1. APPLICATION OF CHI SQUARE TESTS TO FITTING OF IONIC CONDUCTIVITY
- Author
-
R. J. Friauf
- Subjects
Goodness of fit ,Anomaly (natural sciences) ,Mathematical analysis ,General Engineering ,Chi-square test ,Diffusion (business) ,Atmospheric temperature range ,Conductivity ,Temperature measurement ,Standard deviation ,Mathematics - Abstract
In connection with a study of the high temperature conductivity anomaly for the silver halides, several forms of chi square tests have been applied to determine the statistical validity of the results. First the usual procedure for obtaining a least squares fit of conductivity us. temperature is described. Next a discussion of experimental errors shows that uncertainties in resistance, sample dimensions, and temperature measurements may give an accumulated error of around 0.5 %, and that this per cent error should be independent of temperature to a good first approximation. A chi square test is then described for the distribution of deviations in an inter-mediate temperature range, and it is shown that in favorable cases the errors can be described satisfactorily by a normal error distribution with a mean of zero and a standard deviation of 0.39 % for AgCl and 0.43 % for AgBr. Finally a second form of chi square test is described to measure the goodness of fit of the fitting function based on the defect model for the conductivity. It is shown that the value of chi square increases rapidly as the upper end of the intermediate temperature region is extended into the higher temperature region where the anomaly occurs, thereby providing a rather clearly defined upper temperature limit for an acceptable fit. It is concluded that these uses of the chi square test have played an important role in the present study, and that similar uses should be valuable for analyzing the experimental results of other studies of diffusion and ionic conductivity.
- Published
- 1973