27 results on '"Peel, Matthew"'
Search Results
2. Development of a microstructural cohesive zone model for intergranular hydrogen environmentally assisted cracking
- Author
-
De Francisco, Unai, Larrosa, Nicolas O., and Peel, Matthew J.
- Published
- 2022
- Full Text
- View/download PDF
3. 3D characterisation of hydrogen environmentally assisted cracking during static loading of AA7449-T7651
- Author
-
De Francisco, Unai, Beckmann, Felix, Moosmann, Julian, Larrosa, Nicolas O., and Peel, Matthew J.
- Published
- 2021
- Full Text
- View/download PDF
4. The influence of temperature on hydrogen environmentally assisted cracking of AA7449-T7651 in moist air
- Author
-
De Francisco, Unai, Larrosa, Nicolas O., and Peel, Matthew J.
- Published
- 2021
- Full Text
- View/download PDF
5. From Teams to Teamness: Future Directions in the Science of Team Cognition.
- Author
-
Cooke, Nancy J., Cohen, Myke C., Fazio, Walter C., Inderberg, Laura H., Johnson, Craig J., Lematta, Glenn J., Peel, Matthew, and Teo, Aaron
- Subjects
COGNITION ,TEAMS ,COGNITION research ,RESEARCH questions ,RESEARCH teams - Abstract
Objective: We review the current state-of-the-art in team cognition research, but more importantly describe the limitations of existing theories, laboratory paradigms, and measures considering the increasing complexities of modern teams and the study of team cognition. Background: Research on, and applications of, team cognition has led to theories, data, and measures over the last several decades. Method: This article is based on research questions generated in a spring 2022 seminar on team cognition at Arizona State University led by the first author. Results: Future research directions are proposed for extending the conceptualization of teams and team cognition by examining dimensions of teamness; extending laboratory paradigms to attain more realistic teaming, including nonhuman teammates; and advancing measures of team cognition in a direction such that data can be collected unobtrusively, in real time, and automatically. Conclusion: The future of team cognition is one of the new discoveries, new research paradigms, and new measures. Application: Extending the concepts of teams and team cognition can also extend the potential applications of these concepts. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
6. Hydrogen environmentally assisted cracking during static loading of AA7075 and AA7449
- Author
-
De Francisco, Unai, Larrosa, Nicolas O., and Peel, Matthew J.
- Published
- 2020
- Full Text
- View/download PDF
7. Friction-stir welding of dissimilar aluminium alloys
- Author
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Peel, Matthew J.
- Subjects
671 - Published
- 2005
8. Recognising and responding to non-fatal strangulation in domestic abuse.
- Author
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Peel, Matthew and Cunnion, Katy
- Subjects
- *
WOUNDS & injuries , *NECK injuries , *NURSES , *VICTIMS , *RISK assessment , *OCCUPATIONAL roles , *RESPONSIBILITY , *STALKING , *PSYCHIATRIC nurses , *DOMESTIC violence , *SELF-disclosure , *ABUSED women - Abstract
Why you should read this article: • To update your knowledge of what constitutes non-fatal strangulation • To remember that victims/survivors of non-fatal strangulation often do not disclose the assault • To understand the nurse’s responsibility to respond to suspicions of domestic abuse by initiating safeguarding and protection procedures. Victims/survivors (the authors use this term throughout the article but acknowledge that individuals may use various terms to describe their experiences) of non-fatal strangulation associated with domestic abuse are at risk of further serious harm or death, but often do not disclose the assault. In addition, some of the signs and symptoms are not immediately apparent or obvious. Nurses have a professional responsibility to respond to suspicions about and/or disclosure of any type of domestic abuse by initiating safeguarding and protection procedures and must provide effective care. This article discusses non-fatal strangulation in domestic abuse, including the presenting signs and symptoms and barriers to disclosure, and describes the role of the nurse. The authors include a fictional case study to demonstrate the type of situation nurses may experience when they encounter a victim/survivor of non-fatal strangulation. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
9. Linear friction welding of AISI 316L stainless steel
- Author
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Bhamji, Imran, Preuss, Michael, Threadgill, Philip L., Moat, Richard J., Addison, Adrian C., and Peel, Matthew J.
