrological cycle, temperature is imprinted in the water isotopic composition of snowfalls. However, this signal of climatic interest is modified after deposition when snow remains at the surface exposed to the atmosphere. Comparing time series of surface snow isotopic composition at Dome C with satellite observations of surface snow metamorphism, we found that long summer periods without precipitation favor surface snow metamorphism altering the surface snow isotopic composition. Using excess parameters (combining dD, d17O, and d18O fractions) allow the identification of this alteration caused by sublimation and condensation of surface hoar. The combined measurement of all three isotopic compositions could help identifying ice core sections influenced by snow metamorphism in sites with very low snow accumulation.

Sunlit snow is highly photochemically active and plays a key role in the exchange of gas phase species between the cryosphere and the atmosphere. Bromine (Br), Iodine (I) and Mercury (Hg) can be photoactivated by the UV radiation and, in certain circumstances, released from the snowpack into the atmosphere. Mercury is a heavy metal with a known toxicity present in the environment in several different chemical forms. Once present in the snowpack, Hg is very labile and, thanks to the UV light, it can be reduced back to elemental Hg (Hg(0)) and undergo dynamic exchange with the atmosphere. Similar to mercury, iodine can undergo photochemical activation in surface snow resulting in its presence in the surrounding atmosphere where it plays a crucial role in new particle formation. Bromine has a central role in the mercury cycle in polar regions (through the Atmospheric mercury depletion events) as well as contributing to the tropospheric ozone cycle in the polar region causing the so-called Ozone depletion events. However, compared to Iodine and Mercury, it seems to be more stable after deposition into the snow pack. Here we present measurements of bromine, iodine and mercury performed by ICP-MS, on snow pit and shallow core samples taken over a 2100 km traverse in East Antarctica from the coast to the interior (Talos Dome – Dome C traverse 2016 and East Antarctic International Ice Sheet Traverse, EAIIST 2019). The shallow core and the snow pit samples at each site are estimated to cover about 10 to 20 years of snow accumulation, giving us a deposition record from approximately the late 90s, to around the early 21st century. The concentrations determined in different sampling sites show a rather clear decrease trend from the coast with the minima as we approach the inner part of the Antarctic plateau. In addition, the analysis of surface and bulk samples from EAIIST show a decrease of concentrations toward the inland except for the sites characterised by a strong snow metamorphosis caused mainly by the wind friction. In almost all the sampling sites of the EAIIST traverse the concentrations of Br, I and Hg increase with sample depth, possibly due to snowpack photochemical activation in the upper part of the snowpack. Future studies are planned to investigate the possible link between the determined concentration profile and the variation of the solar radiation reaching the Antarctic Plateau during spring caused by the ozone hole formation.

The growth and decay of marine ice sheets act as important controls on regional and global climate and sea level. The Wilkes Subglacial Basin ice sheet appears to have undergone thinning and ice discharge events during recent decades, but its past dynamics are still under debate. The aim of our study is to investigate ice margin retreat of the Wilkes Subglacial Basin ice sheet during late Pleistocene interglacials with the help of new high-resolution records from the TALDICE ice core. Here we present a multiproxy approach associated with modelling sensitivity experiments.The novel high-resolution δ18O signal reveals that interglacial periods MIS 7.5 and 9.3 are characterized by a unique double-peak feature, previously observed for MIS 5.5 (Masson-Delmotte et al., 2011), that is not seen in other Antarctic ice cores. A comparison with our GRISLI modelling results indicates that the Talos Dome site has probably undergone elevation variations of 100-400 m during past interglacials, with a major ice thickness variation during MIS 9.3, likely connected to a relevant margin retreat of the Wilkes Subglacial Basin ice sheet. To validate this elevation change hypothesis, the modelling outputs are compared to the ice-rafted debris record (IBRD) and the neodymium isotope signal from the U1361A sediment core (Wilson et al., 2018), which show that during MIS 5.5 and especially MIS 9.3, the Wilkes Subglacial Basin ice sheet has been subjected to ice discharge events.Overall, our results indicate that the interglacial double-peak δ18O signal could reflect decreases in Talos Dome site elevation during the late stages of interglacials due to Wilkes Subglacial Basin retreat events. These changes coincided with warmer Southern Ocean temperatures and elevated global mean sea level, confirming the sensitivity of the Wilkes Subglacial Basin ice sheet to ocean warming and its potential role in sea-level change.

The EPICA Dome C (EDC) ice core has been drilled from 1996 to 2004. Its study revealed a unique 800 ka long continuous climatic record including 9 deglaciations. Ice cores contain numerous proxies in the ice and in the air trapped in bubbles (chronological constraints, greenhouse gases concentration, local temperature proxies, mid to low latitude climate proxies).Here, we focus on the link between the high and low latitudes during the glacial/interglacial transitions provided by the isotopic composition of water and oxygen archived in both ice and gas matrix. On one hand, the water isotopic composition brings information on past temperatures and water cycle re-organizations: dD records past temperature, whereas the combination of d18O with dD or d17O provide information on the past water cycle organization through d-excess and 17O-excess linked to climatic conditions of the evaporative regions. On the other hand, the elemental composition of oxygen expressed in the O2/N2 ratio provides key information for orbital dating over the last 800 ka in complement with the isotopic composition of atmospheric oxygen (d18O of O2 or d18Oatm) which is related as well to the low latitude water cycle.In this study, we present new high resolution records of water isotopes of many proxies (d18O, d-excess and 17O-excess) as well as high resolution measurements of O2/N2 and d18Oatm over the last 9 deglaciations on the EDC ice core. We detail the coherent low to mid-latitude orbital patterns obtained using our multiproxy approach with a focus on Termination II, Termination V and the 800 – 500 ka. deglaciations. We look at the similar patterns between terminations and between the different proxies presented.

We present a novel application of empirical methodologies that significantly reduce the chronological uncertainty of a low latitude-high altitude Alpine ice core record obtained in 2011 from the glacier Alto dell’Ortles (3859 m, Eastern Alps, Italy). A preliminary absolute timescale based on a peak in 3H activity, and 210Pb and 14C analyses on carbonaceous particles and organic remains provided evidence of one of the oldest Alpine ice core records spanning the last ~7000 years, back to the last Northern Hemisphere Climatic Optimum. Here we combine three empirical methods that provide an additional number of time markers that corroborate the multimillennial nature of the Alto dell’Ortles ice cores while significantly decreasing the uncertainty of the chronology. First, 14C analysis of an additional organic fragment (a charred spruce needle) discovered next to the basal ice provides an age (232 ± 126 BCE) which agrees with previous 14C dates in the oldest part of the record. Second, a new millennial-scale high resolution atmospheric Pb depositional record was used to synchronize the Alto dell’Ortles cores with an accurately-dated (±5 years) Pb record from an array of Arctic ice cores during the ~200 BCE to ~1900 CE time period. This match resulted in a shift of the initial Alto dell’Ortles timescale ~200 years earlier, but still within the initial time uncertainty. Third, novel seasonally resolved pollen records from the upper firn/ice portion of the Alto dell’Ortles cores were combined with δ18O and dust annual variations to refine the dating for the 20th century by means of an automatic algorithm (Straticounter; between 2011 and 1927 CE) and visual counting (1926–1900 CE). The time markers obtained by these three methods were combined in a continuous timescale by running a Montecarlo based fit (COPRA model). This Alto dell’Ortles revised chronology shows a significantly reduced uncertainty, between ±1 and ±4 years after 1927 CE, and between a maximum of ±100 years to a minimum of ±5 years between 1927 CE and 200 BCE by conservative estimates. An investigation of the revised chronology by means of a simple 1-D flow model suggests that non-steady-state conditions (e.g., changes in past snow accumulation rate) need to be considered to provide a full physical explanation of the age-depth relationship obtained. The new revised chronology will allow the constraint of the Holocene climatic and environmental histories emerging from this high-altitude glacial archive of Central Europe. The novel methodologies may also be adopted to build or improve the chronologies of other ice cores extracted from-low latitude/high-altitude glaciers that typically suffer from larger dating uncertainties compared with well dated polar records.

