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Direct air capture (DAC) in combination with storage of CO 2 can lower atmospheric CO 2 concentrations. This study investigates the environmental impact of a new fast-swing solid sorbent DAC system, including CO 2 transport and storage, over its life cycle, using prospective life cycle assessment. This DAC technology is currently on technology readiness level 5 and is expected to operate on an industrial scale by 2030. The technology was upscaled to the industrial scale and future changes in the background over the lifetime of the system were included, such as electricity grid mix decarbonization. Environmental trade-offs for the new DAC system were assessed by comparing environmental benefits from CO 2 sequestration with environmental burdens from production, operation and decommissioning. We considered three electricity generation configurations: grid-connected, wind-connected, and a hybrid configuration. We found net environmental benefits for all configurations and background scenarios for ecosystem damage and climate change. Net human health benefits were observed when the electricity grid decarbonizes quickly and without the use of a battery. The environmental benefits increase with decreasing electricity footprint and are comparable with other DAC technologies. This illustrates that the new DAC system can help to meet the climate goals., (© 2024. The Author(s).)

Tandem photovoltaics applying perovskite on silicon are considered to be a possible route to sustaining continuous efficiency improvements and price reductions. A meaningful market share for such tandems is, however, at least a decade away. Herein, a comprehensive prospective life cycle assessment was conducted, comparing the full life cycle of monofacial and bifacial silicon/perovskite tandem panels with single-junction silicon panels produced up to 2050. The end-of-life included the recovery of silicon and silver. Climate change impacts per kilowatt hour were projected to decrease by two-thirds over time. Tandem panels are expected to reach impacts of 8-10 g CO 2 -eq/kWh in 2050, while single-junction panels may reach 11-13 g CO 2 -eq/kWh in 2050. Other midpoint impact categories with substantial contributions to damaging human health and ecosystem quality were toxicity, particulate matter formation, and acidification, with tandems having lower impacts in each category. Reductions in impacts over time are mainly the result of grid mix decarbonization and panel efficiency improvements. Balance-of-system and recycling were found to contribute substantially to these impact categories. To ensure that tandem panels provide environmental benefits, annual degradation rates should not exceed 1% for monofacial or 3% for bifacial tandems, and refurbishment of panels with advanced degradation is crucial., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)

Zinc oxide (ZnO) is the most common curing activator used to manufacture tires. To minimize environmental impacts by decreasing the zinc content and rolling resistance of tires, ZnO nanoparticles (NPs) anchored on SiO 2 NPs (ZnO@SiO 2 ) are currently under development as new activators at the pilot scale. Here, we applied prospective life cycle assessment to predict the impacts on human health, ecosystem quality, and resource scarcity of synthesizing ZnO@SiO 2 for the production of passenger car tires at an industrial scale. We found that the life cycle impacts of the synthesis are expected to decrease by 89 to 96% between the pilot and industrial scale. The largest contributors to the synthesis of ZnO@SiO 2 were electricity consumption and waste treatment of the solvent. Using the new activator for tire production led to potential reductions of 9 to 12% in life cycle impacts compared to tires that are currently in use. Those reductions were due to the expected decrease in rolling resistance, leading to lower fuel consumption, which outweighed the additional environmental impacts of the synthesis, as well as the potential decrease in lifetime. Our work highlights an opportunity for manufacturers to mitigate their impacts over the full life cycle of the tire., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)

The current debate on the sustainability of bio-based products questions the environmental benefits of replacing fossil- by bio-resources. Here, we analyze the environmental trade-offs of 98 emerging bio-based materials compared to their fossil counterparts, reported in 130 studies. Although greenhouse gas life cycle emissions for emerging bio-based products are on average 45% lower (-52 to -37%; 95% confidence interval), we found a large variation between individual bio-based products with none of them reaching net-zero emissions. Grouped in product categories, reductions in greenhouse gas emissions ranged from 19% (-52 to 35%) for bioadhesives to 73% (-84 to -54%) for biorefinery products. In terms of other environmental impacts, we found evidence for an increase in eutrophication (369%; 163 to 737%), indicating that environmental trade-offs should not be overlooked. Our findings imply that the environmental sustainability of bio-based products should be evaluated on an individual product basis and that more radical product developments are required to reach climate-neutral targets., (© 2023. The Author(s).)