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We explore the magnetic properties of isolated a − b planes of trinuclear organometallic crystals, Mo3S7(dmit)3, in which an interplay of strong electronic correlations and spin molecular-orbital coupling (SMOC) occurs. The magnetic properties can be described by a XXZ+1200, S = 1 Heisenberg model on a honeycomb lattice with single-spin anisotropy, D, which depends strongly on SMOC. Based on ab initio estimates of SMOC in Mo3S7(dmit)3 crystals, we predict that the honeycomb layers of Mo3S7(dmit)3 are Néel ordered. However, in materials with a greater degree of magnetic frustration, Néel order can give way to a large-D phase. [ABSTRACT FROM AUTHOR]

We study the phase diagram of the extended Hubbard model on the kagome lattice at 1/3 filling. By combining a configuration interaction approach to an unrestricted Hartree-Fock, we construct an effective Hamiltonian which takes the correlations back on top of the mean-field solution. We obtain a rich phase diagram with, in particular, the presence of two original phases. The first one consists of local polarized droplets of metal standing on the hexagons of the lattice and an enlarged kagome charge order, inversely polarized, on the remaining sites. The second, obeying a local ice-rule type constraint on the triangles of the kagome lattice, is driven by an antiferromagnetic coupling of spins and is constituted of disconnected six-spin singlet rings. The nature and stability of these phases at large interactions are studied via trial wave functions and perturbation theory. [ABSTRACT FROM AUTHOR]

We study charge ordering driven by Coulomb interactions on triangular lattices relevant to the Wigner-Mott transition in two dimensions. Dynamical mean-field theory reveals the pinball liquid phase, a charge ordered metallic phase containing quasilocalized (pins) coexisting with itinerant (balls) electrons. Based on an effective periodic Anderson model for this phase, we find an antiferromagnetic Kondo coupling between pins and balls and strong quasiparticle renormalization. Non-Fermi liquid behavior can occur in such charge ordered systems due to the spin-flip scattering of itinerant electrons off the pins in analogy with heavy fermion compounds. [ABSTRACT FROM AUTHOR]

Band ferromagnetism in strongly correlated electron systems is one of the most challenging issues in today's condensed-matter physics. In this theoretical work, we study the competition between kinetic term, Coulomb repulsion, and on-site correlated disorder for various lattice geometries. Unconventional and complex ferromagnetic phase diagrams are obtained: wide region of stability, cascade of transitions, re-entrance, high sensitivity to the carrier concentration and strongly inhomogeneous ground states for relatively weak on-site potential. The direct and systematic comparison with exact diagonalization shows that the unrestricted Hartree-Fock method is unexpectedly accurate for such systems, which allows large-size cluster calculations. A match of the order of 99.9% for weak and intermediate couplings is found, slightly reduced to about 95% in the large-repulsion regime. Nano-patterned lattices appear to be particularly promising candidates that could, with the tremendous progress in growing and self-organized techniques, be synthesized in the near future. [ABSTRACT FROM AUTHOR]

We study a model for orbitally degenerate Mott insulators, where localized electrons possess t2g degrees of freedom coupled by several, competing, exchange mechanisms. We provide evidence for two distinct strongly fluctuating regimes, depending on whether superexchange or direct exchange mechanism predominates. In the superexchange-dominated regime, the ground state is dimerized, with nearest-neighbor orbital singlets covering the lattice. By deriving an effective quantum dimer model and analyzing it numerically, we characterize this dimerized phase as a valence bond crystal stabilized by singlet resonances within a large unit cell. In the opposite regime, with predominant direct exchange, the combined analysis of the original model and another effective model adapted to the local constraints shows that subleading perturbations select a highly resonating ground state, with coexisting diagonal and off-diagonal long-range orbital orders [ABSTRACT FROM AUTHOR]

The phase diagram of the XXZ spin-1/2 magnet, equivalent to hard-core bosons, under a staggered magnetic field and on the Cairo pentagonal lattice is computed at zero and finite temperature by using a cluster mean-field theory and a stochastic series expansion quantum Monte Carlo. The complex connectivity and the frustration lead to unconventional phases such as a 1/3 ferrimagnetic plateau stabilized by quantum fluctuations as well as a 5/12 topological phase induced by a local ice-rule constraint. We also report the presence of a ferrimagnetic superfluid and its thermal melting. Finally, we discuss the ferro- and antiferro- magnetic (hopping sign) cases. [ABSTRACT FROM AUTHOR]