The response of the East Antarctic Ice Sheet to past intervals of oceanic and atmospheric warming is still not well constrained but critical for understanding both past and future sea-level change. Furthermore, the ice sheet in the Wilkes Subglacial Basin, which is characterized by a reverse-sloping bed, appears to have undergone thinning and ice discharge events during recent decades. By combining new glaciological evidence on ice sheet elevation from the TALDICE ice core with offshore sedimentological records and ice sheet modelling experiments, we reconstruct the ice dynamics in the Wilkes Subglacial Basin over the past 350,000 years. Our results indicate that the Wilkes Subglacial Basin experienced an extensive retreat 330,000 years ago and a more limited retreat 125,000 years ago. These changes coincided with warmer Southern Ocean temperatures and elevated global mean sea level during those interglacial periods, confirming the sensitivity of the Wilkes Subglacial Basin ice sheet to ocean warming and its potential role in sea-level change.

Environmental sustainability of viticulture is negatively affected by prolonged droughts. In limestone dominated regions, there is limited knowledge on grapevine water status and on methods for accurate evaluation of actual water demand, necessary to appropriately manage irrigation. During a dry vintage, we monitored plant and soil water relations in old and young vines of Istrian Malvasia on Karst red soil. The vineyard with young vines was additionally subdivided into two areas, based on their soil type, 1) karst silty-clay loam, and 2) mixture of crushed rocks and karst silty-clay loam (stony soil). Seasonal changes in exploited water resources were estimated via analysis of oxygen isotope composition (δ18O) of rainfall, deep soil water, and xylem sap. We hypothesized that plants are able to thrive during drought thanks to the water stored in deep soil layers, while they rely less on superficial soil horizons. Our results show that vines growing on karstic substrates have deep roots securing the use of stable water sources during summer, with consequent favourable plant water status. In fact, both young and mature vines approached the threshold of severe water stress, but never surpassed it, as midday leaf water potentials were >−1.3 MPa in all study sites. Vines roots showed flexible water uptake, i.e. the ability to absorb water from deep or shallow soil horizons during drought and after late-summer thunderstorms, which was particularly evident in vines growing on the stony soil. In fact, precipitations of 20 mm were enough for plant water status recovery, due to fast infiltration. On the other hand, at least 50 mm of rainfall were necessary to induce water status recovery in more compact soil (karst silty-clay loam). Our findings provide new knowledge on the rooting depth and water needs of vines growing on shallow soils overlying fractured limestone bedrock.

Processes on both synoptic scale and mesoscale contribute to variations in the atmospheric water vapor isotopic signal in the lower troposphere. The drivers of the isotopic composition of water vapor at these temporal scales is a key topic of discussion. The aim of this paper is to decouple mesoscale from synoptic processes that affect the water vapor isotopic composition over a coastal lagoon and to quantify the vertical mixing and sea breeze contributions to the daily water vapor cycle. We monitored the water vapor isotopic composition at the beginning of the 2017 spring season for 21 days, at the inland boundary of the Venetian Lagoon (Italy) with a commercially available cavity ring-down spectroscopy analyzer. Mean atmospheric pressure fields and back trajectories are used to investigate the long-range transport of water vapor to the study area. Moisture source areas and d-excess correlation maps show that the control on the d-excess parameter is dominated by the mesoscale contribution. The daily cycle of water vapor is studied in detail, showing that the intrusion of air from the free atmosphere represents the main process that occurs in the morning. Under those circumstances, the morning variability of the water vapor isotopic composition can be used as a proxy for the Planetary Boundary Layer height. The study period was characterized by a constant development of the sea breeze circulation that conserved the marine signature of water vapor until the afternoon. However, the water vapor isotopic signal tends to stabilize when atmospheric conditions such as high relative humidity and a weak gradient in the atmospheric pressure field occur, leading to the establishment of an isotopic equilibrium between the atmospheric water vapor and surface waters.

The EPICA Dome C (EDC) ice core has been drilled from 1996 to 2004. Its study revealed a unique 800 ka long continuous climatic record including 9 deglaciations. Ice cores contain numerous proxies in the ice and in the air trapped in bubbles (chronological constraints, greenhouse gases concentration, local temperature proxies, mid to low latitude climate proxies). Here, we focus on information provided by the isotopic (and elemental) composition of water and oxygen archived in both ice and gas matrix. On one hand, the water isotopic composition brings information on past temperatures and water cycle re-organizations: d18O or dD records past temperature, whereas the combination of d18O with dD or d17O provide information on the past water cycle organization through d-excess and 17O-excess linked to climatic conditions of the evaporative regions. On the other hand, the elemental composition of oxygen expressed in the O2/N2 ratio provides key information for orbital dating over the last 800 ka in complement with the isotopic composition of atmospheric oxygen (d18O of O2 or d18Oatm) which is related as well to the low latitude water cycle.In this study, we present new high resolution records of water isotopes (d18O, d-excess and 17O-excess) as well as high resolution measurements of O2/N2 and d18Oatm over the last 9 deglaciations on the EDC ice core. We first use the high resolution records of O2/N2 and d18Oatm to improve absolute dating constrain over the glacial terminations and discuss the link between orbital forcing and climate variations recorded in the EDC ice core. In a second part, we use d-excess, 17O-excess and d18Oatm to constrain the relative chronology of high vs low latitude climatic events at sub-millennial scale over past deglaciations.

The growth and decay of marine ice sheets act as important controls on regional and global climate, in particular, the behavior of the ice sheets is a key uncertainty in predicting sea-level rise during and beyond this century. The East Antarctic Ice Sheet (EAIS), which contains deep subglacial basins with reverse-sloping, is considered to be susceptible to ice loss caused by marine ice sheet instability. Sediment core offshore Wilkes Subglacial Basin reveals oscillations in the provenance of detrital sediment that have been interpreted to reflect an erosion of Wilkes Basin during interglacial periods MIS 5, MIS 7, and MIS 9 greater than Holocene period (Wilson et al., 2018). The aim of our study is to investigate past climate and environmental changes in the coastal area of the East Antarctic Ice Sheet during MIS 7.5 and 9.3 with the help of a new high-resolution water isotopes record of the TALDICE ice core.Here we present new δ18O and δD high resolution (5 cm) records covering the oldest portion of the TALDICE ice core. MIS 7.5 and 9.3 isotopic signal reveals a unique feature, already observed for MIS 5.5, that has not been spotted in other Antarctic ice cores (Masson-Delmotte et al., 2011). Interglacial periods at TALDICE are characterized by a first peak, observed in correspondence to the culmination of the deglaciation event as for all Antarctic cores, followed by a less pronounced isotopic peak (for MIS 5.5 and 9.3) or a plateau (for MIS 7.5) prior to the glacial inception. Several factors might drive this peculiar behavior of the water stable isotopes record, as an increase in temperatures due to a drop in surface elevation or changes in moisture sources.The new δ18O and δD high-resolution records for the TALDICE ice core reveal a unique pattern that characterizes interglacial periods at Talos Dome. Taking into account the coastal position of the core and its vicinity to the Wilkes Subglacial Basin we intend to investigate the possible decrease in surface elevation, through the application of the GRISLI ice sheet model (Quiquet et al., 2018), and changes in moisture sources, traceable from the d-excess record.

