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We investigate the growth of crystals in Zr50Ti50 melts by classical molecular-dynamics simulations with an embedded atom method and a Stillinger–Weber potential model. Both models display fast solidification rates that can be captured by the transition state theory or the Ginzburg–Landau theory at small undercoolings. Fast crystal-growth rates are found to be affected by the pre-existing ordering in liquids, such as the body-centered cubic-like and icosahedral-like structures. The interface-induced ordering unveiled by the crystal-freezing method can explain the rate difference between these two models. However, these orderings fail to rationalize the temperature evolution of the growth rate at deep undercoolings. We correlate the growth kinetics with the detailed dynamical processes in liquids, finding the decoupling of hierarchic relaxation processes when collective motion emerges in supercooled liquids. We find that the growth kinetics is nondiffusive, but with a lower activation barrier corresponding to the structural relaxation or the cage-relative motion in ZrTi melts. These results explore a new relaxation mechanism for the fast growth rate in deeply undercooled liquids. [ABSTRACT FROM AUTHOR]

The Haiyang-2D (HY2D) satellite is the fourth ocean dynamics environment monitoring satellite launched by China. The satellite operates on a re-entry frozen orbit, which necessitates orbital maneuvers to maintain its designated path once the satellite's sub-satellite point deviates beyond a certain threshold. However, the execution of orbit maneuvers presents a significant challenge to the field of Precise Orbit Determination (POD). The thesis selects the on-board GPS data of HY2D satellite in December 2023 and five maneuvering days of that year. Employing a multifaceted approach that includes the assessment of observational data quality, orbit overlap, external orbit validation, and SLR (Satellite Laser Ranging) verification, the research delves into precise orbit determination during both maneuver and non-maneuver periods. The results indicate that: (1) The average number of satellites tracked by the receiver is 6.4; (2) During the non-maneuver periods, the average RMS (Root Mean Square) value of the radial difference in the 6-h overlapping arc segment is 0.66 cm, and the three-dimensional position difference is about 1.16 cm; (3) When compared with the precision science orbits (PSO) provided by CNES (Centre National d'Études Spatiales), the average values of the RMS values of the differences in the radial (R), transverse (T), and normal (N) directions during the non-maneuver and maneuver periods are respectively 1.32 cm, 2.31 cm, 1.92 cm and 3.04 cm, 8.78 cm, 2.72 cm. (4) The SLR verification of the orbit revealed a residual RMS of 2.24 cm. This suggests that by incorporating the modeling of maneuver forces during the maneuver periods, the impact of orbital maneuvers on orbit determination can be mitigated. [ABSTRACT FROM AUTHOR]

In this paper, a matching method for altimeter and transponder signals in Sub-optimal Maximum Likelihood Estimate (SMLE) tracking mode is proposed. In the in-orbit calibration of the altimeter in SMLE tracking mode using the reconstructive transponder, it is necessary to separate the forwarding signal from the ground echo signal. At the same time, the fluctuations in the received signal of the altimeter, which are caused by the forwarding signal of the transponder, can be eliminated. The transponder generates a bias when measuring the arrival time of the transmitting signal from the altimeter and embeds this bias in both the transponder-recorded data and the altimeter-recorded data. Therefore, the two sets of data have one-to-one correspondence, and they are superimposed using the sliding sum method. Moreover, the distance between the altimeter and the transponder is a parabolic geometric relationship, and the outliers are eliminated by the fitting error minimization decision, and the transponder signal is separated from the ground echo. The final altimeter transmitting–receiving signal path is obtained. Furthermore, the principles underlying this method can be used for any transponder that can adjust the response signal delay during calibration. [ABSTRACT FROM AUTHOR]

Surface induces many fascinating physical phenomena, such as dynamic acceleration, surface anchoring, and orientational wetting, and, thus, is of great interest to study. Here, we report classic molecular dynamics simulations on the free-standing surface of imidazolium-based ionic liquids (ILs) [C4mim][PF6] and [C10mim][PF6]. On [C10mim][PF6] surface, a significant orientational wetting is observed, with the wetting strength showing a diverging tendency. Depth of the wetting was captured from the density and orientational order profile by a static length, which remarkably increases below the temperature Tstat upon cooling down. The dynamical correlation length that measures the distance of surface-dynamics acceleration into the bulk was characterized via the spatial-dependent mobility. The translational correlation exhibits a similar drastic increment at Tstat, while the rotational correlation drastically increases at a lower temperature Trot. We connect these results to the dynamics in bulk liquids, by finding Tstat and Trot that correspond to the onset temperatures where the liquids become cooperative for translational and rotational relaxation, respectively. This signifies the importance of collective dynamics in the bulk on the orientational wetting and surface dynamics in the ILs. [ABSTRACT FROM AUTHOR]

