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1. Molecular Editing of Pyrroles to Benzenes/Naphthalenes by N 2 O Deletion.

Author

Xiao WJ, Li CX, Lv JY, Xu S, Shi WX, Su XC, Xue JY, Huang BQ, Zou Y, Yan M, and Zhang XJ

Abstract

A molecular editing reaction for converting pyrrole rings into benzene rings through a sequential pathway of Diels-Alder and cheletropic reactions was developed. The nitrogen atom in a N-bridged intermediate is eliminated in the form of N 2 O by a strain-releasing pathway, ultimately leading to the formation of substituted benzene and naphthalene derivatives., (© 2024 Wiley-VCH GmbH.)

Published
2024
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