A comprehensive database of paleoclimate records is needed to place recent warming into the longer-term context of natural climate variability. We present a global compilation of quality-controlled, published, temperature-sensitive proxy records extending back 12,000 years through the Holocene. Data were compiled from 679 sites where time series cover at least 4000 years, are resolved at sub-millennial scale (median spacing of 400 years or finer) and have at least one age control point every 3000 years, with cut-off values slackened in data-sparse regions. The data derive from lake sediment (51%), marine sediment (31%), peat (11%), glacier ice (3%), and other natural archives. The database contains 1319 records, including 157 from the Southern Hemisphere. The multi-proxy database comprises paleotemperature time series based on ecological assemblages, as well as biophysical and geochemical indicators that reflect mean annual or seasonal temperatures, as encoded in the database. This database can be used to reconstruct the spatiotemporal evolution of Holocene temperature at global to regional scales, and is publicly available in Linked Paleo Data (LiPD) format., Measurement(s)climateTechnology Type(s)digital curationFactor Type(s)temporal interval • geographic location • proxy typeSample Characteristic - Environmentclimate systemSample Characteristic - LocationEarth (planet) Machine-accessible metadata file describing the reported data: https://www.ncdc.noaa.gov/paleo/study/27330

Stable water isotopes are widely-used tracers to investigate hydrological processes occurring in the atmosphere and to determine the geospatial origin of water, i.e. to acquire useful information about the hydrological cycles over catchment basins and to find the origin of water recharging rivers, aquifers, and springs. Mapping the isotopic composition of precipitation provides hydrological and climate information at regional and global scales. However, the isotopic composition of precipitation is usually analyzed at large scales with a limited spatial resolution. In Italy, a few studies mapped the oxygen stable isotopes using annually-averaged data, not accounting for the strong seasonality of the isotopic composition linked to climatic and weather factors. To partially fill this gap, the present study proposes a detailed analysis of more than 2250 isotope data (δ18O, δ2H, and deuterium excess) related to precipitations collected in the Friuli Venezia Giulia (FVG) region (Italy) with monthly or seasonal frequency in 36 sites between 1984 and 2015.The FVG region lies at the north-eastern end of Italy, bordering Austria in the North and Slovenia in the East, and extends over ~7.9·103 km2. From a hydrogeological point of view, FVG is an interesting case study. Large highly-permeable carbonate aquifers are present in the Alps and Prealps, while the southern part of the region is characterized by an alluvial plain, split by the spring belt into two sectors: the High Plain in the North, characterized by an highly-permeable unconfined aquifer, and the Low Plain in the South, characterized by a system of confined and artesian aquifers. All the aquifers are recharged by the effective precipitations which in the FVG exhibits among the highest annual precipitation rates in Italy (with peaks >3000 mm/year).For the present research, the isotopic data were used: (i) to analyze the spatial and seasonal variability of isotopic composition; (ii) to relate water isotopes with orography and weather parameters collected from meteorological stations as well as using ECMWF ERA5 reanalysis; (iii) to reconstruct the local meteoric water lines across the FVG at annual and seasonal bases; (iv) to quantify interannual trends and analyze their spatial distribution; and (iv) to model the spatial distribution of isotope content in precipitation and create annual and seasonal maps.

The iconic curve of D in water showing the 8 glacial/interglacial cycles from the EPICA Dome C icecore is now a reference in paleoclimate. It shows past temperature variability back to 800 ka over the3200 m deep ice core with a 55 cm resolution. However, the millennial and centennial scalevariability gets more challenging to observe in the deepest part of the core. Indeed, the timeresolution worsens when going deeper in the ice because of the ice thinning: it is larger than 200years at 2500 m depth. Furthermore, isotopic diffusion affects the signal at the bottom of the icecore. Pol et al., (2010) have thus shown that the sub-millennial MIS (Marine Isotopic Stage) 19 signal(3157-3181 m deep) is erased because of diffusion and high resolution doesn’t add any furtherinformation at this depth. In this study we want to better characterize the increase of the isotopicdiffusion with depth by providing new high resolution water isotopes at several intervals over theEPICA ice core (EDC).We present here published high resolution (11 cm) d18O measurements over the EDC ice core aswell as new records of high resolution (11 cm) D over MIS 7;13 and 14). We use spectral analyses todetermine at which depth the isotopic diffusion erases the sub-millennial variability. We also showthat cold periods exhibit a larger variability of water isotopes than interglacial periods.The information obtained here is crucial for the new project Beyond EPICA oldest ice core, which hasthe goal of analyzing a 1.5 Ma old ice core. In the deepest part, 1 m of ice core could represent10 000 years of climate archive.

The study of the deep portions of ice cores still represents a poorly explored field due to the presence of processes acting in the lowermost layers and possibly affecting the preservation of the original climatic signal. For the 1620 m TALDICE ice core, drilled at Talos Dome (East Antarctica), the high-resolution climate reconstruction and chronology definition are available only until the depth of ~1450 m (150 kyr BP) (Stenni et al., 2011, Bazin et al., 2013). Our aim is to investigate the portion below 1460 m depth to the bottom of the core, where radargrams show the presence of an unconformity in the ice sheet, to define a preliminary chronology and identify a discernible climatic signal.Here we present the new TALDICE δ18Oatm record in the air bubbles, in association with the new high-resolution δ18Oice and δDice profiles and an 81Kr radiometric date. New 46 measurements of δ18Oatm allowed to increase the resolution of the available profile from 1357 to 1553.95 m depth and to extend the record till the bottom of the core at 1617 m depth. The comparison between the δ18Oatm profile of TALDICE and the one of EPICA Dome C (EDC) ice core (Extier et al., 2018) allows to solidly define a preliminary age-depth relationship for the TALDICE core until 1500 m depth, where the gas age is estimated to be ~200 kyr BP. Below 1500 m, supplementary δ18Oatm measurements will be needed to identify older precession cycles and to extend the age-depth relationship further back in time. On the other hand, the high-resolution isotopic profiles in the ice (18O/16O and D/H ratios) obtained below the depth of 1528 m and compared with the EDC ones suggest that the climatic signal in the ice is preserved until to the lower level of 1547.8 m, which is dated back to 343 kyr BP. However, the lack of similarities with the EDC water isotopes record below this depth, in spite of the 81 Kr radiometric age 459 ± 50 kyr BP at the depth of 1574-1578 m, indicates the missing of the MIS 11 in the isotopic profiles. Moreover, the increase of high-frequency variability in the δ18Oice and δDice below 1547.8 m depth implies that this part of the core lays in an area of the ice sheet characterized by different properties in comparison to the ice above.Additional δ18Oatm, 40Ar, δ18Oice, and δDice measurements will be performed in the lowermost portion of the core and the results will be compared with the new 81Kr radiometric dating at the depth of 1560-1564 m and 1614-1619 m to better constrain the chronology and to investigate the ice properties in the deeper portion of the core.

