1. Azimuthal-rotation sample holder for molecular orientation analysis
- Author
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Daisuke Shindo, Masao Kimura, Yasuo Takeichi, Shohei Yamashita, Takuji Ohigashi, Reiko Murao, Eiji Nemoto, Daisuke Wakabayashi, and T. Harano
- Subjects
scanning transmission X-ray microscopy ,Nuclear and High Energy Physics ,Materials science ,orbital orientation ,02 engineering and technology ,Scanning transmission X-ray microscopy ,Rotation ,01 natural sciences ,Molecular physics ,Displacement (vector) ,symbols.namesake ,Orientation (geometry) ,0103 physical sciences ,X-ray absorption near edge ,Nuclear Experiment ,Instrumentation ,010302 applied physics ,Radiation ,Brewster's angle ,carbon ,Computer Science::Information Retrieval ,Undulator ,021001 nanoscience & nanotechnology ,Research Papers ,Azimuth ,chemical structure ,symbols ,0210 nano-technology ,Excitation - Abstract
An azimuthal-rotation sample holder, with improvements in the rotation-angle accuracy and rotation-axes displacement during azimuthal rotation, was developed for molecular-orientation analysis using scanning transmission X-ray microscopy., In this study, an azimuthal-rotation sample holder compatible with scanning transmission X-ray microscopy was developed. This holder exhibits improvement in the accuracy of rotation angles and reduces the displacement of the rotation axes during azimuthal rotation by using a crossed roller bearing. To evaluate the performance of the holder, the authors investigated the dependence of the optical density around the C K-edge absorption of π-orbital-oriented domains in natural spherical graphite on the rotational angle by using linearly horizontally and vertically polarized undulator radiation. Based on the dependence of the optical density ratio between C 1s → π* and 1s → σ* excitation on the polarization angle of the X-rays, the average two-dimensional orientation angle of the π orbital in each position in a natural spherical graphite sample was visualized.
- Published
- 2020