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Due to its unique layered structure, bismuth oxychloride (BiOCl) has potential applications as a photocatalytic material in clean energy utilization and environmental purification. In recent years, researchers have carried out a lot of studies and made important progress for the preparation and performance enhancement of BiOCl. In this review, the charge separation property of BiOCl was analyzed based on the crystal structure and electronic structure. Subsequently, the common preparation method of BiOCl was expounded, and the growth mechanism of BiOCl was introduced. Furthermore, the strategies for modulating the photocatalytic performance of BiOCl via doping, vacancy creation, internal electric field tuning, co-catalysts modification, composites construction and sensitizers using were summarized. Finally, in view of the current research status of BiOCl photocatalytic material, some problems still need to be addressed include exploring the method of controlled synthesis of other high energy surface BiOCl, developing advanced characterization methods to clarify the detailed transfer path of photogenerated charge and expanding the photocatalytic application range of BiOCl.

Imaging concentrators like the parabolic trough solar concentrators have been widely employed for energy production in solar power plants. The conventional imaging solar concentrators form a non-uniform Gaussian distribution on receiving absorbers yielding the highest temperatures. The traditional CSP system normally truncated a peripheral region of heat flux to better use the central part. CPV/T systems using the waste heat recovery method can largely improve the total efficiency. However, for the CPV module, the coolant temperature was usually below 80 °C, which limited the applications of the thermal cycle such as the ORC system. In this article, a novel trough-type free-form secondary solar concentrator (TFSC) for PV/Thermal hybrid application has been proposed. Different from other CPV/T concepts using a combined PV panel and cooling tunnel/tube, the current concept separates the receiver in two parts. The secondary free-form reflector is generated by the geometric construction method, resulting in uniform heat flux in the edge region and high concentration in the central region. Through the ray tracing method, the optical properties have been verified. Sensitivity analysis of the concentrating structure is also conducted. The results provide supports for the design and applications of novel CPV/T systems. [ABSTRACT FROM AUTHOR]

Background: Limited knowledge exists regarding the casual associations linking blood metabolites and the risk of developing colorectal cancer., Aim: To investigate causal associations between blood metabolites and colon cancer., Methods: The study utilized a two-sample Mendelian randomization (MR) analysis to investigate the causal impact of 486 blood metabolites on colorectal cancer. The primary method of analysis used was the inverse variance weighted model. To further validate the results several sensitivity analyses were performed, including Cochran's Q test, MR-Egger intercept test, and MR robust adjusted profile score. These additional analyses were conducted to ensure the reliability and robustness of the findings., Results: After rigorous selection for genetic variation, 486 blood metabolites were included in the MR analysis. We found Mannose [odds ratio (OR) = 2.09 (1.10-3.97), P = 0.024], N-acetylglycine [OR = 3.14 (1.78-5.53), P = 7.54 × 10 -8 ], X-11593-O-methylascorbate [OR = 1.68 (1.04-2.72), P = 0.034], 1-arachidonoylglycerophosphocholine [OR = 4.23 (2.51-7.12), P = 6.35 × 10 -8 ] and 1-arachidonoylglycerophosphoethanolamine 4 [OR = 3.99 (1.17-13.54), P = 0.027] were positively causally associated with colorectal cancer, and we also found a negative causal relationship between Tyrosine [OR = 0.08 (0.01-0.63), P = 0.014], Urate [OR = 0.25 (0.10-0.62), P = 0.003], N-acetylglycine [0.73 (0.54-0.98), P = 0.033], X-12092 [OR = 0.89 (0.81-0.99), P = 0.028], Succinylcarnitine [OR = 0.48 (0.27-0.84), P = 0.09] with colorectal cancer. A series of sensitivity analyses were performed to confirm the rigidity of the results., Conclusion: This study showed a causal relationship between 10 blood metabolites and colorectal cancer, of which 5 blood metabolites were found to be causal for the development of colorectal cancer and were confirmed as risk factors. The other five blood metabolites are protective factors., Competing Interests: Conflict-of-interest statement: All the authors report no relevant conflicts of interest for this article., (©The Author(s) 2024. Published by Baishideng Publishing Group Inc. All rights reserved.)