Paleoclimate reconstructions from ice core records can be hampered due to the lack of a reliable chronology, especially when the stratigraphy is disturbed and conventional dating methods are not readily applied. The noble gas radioisotopes 81Kr and 39Ar can in these cases provide robust constraints as they yield absolute, radiometric ages. 81Kr (half-life 229 ka) covers the time span from 50-1300 ka, which is particularly relevant for polar ice cores, whereas 39Ar (half-life 269 a) with a dating range of 50-1400 a is suitable for high mountain glaciers. For a long time the use of 81Kr and 39Ar for dating of ice samples was hampered by the lack of a detection technique that can meet its extremely small abundance at a reasonable sample size. Here, we report on 81Kr and 39Ar dating of Antarctic and Tibetan ice cores with the detection method Atom Trap Trace Analysis (ATTA), using 5-10 kg of ice for 81Kr and 2-5 kg for 39Ar. Among others, we measured 81Kr in the lower section of Taldice ice core, which is difficult to date by conventional methods, and in the meteoric bottom of the Vostok ice core in comparison with an age scale derived from hydrate growth. Moreover, we have obtained an 39Ar profile for an ice core from central Tibet in combination with a timescale constructed by layer counting. The presented studies demonstrate how the obtained 81Kr and 39Ar ages can complement other methods in developing an ice core chronology, especially for the bottom part.[1] Z.-T. Lu, Tracer applications of noble gas radionuclides in the geosciences, Earth-Science Reviews 138, 196-214, (2014)[2] C. Buizert, Radiometric 81Kr dating identifies 120,000-year-old ice at Taylor Glacier, Antarctica, Proceedings of the National Academy of Sciences, 111, 6876, (2014)[3] L. Tian, 81Kr Dating at the Guliya Ice Cap, Tibetan Plateau, Geophysical Research Letters, (2019)[4] http://atta.ustc.edu.cn

The atmospheric processes determining the isotopic composition of precipitation on the Antarctic plateau are yet to be fully understood, as well as the post-depositional processes altering the snow pristine isotopic signal. Improving the comprehension of these physical mechanisms is of crucial importance for interpreting the isotopic records from ice cores drilled in the low accumulation area of Antarctica, e.g., the upcoming Beyond EPICA drilling at Little Dome C.Up to now, few records of the isotopic composition of precipitation in Antarctica are available, most of them limited in time or sampling frequency. Here we present a 9-year long δ18O and δD record (2008-2016) of precipitation at Concordia base, East Antarctica. The snow is collected daily on a raised platform (1 m), positioned in the clean area of the station; the precipitation collection is still being carried out each year by the winter over personnel.A significant positive correlation between isotopes in precipitation and 2-m air temperature is observed at both seasonal and interannual scale; the lowest temperature and isotopic values are usually recorded during winters characterized by a strongly positive Southern Annular Mode index.To improve the understanding of the mechanisms governing the isotopic composition of precipitation, we compare the isotopic data of Concordia samples with on-site observations, meteorological data from the Dome C AWS of the University of Wisconsin-Madison, as well as with high-resolution simulation results from the isotope-enabled atmospheric general circulation models ECHAM5-wiso and ECHAM6-wiso, nudged with the ERA-Interim and ERA5 reanalyses respectively.

International audience; In central Antarctica, where accumulation rates are very low, summer sublimation of surface snow is a key element of the surface mass balance, but its fingerprint in isotopic composition of water (δD, δ 18 O, and δ 17 O) remains unclear. In this study, we examined the influence of summer sublimation on δD, δ 18 O, and δ 17 O in precipitation using data sets of isotopic composition of precipitation at various sites on the inland East Antarctica. We found unexpectedly low δ 18 O values in the summer precipitation, decoupled from surface air temperatures. This feature can be explained by the combined effects of weak or nonexistent temperature inversion and moisture recycling associated with sublimation-condensation processes in summer. Isotopic fractionation during the moisture-recycling process also explains the observed high values of d-excess and 17 O-excess in summer precipitation. Our results suggest that the local cycle of sublimation-condensation in summer is an important process for the isotopic composition of surface snow, water vapor, and consequently precipitation on inland East Antarctica.

Ongoing climate change is apparently increasing tree mortality rates, and understanding mechanisms of drought-induced tree decline can improve mortality projections. Differential drought impact on conspecific individuals within a population has been reported, but no clear mechanistic explanation for this pattern has emerged. Following a severe drought (summer 2012), we monitored over a 3-year period healthy (H) and declining (D) Pinus nigra trees co-occurring in a karstic woodland to highlight eventual individual-specific physiological differences underlying differential canopy dieback. We investigated differences in water and carbon metabolism, and xylem anatomy as a function of crown health status, as well as eventual genotypic basis of contrasting drought responses. H and D trees exploited the same water pools and relied on similar hydraulic strategies to cope with drought stress. Genetic analyses did not highlight differences between groups in terms of geographical provenance. Hydraulic and anatomical analyses showed conflicting results. The hydraulic tracheid diameter and theoretical hydraulic conductivity were similar, but D trees were characterized by lower water transport efficiency, greater vulnerability to xylem conduit implosion and reduced carbohydrate stores. Our results suggest that extreme drought events can have different impacts on conspecific individuals, with differential vulnerability to xylem embolism likely playing a major role in setting the fate of trees under climate change.

Extreme summer droughts induced differential impacts in a population of Pinus nigra trees. We analyzed eventual physiological differences between desiccated and healthy trees. Desiccated trees were more vulnerable to drought-induced xylem embolism, and were also suffering from depletion of carbohydrate reserves. Our data suggest that genotypic or phenotypic intraspecific variability can play fundamental roles in defining individual drought responses/impacts, dictating the fate of single trees under global-change-type droughts., Ongoing climate change is apparently increasing tree mortality rates, and understanding mechanisms of drought-induced tree decline can improve mortality projections. Differential drought impact on conspecific individuals within a population has been reported, but no clear mechanistic explanation for this pattern has emerged. Following a severe drought (summer 2012), we monitored over a 3-year period healthy (H) and declining (D) Pinus nigra trees co-occurring in a karstic woodland to highlight eventual individual-specific physiological differences underlying differential canopy dieback. We investigated differences in water and carbon metabolism, and xylem anatomy as a function of crown health status, as well as eventual genotypic basis of contrasting drought responses. H and D trees exploited the same water pools and relied on similar hydraulic strategies to cope with drought stress. Genetic analyses did not highlight differences between groups in terms of geographical provenance. Hydraulic and anatomical analyses showed conflicting results. The hydraulic tracheid diameter and theoretical hydraulic conductivity were similar, but D trees were characterized by lower water transport efficiency, greater vulnerability to xylem conduit implosion and reduced carbohydrate stores. Our results suggest that extreme drought events can have different impacts on conspecific individuals, with differential vulnerability to xylem embolism likely playing a major role in setting the fate of trees under climate change.