- Published
- 2010
- Full Text
- View/download PDF
10. Acute behavioural disturbance: recognition, assessment and management.
- Author
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Peel, Matthew
- Subjects
- *
OBESITY , *DISSEMINATED intravascular coagulation , *SUBSTANCE abuse , *HOSPITAL emergency services , *RHABDOMYOLYSIS , *MENTAL health , *DIFFERENTIAL diagnosis , *BEHAVIOR disorders , *RISK assessment , *RESTRAINT of patients , *EMERGENCY medical services , *AGGRESSION (Psychology) , *HYPERKALEMIA , *DRUG abusers , *CONTROL (Psychology) , *EMERGENCY medicine , *POLICE , *ACIDOSIS , *DISEASE risk factors - Abstract
AUTH Why you should read this article: • To recognise the signs and symptoms of acute behavioural disturbance • To learn about the pathophysiology of acute behavioural disturbance • To understand the principles of assessment and management of people with acute behavioural disturbance Acute behavioural disturbance (ABD) is a clinical emergency which typically affects overweight men in their mid-thirties who chronically misuse illicit stimulants. People with ABD are most likely to be seen in police custody or emergency departments, therefore nurses working in these areas must be able to recognise the signs and symptoms and know how to respond appropriately. Presentation varies, but the signs and symptoms commonly include extreme agitation, hyperthermia, hostility and exceptional strength without fatigue. Further, it is important to recognise that people with ABD are at risk of developing metabolic acidosis, hyperkalaemia, rhabdomyolysis or disseminated intravascular coagulation. This article gives an overview of ABD and describes the main elements of management and treatment. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
11. Assessing and managing people exposed to conducted energy device (Taser) discharge.
- Author
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Peel, Matthew and Tremlett, Dave
- Subjects
- *
OCCUPATIONAL roles , *RESPIRATORY organs , *ELECTRICAL injuries , *PHYSICAL fitness , *MEDICAL protocols , *CARDIOVASCULAR system , *ELECTRIC stimulation , *NURSES , *NEUROMUSCULAR manifestations of general diseases , *AGGRESSION (Psychology) , *EMERGENCY nursing , *POLICE - Abstract
Why you should read this article: • To enhance your awareness of the physiological effects and potential complications of exposure to Taser • To acknowledge recent changes to the assessment and management of people who have been 'tasered' • To understand the role of nurses in post-Taser assessment and management in custodial and emergency settings The use of conducted energy devices – better known under the brand name Taser – by police officers is subject to scrutiny. Consequently, the clinical assessment and management of people who have been exposed to Taser discharge is also subject to scrutiny. In 2021 the Conducted Energy Device Joint Working Group published a new guideline on assessment in police custody after Taser discharge. The guideline enables any appropriately trained and competent healthcare professional, including nurses, to undertake post-Taser assessments and determine the person's fitness to be detained in police custody. This would be done in the first instance by nurses working in police custody suites, but emergency department (ED) nurses may also be involved, as people who have been 'tasered' may need referral to the ED. This article explains how Tasers work, their physiological effects and potential complications, and the required approaches to clinical assessment and management as outlined in the new guideline. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
12. Care bundles: resuscitation of patients with severe sepsis
- Author
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Peel, Matthew
- Subjects
Resuscitation -- Methods ,Sepsis -- Care and treatment -- Patient outcomes -- Prognosis ,Critically ill -- Care and treatment -- Prognosis -- Methods ,Health ,Health care industry - Abstract
Summary This article outlines a nurse-led system to identify patients with severe sepsis outside critical care settings. It also discusses how the Surviving Sepsis Campaign's severe sepsis resuscitation care bundle [...]
