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Abstract In the present paper, we reported the luminescence properties of BiOCl:Dy(3+) and BiOCl:Dy(3+), Li+ phosphor synthesized by conventional solid state method. X-ray diffraction (XRD) and excitation and emission spectroscopy were used to characterize the samples. Results show that pure tetragonal BiOCl:Dy(3+) crystals can be synthesized successfully at 500 °C, and Li+ ion dopant improves the crystallinity of samples furtherly. Under near UV light excitation, the samples,give the characteristic luminescence of Dy(3+) ions located at 478 (blue) and 574 nm (yellow), which show a low yellow-to-blue intensity ratio (Y/B) of Dy(3+) emission and white light emission. Moreover, codoping of Li+ ion can realize the enhancement of emission intensity and the adjustment of emission color. The characteristics of BiOCl:Dy(3+) phosphor, low temperature preparation, good near ultraviolet excitation and white light emission make it to a promising near-ultraviolet WLED phosphor.