International audience; Polar ice sheets are remarkable repositories of tephra layers. The Talos Dome ice core (72°49′S, 159°11′E), drilled at the edge of the East Antarctic Plateau, close to Late Quaternary volcanoes, offers considerable potential to extend the current tephra time-stratigraphic framework. A tephrochronological study was undertaken of the ice core sections related to the Last Interglacial and the transition to the subsequent glacial period. Thirteen macroscopically visible layers, interpreted to be related to primary deposition of fallout tephra, have been analysed for quantitative grain size and glass shard geochemistry. The layers, precisely framed within the climate (δ18O) record for the core, span in age from 111.6 ± 1.9 to 123.3 ± 2.2 ka. Coarse particle size suggests origin from regional sources. Indeed, the vast majority of the samples display an alkaline affinity and trachytic composition that are both typical geochemical features of rifting Antarctic volcanism. Using subtle differences in the geochemical signatures and the comparison with data from previous studies, a few layers are attributed to known coeval Mt. Melbourne eruptions. Another sample subset is consistent with derivation from The Pleiades and Mt. Rittmann volcanoes. One peculiar trachytic glass population appears to be related to activity of the more distant Marie Byrd Land volcanoes. The newly detected tephras provide stratigraphic markers that could facilitate future synchronisation and dating of palaeoclimatic records. The Talos Dome tephra inventory also contributes significantly to the reconstruction of the Northern Victoria Land explosive volcanism, for which chronostratigraphic data for the Last Interglacial temporal segment are poor.

In 2012, an extreme summer drought induced species-specific die-back in woody species in NE-Italy. Quercus pubescens and Ostrya carpinifolia were heavily impacted, while Prunus mahaleb was largely unaffected. By comparing seasonal changes in isotopic composition of xylem sap, rainfall and deep soil samples, we show that P. mahaleb has a deeper root system than the other two species. This morphological trait allowed P. mahaleb to maintain higher water potential (Ψ), gas exchange rates and non-structural carbohydrates content (NSC) throughout the summer, when compared to the other species. More favourable water and carbon states allowed relatively stable maintenance of stem hydraulic conductivity (k) throughout the growing season. In contrast, in Q. pubescens and O. carpinifolia decreasing Ψ and NSC were associated with significant hydraulic failure, with spring-to-summer k loss averaging 60%. Our data support to the hypothesis that drought-induced tree decline is a complex phenomenon that cannot be modelled on the basis of single predictors of tree status like hydraulic efficiency, vulnerability, and carbohydrate content. Our data highlight the role of rooting depth in seasonal progression of water status, gas exchange and NSC, with possible consequences for energy-demanding mechanisms involved in the maintenance of vascular integrity. This article is protected by copyright. All rights reserved.

Major explosive volcanic eruptions may significantly alter the global atmosphere for about 2&ndash, 3 years. During that period, volcanic products (mainly H2SO4) with high residence time, stored in the stratosphere or, for shorter times, in the troposphere are gradually deposited onto polar ice caps. Antarctic snow may thus record acidic signals providing a history of past volcanic events. The high resolution sulphate concentration profile along a 197 m long ice core drilled at GV7 (Northern Victoria land) was obtained by Ion Chromatography on around 3500 discrete samples. The relatively high accumulation rate (241 &plusmn, 13 mm we yr &minus, 1) and the 5-cm sampling resolution allowed a preliminary counted age scale. The obtained stratigraphy covers roughly the last millennium and 24 major volcanic eruptions were identified, dated, and tentatively ascribed to a source volcano. The deposition flux of volcanic sulphate was calculated for each signature and the results were compared with data from other Antarctic ice cores at regional and continental scale. Our results show that the regional variability is of the same order of magnitude as the continental one.

The Antarctic temperature changes over the past millennia remain more uncertain than in many other continental regions. This has several origins: 1) the number of high resolution ice cores is small, in particular on the Antarctic Plateau and in some coastal areas in East Antarctica; 2) the short instrumental records limit the calibration period for reconstructions and the assessment of the methodologies; 3) the link between isotope records from ice cores and local climate is usually complex and dependent on the spatial and time scales investigated. Here, we use climate model results, pseudoproxy and data assimilation experiments to assess the potential of reconstructing the Antarctic temperature over the last two millennia based on a new database of stable oxygen isotopes in ice cores compiled in the framework of Antarctica2k (Stenni et al., 2017). The well-known covariance between δ18O and temperature is reproduced in the two isotope-enabled models used (ECHAM5/MPI-OM and ECHAM5-wiso), but is generally weak over the different Antarctic regions, limiting the skill of the reconstructions. Furthermore, the strength of the link displays large variations over the past millennium, further affecting the potential skill of temperature reconstructions based on statistical methods which rely on the assumption that the last decades are a good estimate for longer temperature reconstructions. Using a data assimilation technique allows in theory taking into account changes in the δ18O-temperature link through time and space. Pseudoproxy experiments confirm the benefits of using data assimilation methods instead of statistical ones that provide reconstructions with unrealistic variances in some Antarctic subregions. They also confirm that the relatively weak link between both variables leads to a limited potential for reconstructing temperature based on δ18O. The reconstruction skill is however higher and more uniform among reconstruction methods when the reconstruction target is the Antarctic as a whole rather than smaller Antarctic subregions. This consistency between the methods at the large scale is also observed when reconstructing temperature based on the real δ18O regional composites of Stenni et al. (2017). In this case, temperature reconstructions based on data assimilation confirm the long term cooling over Antarctica during the last millennium, and the later onset of anthropogenic warming compared to the simulations without data assimilation, especially visible in West Antarctica. Data assimilation also allows reconciling models and direct observations by reconstructing the East-West contrast regarding the recent temperature trends, indicating that internal variability likely plays a major role in driving this heterogeneous recent warming. This is further supported by the large spread of individual PMIP/CMIP model realizations regarding the recent warming pattern. As in the pseudoproxy framework, the reconstruction methods perform differently at the subregional scale, especially in terms of the variance of the produced time series. While the potential benefits of using a data assimilation method instead of a statistical one have been highlighted in a pseudoproxy framework, the instrumental series are too short to confirm it in a realistic setup.

International audience; The oldest ice core records are obtained from the East Antarctic Plateau. Water isotopes are key proxies to reconstructing past climatic conditions over the ice sheet and at the evaporation source. The accuracy of climate reconstructions depends on knowledge of all processes affecting water vapour, precipitation and snow isotopic compositions. Fractionation processes are well understood and can be integrated in trajectory-based Rayleigh distillation and isotope-enabled climate models. However, a quantitative understanding of processes potentially altering snow isotopic composition after deposition is still missing. In low-accumulation sites, such as those found in East Antarctica, these poorly constrained processes are likely to play a significant role and limit the interpretability of an ice core's isotopic composition. By combining observations of isotopic composition in vapour, precipitation, surface snow and buried snow from Dome C, a deep ice core site on the East Antarctic Plateau, we found indications of a seasonal impact of metamorphism on the surface snow isotopic signal when compared to the initial precipitation. Particularly in summer, exchanges of water molecules between vapour and snow are driven by the diurnal sublimation-condensation cycles. Overall, we observe in between precipitation events modification of the surface snow isotopic composition. Using high-resolution water isotopic composition profiles from snow pits at five Antarctic sites with different accumulation rates, we identified common patterns which cannot be attributed to the seasonal variability of precipitation. These differences in the precipitation, surface snow and buried snow isotopic composition provide evidence of post-deposition processes affecting ice core records in low-accumulation areas.