Quantum magnets with pure Kitaev spin exchange interactions can host a gapped quantum spin liquid with a single Majorana edge mode propagating in the counterclockwise direction when a small positive magnetic field is applied. Here, we show how under a sufficiently strong positive magnetic field a topological transition into a gapped quantum spin liquid with two Majorana edge modes propagating in the clockwise direction occurs. The Dzyaloshinskii-Moriya interaction is found to turn the nonchiral Kitaev's gapless quantum spin liquid into a chiral one with equal Berry phases at the two Dirac points. Thermal Hall conductance experiments can provide evidence of the novel topologically gapped quantum spin liquid states predicted. [ABSTRACT FROM AUTHOR]

We show that introducing long-range Coulomb interactions immediately lifts the massive ground state degeneracy induced by geometric frustration for electrons on quarter-filled triangular lattices in the classical limit. Important consequences include the stabilization of a stripe-ordered crystalline (global) ground state, but also the emergence of very many low-lying metastable states with amorphous "stripe-glass" spatial structures. Melting of the stripe order thus leads to a frustrated Coulomb liquid at intermediate temperatures, showing remarkably slow (viscous) dynamics, with very long relaxation times growing in Arrhenius fashion upon cooling, as typical of strong glass formers. On shorter time scales, the system falls out of equilibrium and displays the aging phenomena characteristic of supercooled liquids above the glass transition. Our results show remarkable similarity with the recent observations of charge-glass behavior in ultraclean triangular organic materials of the θ-(BEDT-TTF)2 family. [ABSTRACT FROM AUTHOR]

We study the ground-state properties of a frustrated two-species mixture of hard-core bosons on a triangular lattice, as a function of tunable amplitudes for tunneling and interactions. By combining three different methods, a self-consistent cluster mean-field, exact diagonalization, and effective theories, we unravel a very rich and complex phase diagram. More specifically, we discuss the existence of three original mixture supersolids: (i) a commensurate with frozen densities and supersolidity in spin degrees of freedom, in a regime of strong interspecies interactions; and (ii) when this interaction is weaker, two mutually competing incommensurate supersolids. Finally, we show how these phases can be stabilized by a quantum fluctuation enhancement of peculiar insulating parent states. [ABSTRACT FROM AUTHOR]

We perform an extensive study of Sr3Cr2O7, the n=2 member of the Ruddlesden-Popper Srn+1CrnO3n+1 system. An antiferromagnetic ordering is clearly visible in the magnetization and the specific heat, which yields a huge transition entropy, Rln(6). By neutron diffraction as a function of temperature we have determined the antiferromagnetic structure that coincides with the one obtained from density functional theory calculations. It is accompanied by anomalous asymmetric distortions of the CrO6 octahedra. Strong coupling and Lanczos calculations on a derived Kugel-Khomskii Hamiltonian yield a simultaneous orbital and moment ordering. Our results favor an exotic ordered phase of orbital singlets not originated by frustration. [ABSTRACT FROM AUTHOR]

We carefully revisit the electron-boson scattering problem, going beyond weak-coupling expansions and popular semiclassical treatments. By providing numerically exact results valid at finite temperatures, we demonstrate the existence of a broad regime of electron-boson scattering where quantum localization processes become relevant despite the absence of extrinsic disorder. Localization in the Anderson sense is caused by the dynamical randomness resulting from a large thermal boson population, being, however, effective only at transient times before diffusion can set in. Compelling evidence of this transient localization phenomenon is provided by the observation of a distinctive displaced Drude peak in the optical absorption and the ensuing suppression of conductivity. Our findings identify a general route for anomalous metallic behavior that can broadly apply in interacting quantum matter.

