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Your search keyword '"Vernon D. Parker"' showing total 2 results
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2 results on '"Vernon D. Parker"'

1. THE RATE AND ACTIVATION PARAMETERS FOR THE CLEAVAGE OF THE METAL METAL BOND OF THE ANION RADICAL OF A DI-IRON CARBONYL COMPLEX

Author

Stephen G. Davies, Stephen J. Simpson, and Vernon D. Parker

Subjects
chemistry.chemical_compound, Electron transfer, Crystallography, Cyclopentadiene, Reaction rate constant, chemistry, Dimer, Inorganic chemistry, Molecular Medicine, Activation energy, Electrochemistry, Acetonitrile, Ion
Abstract

Electron transfer to [(C5H5)Fe(CO)2] 2 gives an anion radical in which the electronic configuration of one Fe no longer conforms to the '18 e' rule and which undergoes cleavage of the metal-metal bond with a rate constant equal to 1060 s-1 at 273 K and an activation energy of 15.7 kcal mol-1 (1 kcal = 4.18 kJ) in acetonitrile.

Published
2016

2. Reactivity of Aromatic Radical Cations. Rate Constants for Reactions of 9-Phenyl- and 9,10-Diphenylanthracene Radical Cations with Acyclic Amines

Author

Vernon D. Parker, Mark S. Workentin, Danial D. M. Wayner, and Linda J. Johnston

Subjects
chemistry.chemical_compound, Colloid and Surface Chemistry, Reaction rate constant, Radical-nucleophilic aromatic substitution, Radical ion, Chemistry, Reactivity (chemistry), 9,10-Diphenylanthracene, General Chemistry, Photochemistry, Biochemistry, Catalysis
Published
1994

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