The description of the hydrological cycle in Atmospheric General Circulation Models (GCMs) can be validated using water isotopes as tracers. Many GCMs now simulate the movement of the stable isotopes of water, but here we present the first GCM simulations modelling the content of natural tritium in water. These simulations were obtained using a version of the LMDZ General Circulation Model enhanced by water isotopes diagnostics, LMDZ-iso. To avoid tritium generated by nuclear bomb testing, the simulations have been evaluated against a compilation of published tritium datasets dating from before 1950, or measured recently. LMDZ-iso correctly captures the observed tritium enrichment in precipitation as oceanic air moves inland (the so-called continental effect) and the observed north-south variations due to the latitudinal dependency of the cosmogenic tritium production rate. The seasonal variability, linked to the stratospheric intrusions of air masses with higher tritium content into the troposphere, is correctly reproduced for Antarctica with a maximum in winter. LMDZ-iso reproduces the spring maximum of tritium over Europe, but underestimates it and produces a peak in winter that is not apparent in the data. This implementation of tritium in a GCM promises to provide a better constraint on: (1) the intrusions and transport of air masses from the stratosphere and (2) the dynamics of the modelled water cycle. The method complements the existing approach of using stable water isotopes., Accepted paper version. See published version in EPSL Elsevier website

Here we review Antarctic snow accumulation variability, at the regional scale, over the past 1000 years. A total of 80 ice core snow accumulation records were gathered, as part of a community led project coordinated by the PAGES Antarctica 2k working group. The ice cores were assigned to seven geographical regions, separating the high accumulation coastal zones below 2000 m elevation from the dry central Antarctic Plateau. The regional composites of annual snow accumulation were evaluated against modelled surface mass balance (SMB) from RACMO2.4 and precipitation from ERA-interim reanalysis. With the exception of the Weddell Sea coast, the low-elevation composites capture the regional precipitation and SMB variability. The central Antarctic sites lack coherency and are either not representing regional precipitation or indicate the models inability to capture relevant precipitation processes in the cold, dry central plateau. The drivers of precipitation are reviewed for each region and the temporal variability and trends evaluated over the past 100, 200 and 1000 years. Our study suggests an overall increase in SMB across the grounded Antarctic ice sheet of ~ 44 GT since 1800 AD, with the largest (area-weighted) contribution from the Antarctic Peninsula (AP). Only four ice core records cover the full 1000 years and suggest a decrease in snow accumulation during this period. However, our study emphasizes the importance of low elevation coastal zones (especially AP and DML), which have been underrepresented in previous investigations of temporal snow accumulation.

Climate trends in the Antarctic region remain poorly characterised, owing to the brevity and scarcity of direct climate observations and the large magnitude of interannual to decadal-scale climate variability. Here, within the framework of the PAGES Antarctica 2k working group, we build an enlarged database of ice core water stable isotope records from Antarctica, consisting of 112 records. We produce both unweighted and weighted isotopic (δ18O) composites and temperature reconstructions since 0 CE, binned at 5 and 10-year resolution, for 7 climatically-distinct regions covering the Antarctic continent. Following earlier work of the Antarctica 2k working group, we also produce composites and reconstructions for the broader regions of East Antarctica, West Antarctica, and the whole continent. We use three methods for our temperature reconstructions: i) a temperature scaling based on the δ18O-temperature relationship output from an ECHAM5-wiso model simulation nudged to ERA-interim atmospheric reanalyses from 1979 to 2013, and adjusted for the West Antarctic Ice Sheet region to borehole temperature data; ii) a temperature scaling of the isotopic normalized anomalies to the variance of the regional reanalysis temperature and iii) a composite-plus-scaling approach used in a previous continental scale reconstruction of Antarctic temperature since 1 CE but applied to the new Antarctic ice core database. Our new reconstructions confirm a significant cooling trend from 0 to 1900 CE across all Antarctic regions where records extend back into the 1st millennium, with the exception of the Wilkes Land coast and Weddell Sea coast regions. Within this long-term cooling trend from 0–1900 CE we find that the warmest period occurs between 300 and 1000 CE, and the coldest interval from 1200 to 1900 CE. Since 1900 CE, significant warming trends are identified for the West Antarctic Ice Sheet, the Dronning Maud Land coast and the Antarctic Peninsula regions, and these trends are robust across the distribution of records that contribute to the unweighted isotopic composites and also significant in the weighted temperature reconstructions. Only for the Antarctic Peninsula is this most recent century-scale trend unusual in the context of natural variability over the last 2000-years. However, projected warming of the Antarctic continent during the 21st Century may soon see significant and unusual warming develop across other parts of the Antarctic continent. The extended Antarctica 2k ice core isotope database developed by this working group opens up many avenues for developing a deeper understanding of the response of Antarctic climate to natural and anthropogenic climate forcings. The first long-term quantification of regional climate in Antarctica presented herein is a basis for data-model comparison and assessments of past, present and future driving factors of Antarctic climate.

Stable water isotopes (δ18O) obtained from snow and ice samples of polar regions are used to reconstruct past climate variability, but heat and mass transport processes can affect the isotopic composition. Here we present an experimental study on the effect on the snow isotopic composition by airflow through a snow pack in controlled laboratory conditions. The influence of isothermal and controlled temperature gradient conditions on the δ18O content in the snow and interstitial water vapor is elucidated. The observed disequilibrium between snow and vapor isotopes led to exchange of isotopes between snow and vapor under non-equilibrium processes, significantly changing the δ18O content of the snow. The type of metamorphism of the snow had a significant influence on this process. These findings are pertinent to the interpretation of the records of stable isotopes of water from ice cores. These laboratory measurements suggest that a highly resolved history is relevant for the interpretation of the snow isotopic composition in the field.

The correct derivation of paleotemperatures from ice cores requires exact knowledge of all processes involved before and after the deposition of snow and the subsequent formation of ice. At the Antarctic deep ice core drilling site Dome C, a unique data set of daily precipitation amount, type, and stable water isotope ratios is available that enables us to study in detail atmospheric processes that influence the stable water isotope ratio of precipitation. Meteorological data from both automatic weather station and a mesoscale atmospheric model were used to investigate how different atmospheric flow patterns determine the precipitation parameters. A classification of synoptic situations that cause precipitation at Dome C was established and, together with back-trajectory calculations, was utilized to estimate moisture source areas. With the resulting source area conditions (wind speed, sea surface temperature, and relative humidity) as input, the precipitation stable isotopic composition was modeled using the so-called Mixed Cloud Isotope Model (MCIM). The model generally underestimates the depletion of 18O in precipitation, which was not improved by using condensation temperature rather than inversion temperature. Contrary to the assumption widely used in ice core studies, a more northern moisture source does not necessarily mean stronger isotopic fractionation. This is due to the fact that snowfall events at Dome C are often associated with warm air advection due to amplification of planetary waves, which considerably increases the site temperature and thus reduces the temperature difference between source area and deposition site. In addition, no correlation was found between relative humidity at the moisture source and the deuterium excess in precipitation. The significant difference in the isotopic signal of hoarfrost and diamond dust was shown to disappear after removal of seasonality. This study confirms the results of an earlier study carried out at Dome Fuji with a shorter data set using the same methods.