We present a mechanical analog of a quantum wave-particle duality: a vibrating string threaded through a freely moving bead or "masslet." For small string amplitudes, the particle movement is governed by a set of nonlinear dynamical equations that couple the wave field to the masslet dynamics. Under specific conditions, the particle achieves a regime of transparency in which the field and the particle's dynamics appear decoupled. In that special case, the particle conserves its momentum and a guiding wave obeying a Klein-Gordon equation, with real or imaginary mass, emerges. Similar to the double-solution theory of de Broglie, this guiding wave is locked in phase with a modulating group wave comoving with the particle. Interestingly, both subsonic and supersonic particles can fall into a quantum regime as is the case with the slower-than-light bradyons and hypothetical, faster-than-light tachyons of particle physics.

It is well known that the low-energy sector of quantum spin liquids and other magnetically disordered systems is governed by short-ranged resonating-valence bonds. Here we show that the standard minimal truncation to the nearest-neighbor valence-bond basis fails completely even for systems where it should work the most, according to received wisdom. This paradigm shift is demonstrated for the quantum spin-1/2 square kagome, where strong geometric frustration, similar to the kagome, prevents magnetic ordering down to zero temperature. The shortest tunneling events bear the strongest longer-range singlet fluctuations, leading to amplitudes that do not drop exponentially with the length of the loop L, and to an unexpected loop-six valence-bond crystal, which is otherwise very high in energy at the minimal truncation level. The low-energy effective description gives in addition a clear example of correlated loop processes that depend not only on the type of the loop but also on its lattice embedding, a direct manifestation of the long-range nature of the virtual singlets.

We investigate the organized formation of strain, ripples, and suspended features in macroscopic graphene sheets transferred onto corrugated substrates made of an ordered array of silica pillars with variable geometries. Depending on the pitch and sharpness of the corrugated array, graphene can conformally coat the surface, partially collapse, or lie fully suspended between pillars in a fakir-like fashion over tens of micrometers. With increasing pillar density, ripples in collapsed films display a transition from random oriented pleats emerging from pillars to organized domains of parallel ripples linking pillars, eventually leading to suspended tent-like features. Spatially resolved Raman spectroscopy, atomic force microscopy, and electronic microscopy reveal uniaxial strain domains in the transferred graphene, which are induced and controlled by the geometry. We propose a simple theoretical model to explain the structural transition between fully suspended and collapsed graphene. For the arrays of high density pillars, graphene membranes stay suspended over macroscopic distances with minimal interaction with the pillars' apexes. It offers a platform to tailor stress in graphene layers and opens perspectives for electron transport and nanomechanical applications.

Bosonic and fermionic Hubbard models on the checkerboard lattice are studied numerically for infinite on-site repulsion. At particle density n=1/4 and strong nearest-neighbor repulsion, insulating Valence-Bond crystals (VBC) of resonating particle pairs are stabilized. Their melting into superfluid or metallic phases under increasing hopping is investigated at T=0 K. We identify a novel and unconventional commensurate VBC supersolid region, precursor to the melting of the bosonic crystal. Hardcore bosons (spins) are compared to fermions (electrons), as well as positive to negative (frustrating) hoppings.

The effect of a magnetic field on a gapped quantum magnet is described within the framework of the quantum dimer model. A minimal model describing the proliferation of itinerant spinons above a critical field is proposed and investigated by Lanczos exact diagonalizations and quantum Monte Carlo simulations. For both square and triangular lattices, it is shown that spinons are fully polarized and Bose condense. This offers a novel scenario of a quantum critical point in the dimer-liquid phase (triangular lattice) characterized by the continuous appearance of a spinon superfluid density, contrasting with the usual triplet condensation picture. The possible role of other spinon kinetic terms neglected in the model are discussed.

The doped two-dimensional quantum dimer model is investigated by numerical techniques on the square and triangular lattices, with significantly different results. On the square lattice, at small enough doping, there is always a phase separation between an insulating valence-bond solid and a uniform superfluid phase, whereas on the triangular lattice, doping leads directly to a uniform superfluid in a large portion of the resonating-valence-bond (RVB) phase. Under an applied Aharonov-Bohm flux, the superfluid exhibits quantization in terms of half-flux quanta, consistent with Q=2e elementary charge quanta in transport properties.