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1. Intercalação Eletroquímica de Cátions Hexilamínio na Matriz Lamelar 1T-TiS2

Author

Ireno Denicoló, Luciana B. Adad, Fernando Wypych, and Maria A.B. Gomes

Subjects
Steric effects, Stereochemistry, Intercalation (chemistry), General Chemistry, Electrochemistry, Crystallography, chemistry.chemical_compound, symbols.namesake, chemistry, electrochemistry, Ternary compound, titanium disulfide, symbols, van der Waals force, intercalation compounds
Abstract

The electrochemical synthesis of a ternary compound obtained by the intercalation of hydrated hexilaminium cations into the layered compound 1T-TiS2 is reported. Two different compounds were detected by cyclovoltammetry and studied by X-ray diffractometry. Models showing the steric arrangement of the hydrated hexilaminium cations into the Van der Waals gaps were proposed.

Published
1997

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