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1. A Novel, One-Step Palladium and Phenylsilane Activated Amidation from Allyl Ester on Solid Support.

Author

Zheming Ruan, Van Kirk, Katy, Cooper, Christopher B., and Lawrence, R. Michael

Subjects
*CATALYSIS, *CARBOXYLIC acids, *ORGANIC acids, *PALLADIUM compounds, *ESTERS, *ORGANIC compounds, *ORGANIC solvents, *ACIDS
Abstract

The direct conversion of solid-supported carboxylic acid allyl esters to carboxamides through the use of phenylsilane and catalytic Pd(PPh3)4 under mild reaction conditions is reported. The use of this methodology for the generation of a 48 compound solidphase array is described herein. [ABSTRACT FROM AUTHOR]

Published
2008
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