1. Mechanism of Saponite Crystallization from a Rapidly Formed Amorphous Intermediate
- Author
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Tomasz M. Stawski, R. Besselink, Jörn Hövelmann, Dominique J. Tobler, Helen M. Freeman, and Liane G. Benning
- Subjects
Materials science ,Coprecipitation ,FOS: Physical sciences ,Infrared spectroscopy ,chemistry.chemical_element ,Condensed Matter - Soft Condensed Matter ,engineering.material ,010402 general chemistry ,01 natural sciences ,Hydrothermal circulation ,law.invention ,Aluminosilicate ,law ,General Materials Science ,Saponite ,Crystallization ,Condensed Matter - Materials Science ,010405 organic chemistry ,Magnesium ,Materials Science (cond-mat.mtrl-sci) ,General Chemistry ,Condensed Matter Physics ,0104 chemical sciences ,Amorphous solid ,chemistry ,Chemical engineering ,engineering ,Soft Condensed Matter (cond-mat.soft) - Abstract
Although clays are crucial mineral phases in Earth's weathering engine, it is unclear how they form in surface environments under (near-)ambient pressures and temperature. Most synthesis routes, attempting to give insights into the plausible mechanisms, rely on hydrothermal conditions, yet many geological studies showed that clays may actually form at moderate temperatures (< 100 deg. C) in most terrestrial settings. Here, we present the mechanism of the low-temperature (25-95 deg. C) crystallization of a synthetic Mg-clay, saponite. We describe the pathway at the various sub-stages of the reaction, as we derived from high-energy X-ray diffraction, infrared spectroscopy and transmission electron microscopy data. Our results reveal that saponite crystallizes via a two stage process: 1) a rapid (several minutes) co-precipitation where ~20% of the available magnesium becomes incorporated into an aluminosilicate network followed by 2) a much slower crystallization mechanism (many hours to days) where the remaining magnesium becomes gradually incorporated into the growing saponite sheet structure., manuscript + supporting information
- Published
- 2020
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