In order to accomplish the calibration and validation (Cal/Val) of altimeters, the Wanshan calibration site (WSCS) has been used as a calibration site for satellite altimeters since its completion in August 2019. In this paper, we introduced the WSCS and the dedicated equipment including permanent GNSS reference stations (PGSs), acoustic tide gauges (ATGs), and dedicated GNSS buoys (DGB), etc. placed on Zhi'wan, Wai'ling'ding, Dan'gan, and Miao'Wan islands of the WSCS. The PGSs data of Zhi'wan and Wai'ling'ding islands were processed and analyzed using the GAMIT/GLOBK (Version 10.7) and Hector (Version 1.9) software to define the datum for Cal/Val of altimeters in WSCS. The DGB was used to transfer the datum from the PGSs to the ATGs of Zhi'wan, Wai'ling'ding, and Dan'gan islands. Separately, the tidal and mean sea surface (MSS) corrections are needed in the Cal/Val of altimeters. We evaluated the global/regional tide models of FES2014, HAMTIDE12, DTU16, NAO99jb, GOT4.10, and EOT20 using the three in situ tide gauge data of WSCS and Hong Kong tide gauge data (No. B329) derived from the Global Sea Level Observing System. The HAMTIDE12 tide model was chosen to be the most accurate one to maintain the tidal difference between the locations of the ATGs and the altimeter footprints. To establish the sea surface connections between the ATGs and the altimeter footprints, a GPS towing body and a highly accurate ship-based SSH measurement system (HASMS) were used to measure the sea surface of this area in 2018 and 2022, respectively. The global/regional mean sea surface (MSS) models of DTU 2021, EGM 2008 (mean dynamic topography minus by CLS_MDT_2018), and CLS2015 were accurately evaluated using the in situ measured data and HY-2A altimeter, and the CLS2015 MSS model was used for Cal/Val of altimeters in WSCS. The data collected by the equipment of WSCS, related auxiliary models mentioned above, and the sea level data of the hydrological station placed on Dan'gan island were used to accomplish the Cal/Val of HY-2B, HY-2C, Jason-3, and Sentinel-3A (S3A) altimeters. The bias of HY-2B (Pass No. 375) was −16.7 ± 45.2 mm, with a drift of 0.5 mm/year. The HY-2C biases were −18.9 ± 48.0 mm with drifts of 0.0 mm/year and −5.6 ± 49.3 mm with −0.3 mm/year drifts for Pass No. 170 and 185, respectively. The Jason-3 bias was −4.1 ± 78.7 mm for Pass No. 153 and −25.8 ± 85.5 mm for Pass No. 012 after it has changed its orbits since April 2022, respectively. The biases of S3A were determined to be −16.5 ± 46.3 mm with a drift of −0.6 mm/year and −9.8 ± 30.1 mm with a drift of 0.5 mm/year for Pass No. 260 and 309, respectively. The calibration results show that the WSCS can commercialize the satellite altimeter calibration. We also discussed the calibration potential for a wide swath satellite altimeter of WSCS. [ABSTRACT FROM AUTHOR]

The ternary cathode material LiNi0.8Co0.1Mn0.1O2 is widely used in lithium batteries, and the sintering process plays a crucial role in its production. Proper configuration of sintering kiln parameters directly affects the quality of LiNi0.8Co0.1Mn0.1O2. However, determining optimal working conditions through onsite trials is time‐consuming and expensive. A predictive model for the sintering furnace of ternary cathode material is developed. The predictive model incorporates chemical reactions, thermal conduction inside the saggars, and convective and radiative heat transfer within the furnace. It comprehensively analyzes the relationship between furnace temperature and material temperature. Radiative heat transfer within the furnace is calculated using the Monte Carlo method, and convective heat transfer properties on the surface of the saggars are obtained through computational fluid dynamics simulations. Heat transfer inside the saggars is resolved using the finite difference method. The model accounts for the effects of operational and structural parameters. Onsite experiments validate the accuracy of the model, with a simulation error of <±10% under typical working conditions. Leveraging this model, the effects of loading quantity, moving velocity, and saggar size on the sintering of ternary cathode materials are compared. Optimization recommendations are proposed to enhance production capacity. [ABSTRACT FROM AUTHOR]