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1. A Family of Lanthanoid‐Sodium Multifunctional Coordination Polymers: Single‐Molecule Magnet, Luminescent and Magnetocaloric Properties.

Author

Troyano, Alejandro Cuesta, González, Jonay, Arauzo, Ana, Bartolomé, Elena, and Sañudo, E. Carolina

Subjects
*COORDINATION polymers, *SINGLE molecule magnets, *RARE earth metals, *DIAMAGNETIC materials, *MAGNETOCALORIC effects
Abstract

In this paper we report the microwave assisted synthesis and characterization of a family of Na−Ln coordination polymers (CPs) of formula [NaDy2(MeCOO)2(SALOH)5(chpH)2] (1Ln, Ln=Eu, Gd, Tb, Dy, Ho, Y). The Na+ cations isolate Ln2 units in a one‐dimensional polymer. By changing the lanthanoid ions, we attain Single Molecule Magnet properties (1Dy), luminescent properties (1Eu, 1Tb, 1Ho), a diamagnetic material (1Y) and a material that presents magnetocaloric effect (1Gd). [ABSTRACT FROM AUTHOR]

Published
2024
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