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1. Ethyl 2-(Diisopropoxyphosphoryl)-2H-Azirine-3-Carboxylate: Reactions with Activated 1,3-Butadienes

Author

Américo Lemos, Xerardo García-Mera, José E. Rodríguez-Borges, M. José Alves, and Universidade de Santiago de Compostela. Departamento de Química Orgánica

Subjects
Azirine, chemistry.chemical_compound, Dienophiles, chemistry, Product (mathematics), Phosphonate derivative compounds, Aza-Diels-Alder cycloaddition, Carboxylate, 2H-Azirines, Medicinal chemistry
Abstract

The 12th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis Ethyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate was generated “in situ” and reacted with a number of 1,3-butadienes. Cycloadducts, or in one case an ensuing rearranged product, were isolated with moderate to good yields The authors thank Fundação para a Ciência e Tecnologia, CIQA-Centro de Investigação em Química do Algarve and Xunta de Galicia for financial support under project 07CSA008203PR

Published
2008

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