Water stable isotopes in Greenland ice core data provide key paleoclimatic information, and have been compared with precipitation isotopic composition simulated by isotopically enabled atmospheric models. However, post-depositional processes linked with snow metamorphism remain poorly documented. For this purpose, monitoring of the isotopic composition (δ18O, δD) of near-surface water vapor, precipitation and samples of the top (0.5 cm) snow surface has been conducted during two summers (2011–2012) at NEEM, NW Greenland. The samples also include a subset of 17O-excess measurements over 4 days, and the measurements span the 2012 Greenland heat wave. Our observations are consistent with calculations assuming isotopic equilibrium between surface snow and water vapor. We observe a strong correlation between near-surface vapor δ18O and air temperature (0.85 ± 0.11‰ °C−1 (R = 0.76) for 2012). The correlation with air temperature is not observed in precipitation data or surface snow data. Deuterium excess (d-excess) is strongly anti-correlated with δ18O with a stronger slope for vapor than for precipitation and snow surface data. During nine 1–5-day periods between precipitation events, our data demonstrate parallel changes of δ18O and d-excess in surface snow and near-surface vapor. The changes in δ18O of the vapor are similar or larger than those of the snow δ18O. It is estimated using the CROCUS snow model that 6 to 20% of the surface snow mass is exchanged with the atmosphere. In our data, the sign of surface snow isotopic changes is not related to the sign or magnitude of sublimation or deposition. Comparisons with atmospheric models show that day-to-day variations in near-surface vapor isotopic composition are driven by synoptic variations and changes in air mass trajectories and distillation histories. We suggest that, in between precipitation events, changes in the surface snow isotopic composition are driven by these changes in near-surface vapor isotopic composition. This is consistent with an estimated 60% mass turnover of surface snow per day driven by snow recrystallization processes under NEEM summer surface snow temperature gradients. Our findings have implications for ice core data interpretation and model–data comparisons, and call for further process studies.

Application of stable isotopes in soil studies has improved quantitative evaluation of evaporation and other hydrological processes in soil. This study was carried out to determine the effect of tillage on evaporative loss of water from the soil. Zero tillage and conventional tillage were compared. Suction tubes were installed for soil water collection at the depths 0.15, 0.50, and 1.0 m by pumping soil water with a peristaltic pump. Soil water evaporation was estimated using stable isotopes of water. The mean isotopic composition of the soil water at 0.15 m soil depth were -1.15‰ (δ18O) and -0.75‰ (δD) and were highly enriched compared with the isotopic compositions of the site precipitation. Soil water stable isotopes (δ18O and δD) were more enriched near the surface under zero tillage while they were less negative down the profile under zero tillage. This suggests an occurrence of more evaporation and infiltration under conventional then zero tillage, respectively, because evaporative fractionation contributes to escape of lighter isotopes from liquid into the vapour phase leading to enrichment in heavy isotopes in the liquid phase. The annual evaporation estimated using the vapour diffusion equation ranges from 46-70 and 54-84 mm year-1 under zero and conventional tillage, respectively, indicating more evaporation under conventional tillage compared with zero tillage. Therefore, to reduce soil water loss, adoption of conservation tillage practices such as zero tillage is encouraged.

