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The present study focuses on the comparative analysis of superparamagnetic iron oxide nanoparticles (SPIONs) characteristics with the TOPSIS method. The prediction of the characteristics of SPIONs is required for better manufacturing of these nanoparticles. Although the characteristics of these nanoparticles have been investigated, no research has been done on their comparison in order to determine which one of their surface functionalities would be more appropriate for their diverse applications. The objective of this study was to analyze the characteristics of SPIONs without or with surface charge with a prediction model and TOPSIS in order to determine the best nanoparticles. Moreover, the effect of inappropriate consideration of their cost criterion on their ranks was explored with the modified TOPSIS. This analysis showed that the characteristics of SPIONs such as antibiofilm activity, hemocompatibility, activity with hydrogen peroxide, rheological properties, and the labour of their chemical synthesis could affect their ranking. Neutral SPIONs, negatively charged SPIONs, and positively charged SPIONs were ranked as the first, second, and third candidates, respectively. However, the improvement of the activity of positively charged SPIONs with hydrogen peroxide showed an increase to 0.3 instead of 0.2, which resulted in a better rank of these nanoparticles in comparison with that of the same nanoparticles in the first analysis series. One of the advantages of this study was to determine the impact of the characteristics of SPIONs on their ranking for their manufacturing. The other advantage was getting the information for further comparative study of these nanoparticles with the others. The results of this work can be used in manufacturing engineering and materials science.

The present study focuses on the rheological properties of polyethylene glycol (PEG) modified, positively charged, and negatively charged superparamagnetic iron oxide nanoparticles (SPIONs) at different temperatures. We hypothesized that the surface properties of these nanoparticles in the water did not affect their rheological properties. These nanoparticles had not the same surface properties as SPIONs-PEG had not to charge on their surface whereas positively charged and negatively charged ones with amine and carboxyl groups as their surfaces had positive and negative surface charges, respectively. However, their rheological behaviors were not different from each other. The comparative rheological study of SPIONs revealed their pseudo-Newtonian behavior. The viscosity of SPIONs decreased with the increase in temperature. At low shear rates, the shear stress of SPIONs was independent of rate and increased with the increase of rate. Moreover, at high shear rates, the shear stress for PEG-SPIONs was more than those for positively charged and negatively charged SPIONs. These measurements also revealed that at high shear rates, the shear stress of samples decreased with the increase of temperature. The shear stress of samples decreased with the increase of shear strain and the temperature. We also observed that all the samples had the same amount of shear strain at each shear stress, which indicated the exact resistance of SPIONs to deformation. Furthermore, the shear modulus decreased with time for these nanoparticles. These results suggest that these nanoparticles are promising candidates with appropriate properties for fluid processing applications and drug vectors in biomedical applications.