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1. New Synthesis of Isoquinoline Derivatives by Reactions of 2-(2-Methoxyethenyl)benzonitriles with Organolithiums and Lithium Dialkylamides.

Author

Kobayashi, Kazuhiro, Shiokawa, Taiyo, Morikawa, Osamu, and Konishi, Hisatoshi

Subjects
ISOQUINOLINE, QUINOLINE, RING formation (Chemistry), CHEMICAL reactions, LITHIUM
Abstract

A simple and efficient synthesis of 1-alkyl(or aryl)isoquinoline and isoquinolin-1-amine derivatives based on intramolecular cyclization of 2-(2-methoxyethenyl)benzonitriles initiated by the addition of alkyl(or aryl)lithiums and lithium dialkylamides to the nitrile carbons, respectively, is described. [ABSTRACT FROM AUTHOR]

Published
2004
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