Past global climate changes had strong regional expression. To elucidate their spatio-temporal pattern, we reconstructed past temperatures for seven continental-scale regions during the past one to two millennia. The most coherent feature in nearly all of the regional temperature reconstructions is a long-term cooling trend, which ended late in the nineteenth century. At multi-decadal to centennial scales, temperature variability shows distinctly different regional patterns, with more similarity within each hemisphere than between them. There were no globally synchronous multi-decadal warm or cold intervals that define a worldwide Medieval Warm Period or Little Ice Age, but all reconstructions show generally cold conditions between AD 1580 and 1880, punctuated in some regions by warm decades during the eighteenth century. The transition to these colder conditions occurred earlier in the Arctic, Europe and Asia than in North America or the Southern Hemisphere regions. Recent warming reversed the long-term cooling; during the period AD 1971?2000, the area-weighted average reconstructed temperature was higher than any other time in nearly 1,400 years. Fil: Ahmed, Moinuddin. Federal Urdu University of Arts, Science and Technology. Department of Botany; Pakistán Fil: Anchukaitis, Kevin J.. Columbia University. Lamont Doherty Earth Observatory; Estados Unidos. Woods Hole Oceanographic Institution; Estados Unidos Fil: Asrat, Asfawossen . Addis Ababa University. School of Earth Sciences; Etiopía Fil: Borgaonkar, Hemant P.. Indian Institute of Tropical Meteorology; India Fil: Braida, Martina . University of Trieste. Dipartimento di Matematica e Geoscienze; Italia Fil: Buckley, Brendan M. . Columbia University. Lamont Doherty Earth Observatory; Estados Unidos Fil: Ulf Büntgen. Swiss Federal Research Institute WSL; Suiza Fil: Chase, Brian M.. Université Montpellier. Département Paléoenvironnements et Paléoclimats (PAL); Francia. University of Bergen. Department of Archaeology, History, Cultural Studies and Religion; Noruega Fil: Christie, Duncan A. . Universidad Austral de Chile. Laboratorio de Dendrocronología y Cambio Global; Chile. Universidad de Chile. Center for Climate and Resilience Research; Chile Fil: Cook, Edward R.. Columbia University. Lamont Doherty Earth Observatory; Argentina Fil: Curran, Mark A. J.. Australian Antarctic Division; Australia. University of Tasmania. Antarctic Climate & Ecosystems Cooperative Research Centre; Australia Fil: Diaz, Henry F. . National Oceanic and Atmospheric Administration. Cooperative Institute for Research in Environmental Sciences, ; Estados Unidos Fil: Esper, Jan. Johannes Gutenberg University. Department of Geography,; Alemania Fil: Fan, Ze-Xin . Chinese Academy of Sciences. Xishuangbanna Tropical Botanical Garden ; China Fil: Gaire, Narayan P. . Nepal Academy of Science and Technology. Faculty of Science,; Nepal Fil: Ge, Quansheng. Chinese Academy of Sciences. Institute of Geographical Sciences and Natural Resources Research, ; China Fil: Gergis, Joëlle. University of Melbourne. School of Earth Sciences; Australia Fil: González-Rouco, J Fidel. Universidad Complutense de Madrid. Departamento Astrofísica y CC de la Atmósfera; España Fil: Goosse, Hugues. Université Catholique de Louvain. LemaitreCenter for Earth and Climate Research, Earth and Life Institute; Bélgica Fil: Grab, Stefan W. . University of the Witwatersrand. School of Geography,Archaeology and Environmental Studies; Sudáfrica Fil: Graham, Nicholas. Hydrologic Research Center; Estados Unidos Fil: Graham, Rochelle . Hydrologic Research Center; Estados Unidos Fil: Grosjean, Martin . University of Bern. Oeschger Centre for Climate Change Research & Institute of Geography; Suiza Fil: Hanhijärvi, Sami T.. University of Helsinki. Department of Environmental Sciences; Finlandia Fil: Kaufman, Darrell S.. Northern Arizona University. School of Earth Sciences and Environmental Sustainability; Estados Unidos Fil: Kiefer, Thorsten . International Project Office, Past Global Changes (PAGES); Suiza Fil: Kimura, Katsuhiko. Fukushima University. Department of Symbiotic System Science; Japón Fil: Korhola, Atte A.. University of Helsinki. Department of Environmental Sciences; Finlandia Fil: Krusic, Paul J.. Stockholm University. Department of Physical Geography and Quaternary Geology; Suecia Fil: Lara, Antonio. Universidad Austral de Chile. Laboratorio de Dendrocronología y Cambio Global; Chile. Universidad de Chile. Center for Climate and Resilience Research; Chile Fil: Lézine, Anne-Marie. Université Pierre et Marie Curie. Laboratoire d’Océanographie et du Climat: Expérimentations et Approches Numériques (LOCEAN); Francia Fil: Ljungqvist, Fredrik C.. Stockholm University. Department of History, ; Suecia Fil: Lorrey, Andrew M.. National Institute of Water and Atmospheric Research Ltd., National Climate Centre Auckland; Nueva Zelanda Fil: Luterbacher, Jürg. Justus Liebig University. Department of Geography, Climatology, Climate Dynamics and Climate Change; Alemania Fil: Masson-Delmotte, Valérie . Laboratoire des Science du Climat et de l’Environnement, Gif-sur-Yvette; Francia Fil: McCarroll, Danny. Swansea University. Department of Geography; Reino Unido Fil: McConnell, Joseph R.. Nevada System of Higher Education. Desert Research Institute; Estados Unidos Fil: McKay, Nicholas P.. Northern Arizona University. School of Earth Sciences and Environmental Sustainability; Estados Unidos Fil: Morales, Mariano Santos. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina Fil: Moy, Andrew D.. Australian Antarctic Division; Australia. University of Tasmania. Antarctic Climate & Ecosystems Cooperative Research Centre; Australia Fil: Mulvaney, Robert. British Antarctic Survey; Reino Unido Fil: Mundo, Ignacio Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina Fil: Nakatsuka, Takeshi. Nagoya University. Department of Earth and Environmental Sciences; Japón Fil: Nash, David J.. University of the Witwatersrand. School of Geography,Archaeology and Environmental Studies; Sudáfrica. University of Brighton. School of Environment and Technology; Reino Unido Fil: Neukom, Raphael . Swiss Federal Research Institute WSL; Suiza Fil: Nicholson, Sharon E.. Florida State University. Department of Earth, Ocean and Atmospheric Sciences, ; Estados Unidos Fil: Oerter, Hans. Alfred Wegener Institute for Polar and Marine Research in the Helmholtz Association. Department of Glaciology; Alemania Fil: Palmer, Jonathan G.. University of Exeter. College of Life and Environmental Sciences; Reino Unido. University of New South Wales. Climate Change Research Centre; Australia Fil: Phipps, Steven J.. University of New South Wales. Climate Change Research Centre; Australia. University of New South Wales. ARC Centre of Excellence for Climate System Science; Australia Fil: Prieto, Maria del Rosario. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina Fil: Rivera, Andres. Centro de Estudios Cientificos; Chile Fil: Sano, Masaki. Nagoya University. Department of Earth and Environmental Sciences; Japón Fil: Severi, Mirko. University of Florence. Department of Chemistry ‘Ugo Schiff’; Italia Fil: Shanahan, Timothy M.. University of Texas at Austin. Jackson School of Geosciences; Estados Unidos Fil: Shao, Xuemei. Chinese Academy of Sciences. Institute of Geographical Sciences and Natural Resources Research; China Fil: Shi, Feng. Chinese Academy of Sciences. LASG, Institute of Atmospheric Physics, ; China Fil: Sigl, Michael . Nevada System of Higher Education. Desert Research Institute,; Estados Unidos Fil: Smerdon, Jason E.. Columbia University. Lamont Doherty Earth Observatory; Estados Unidos Fil: Solomina, Olga N. . Russian Academy of Sciences. Institute of Geography; Rusia Fil: Steig, Eric J.. University of Washington. Department of Earth and Space Sciences; Estados Unidos Fil: Stenni, Barbara. University of Trieste. Dipartimento di Matematica e Geoscienze; Italia Fil: Thamban, Meloth. National Centre for Antarctic and Ocean Research; India Fil: Trouet, Valerie. University of Arizona. Laboratory of Tree-Ring Research; Estados Unidos Fil: Turney, Chris S.M.. University of New South Wales. Climate Change Research Centre; Australia Fil: Umer, Mohammed. Addis Ababa University. School of Earth Sciences; Etiopía Fil: van Ommen, Tas. Australian Antarctic Division; Australia. University of Tasmania. Antarctic Climate & Ecosystems Cooperative Research Centre; Australia Fil: Verschuren, Dirk. Ghent University. Department of Biology; Bélgica Fil: Viau, Andre E.. University of Ottawa. Department of Geography; Canadá Fil: Villalba, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Científico Tecnológico Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; Argentina Fil: Vinther, Bo M.. University of Copenhagen. Niels Bohr Institute; Dinamarca Fil: von Gunten, Lucien . Past Global Changes (PAGES). International Project Office, ; Suiza Fil: Wagner, Sebastian. Helmholtz-Zentrum Geesthacht. Institute for Coastal Research; Alemania Fil: Wahl, Eugene R.. National Oceanic and Atmospheric Administration. National Climatic Data Center; Estados Unidos Fil: Wanner, Heinz. University of Bern. Oeschger Centre for Climate Change Research & Institute of Geography; Suiza Fil: Werner, Johannes P.. Justus Liebig University. Department of Geography, Climatology, Climate Dynamics and Climate Change; Alemania Fil: White, James W.C.. University of Colorado. Institute of Arctic and Alpine Research; Estados Unidos Fil: Yasue, Koh. Shinshu University. Department of Forest Science; Japón Fil: Zorita, Eduardo. Helmholtz-Zentrum Geesthacht. Institute for Coastal Research; Alemania

The oldest ice core records are obtained from the East Antarctic plateau. Water stable isotopes records are key for reconstructions of past climatic conditions both over the ice sheet and at the evaporation source. The accuracy of such climate reconstructions crucially depends on the knowledge of all the processes affecting the water vapour, precipitation and snow isotopic composition. Atmospheric fractionation processes are well understood and can be integrated in Rayleigh distillation and complex isotope enabled climate models. However, a comprehensive quantitative understanding of processes potentially altering the snow isotopic composition after the deposition is still missing, especially for exchanges between vapour and snow. In low accumulation sites such as found on the East Antarctic Plateau, these poorly constrained processes are especially likely to play a significant role. This limits the interpretation of isotopic composition from ice core records, specifically at short time scales. Here, we combine observations of isotopic composition in the vapour, the precipitation, the surface snow and the buried snow from various sites of the East Antarctic Plateau. At the seasonal scale, we highlight a significant impact of metamorphism on surface snow isotopic signal compared to the initial precipitation isotopic signal. In particular, in summer, exchanges of water molecules between vapour and snow are driven by the sublimation/condensation cycles at the diurnal scale. Using highly resolved isotopic composition profiles from pits in five East Antarctic sites, we identify a common 20 cm cycle which cannot be attributed to the seasonal variability of precipitation. Altogether, the smaller range of isotopic compositions observed in the buried and in the surface snow compared to the precipitation, and also the reduced slope between surface snow isotopic composition and temperature compared to precipitation, constitute evidences of post-deposition processes affecting the variability of the isotopic composition in the snow pack. To reproduce these processes in snow-models is crucial to understand the link between snow isotopic composition and climatic conditions and to improve the interpretation of isotopic composition as a paleoclimate proxy.