1. Remote molecular composition analysis of laser-ablated material.
- Author
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Lubin, Philip, Pelizzo, Maria G., Erlikhman, Jacob, Cohen, Alexander N., Madajian, Jonathan, Meinhold, Peter, Hughes, Gary B., Rupert, Nicholas, and Srinivasan, Prashant
- Subjects
MATERIALS analysis ,REFLECTIVE materials ,ABSORPTION spectra ,COLLISION induced dissociation ,MOLECULAR spectroscopy ,OPTICS ,ULTRAVIOLET lasers - Abstract
A novel method is described for remotely interrogating bulk molecular composition of rocky materials. Laser energy heats a local area on the substrate; flux is optimized to melt and evaporate target constituents with low rates of molecular dissociation. Substrate temperature rises until an equilibrium is established between incident flux and latent phase-change energies, reaching ˜2500 K in vacuum. A blackbody signal is emitted by the heated spot, traveling outward through the evaporated material; reflective optics direct the signal into a spectrometer. Ro-vibrational absorption in the plume provides a diagnostic for identifying bulk molecular composition of the substrate. Absorption spectra are modeled for compounds with available a priori molecular cross-sections, based on laser and receiver characteristics, and target material properties. Mass ejection flux drives the plume density profile. Qualitative, species-specific spectral profiles are derived by integrating molecular cross section along a path through the plume. Simulations indicate robust absorption profiles. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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