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Pure chitosan (CS) and hybrid ionic liquid-chitosan membranes loaded with 5 wt% 1-ethyl-3-methylimidazolium acetate ([emim][Ac]) ionic liquid were prepared in order to improve the thermal behavior of supported ionic liquid membranes (SILMs) for CO2 separation. Gas permeability, solubility and diffusivity were evaluated in the temperature range 298-323 K. The temperature influence was well described in terms of the Arrhenius-van't Hoff exponential relationships. Activation energies were calculated and compared with those obtained for SILMs with the same ionic liquid. The introduction of this ionic liquid in the hybrid solid membrane decreases the permeability activation energy, leading to a lower influence of the temperature in the permeability and diffusivity. Moreover, the thermal behavior is similar to pure chitosan membranes, and the mechanical strength and flexibility were improved due to the introduction of the ionic liquid in the polymer matrix. [ABSTRACT FROM AUTHOR]

The Kardar-Parisi-Zhang (KPZ) equation is a paradigmatic model of nonequilibrium low-dimensional systems with spatiotemporal scale invariance, recently highlighting universal behavior in fluctuation statistics. Its space derivative, namely the noisy Burgers equation, has played a very important role in its study, predating the formulation of the KPZ equation proper, and being frequently held as an equivalent system. We show that, while differences in the scaling exponents for the two equations are indeed due to a mere space derivative, the field statistics behave in a remarkably different way: while the KPZ equation follows the Tracy-Widom distribution, its derivative displays Gaussian behavior, hence being in a different universality class. We reach this conclusion via direct numerical simulations of the equations, supported by a dynamic renormalization group study of field statistics. [ABSTRACT FROM AUTHOR]

Symmetries play a conspicuous role in the large-scale behavior of critical systems. In equilibrium they allow us to classify asymptotics into different universality classes, and out of equilibrium, they sometimes emerge as collective properties which are not explicit in the "bare" interactions. Here we elucidate the emergence of an up-down symmetry in the asymptotic behavior of the stochastic scalar Burgers equation in one and two dimensions, manifested by the occurrence of Gaussian fluctuations even within the time regime controlled by nonlinearities. This robustness of Gaussian behavior contradicts naive expectations due to the detailed relation--including the lack of up-down symmetry--between the Burgers equation and the Kardar-Parisi-Zhang equation, which paradigmatically displays non-Gaussian fluctuations described by Tracy-Widom distributions. We reach our conclusions via a dynamic renormalization group study of the field statistics, confirmed by direct evaluation of the field probability distribution function from numerical simulations of the dynamical equation. [ABSTRACT FROM AUTHOR]

We study numerically a family of surface growth models that are known to be in the universality class of the Kardar-Parisi-Zhang equation when driven by uncorrelated noise. We find that, in the presence of noise with power-law temporal correlations with exponent θ, these models exhibit critical exponents that differ both quantitatively and qualitatively from model to model. The existence of a threshold value for θ below which the uncorrelated fixed point is dominant occurs for some models but not for others. In some models the dynamic exponent z(θ) is a smooth decreasing function, while it has a maximum in other cases. Despite all models sharing the same symmetries, critical exponents turn out to be strongly model dependent. Our results clearly show the fragility of the universality class concept in the presence of long-range temporally correlated noise.

The scaling behavior of the excited energy states of the directed polymer in random media is analyzed numerically. We find that the spatial correlations of polymer energies scale as ∼k^{-δ} for small enough wave numbers k with a nontrivial exponent δ≈1.3. The equivalence between the stochastic-field equation that describes the partition function of the directed polymer and that governing the time evolution of infinitesimal perturbations in space-time chaos is exploited to connect this exponent δ with the spatial correlations of the Lyapunov vectors reported in the literature. The relevance of our results for other problems involving optimization in random systems is discussed.

The one-dimensional Kardar-Parisi-Zhang (KPZ) equation is becoming an overarching paradigm for the scaling of nonequilibrium, spatially extended, classical and quantum systems with strong correlations. Recent analytical solutions have uncovered a rich structure regarding its scaling exponents and fluctuation statistics. However, the zero surface tension or zero viscosity case eludes such analytical solutions and has remained ill-understood. Using numerical simulations, we elucidate a well-defined universality class for this case that differs from that of the viscous case, featuring intrinsically anomalous kinetic roughening (despite previous expectations for systems with local interactions and time-dependent noise) and ballistic dynamics. The latter may be relevant to recent quantum spin chain experiments which measure KPZ and ballistic relaxation under different conditions. We identify the ensuing set of scaling exponents in previous discrete interface growth models related with isotropic percolation, and show it to describe the fluctuations of additional continuum systems related with the noisy Korteweg-de Vries equation. Along this process, we additionally elucidate the universality class of the related inviscid stochastic Burgers equation.