- Published
- 2008
13. Recognising and responding to bruising in children.
- Author
-
Peel, Matthew
- Subjects
- *
MOTHERS , *CAREGIVERS , *CHILD abuse , *BRUISES , *DOMESTIC violence , *SCHOOL nursing , *PLAY , *CHILDREN'S health , *NURSES , *PARENTS , *HEALTH promotion , *CHILDREN - Abstract
Why you should read this article: • To refresh your knowledge of the various types of bruises in children and their potential causes • To recognise the circumstances where bruising might be suspicious and potentially a result of child physical abuse • To understand the actions that nurses need to take if they encounter bruising in a child Bruises are commonly seen in children and are usually easily explained by play or accidents. However, bruises are also common in children who have been physically abused. For this reason, nurses must determine if the reasons for bruising that are given by parents or carers provide a suitable explanation. This will in part depend on the veracity of the reasons given, as well as the type of bruising, its location and any pattern to the bruising. This article explains how nurses can identify various types of bruises and how these should be documented. The author also details how nurses should raise any suspicion of child physical abuse with the child, parents or carers, and how nurses can escalate any concerns. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
14. Understanding the nurse's role as a professional witness.
- Author
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Peel, Matthew
- Subjects
- *
OCCUPATIONAL roles , *FORENSIC nursing , *HOSPITAL nursing staff , *NURSES , *LEGAL evidence , *COMMUNICATION , *FORENSIC medicine , *CRIMINAL justice system - Abstract
Why you should read this article: • To enhance your understanding of the court system in the UK • To learn how to write a professional witness statement • To learn how to give oral evidence in court as a professional witness Nurses working in any setting may be required to assist the courts or coroners by preparing statements or giving evidence in court. Nurses can act as 'professional witnesses' who provide evidence of something they have seen, heard or been involved with as part of their professional duties. This article outlines how nurses should respond to requests for written statements and suggests a format for providing such statements. It also explains the typical approach to providing oral evidence in court and how nurses should prepare and present themselves in the witness box. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
15. In situ study of dynamic recrystallization and hot deformation behavior of a multiphase titanium aluminide alloy.
- Author
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Liss, Klaus-Dieter, Schmoelzer, Thomas, Yan, Kun, Reid, Mark, Peel, Matthew, Dippenaar, Rian, and Clemens, Helmut
- Subjects
RECRYSTALLIZATION (Metallurgy) ,EFFECT of high temperatures on titanium alloys ,MATERIAL plasticity ,CRYSTAL grain boundaries ,DIFFRACTION patterns - Abstract
Hot-compression tests were conducted in a high-energy synchrotron x-ray beam to study in situ and in real time microstructural changes in the bulk of a β-solidifying titanium aluminide alloy. The occupancy and spottiness of the diffraction rings have been evaluated in order to access grain growth and refinement, orientation relationships, subgrain formation, dynamic recovery, and dynamic recrystallization, as well as phase transformations. This method has been applied to an alloy consisting of two coexisting phases at high temperature and it was found that the bcc β-phase recrystallizes dynamically, much faster than the hcp α-phase, which deforms predominantly through crystallographic slip underpinned by a dynamic recovery process with only a small component of dynamic recrystallization. The two phases deform to a very large extent independently from each other. The rapid recrystallization dynamics of the β-phase combined with the easy and isotropic slip characteristics of the bcc structure explain the excellent deformation behavior of the material, while the presence of two phases effectively suppresses grain growth. [ABSTRACT FROM AUTHOR]
- Published
- 2009
- Full Text
- View/download PDF
16. Assessment of people who have been tasered.
- Author
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Peel, Matthew
- Subjects
- *
ELECTRICAL injuries , *ELECTRICITY , *EMERGENCY medicine , *EMERGENCY nursing , *HEART beat , *HOSPITAL emergency services , *LACTATES , *NEUROPHYSIOLOGY , *NURSING assessment , *POLICE , *RESPIRATORY measurements , *WEAPONS , *NEUROMUSCULAR system , *THERAPEUTICS - Abstract
The use of Tasers® by the police is subject to intense scrutiny and controversy. With increasing numbers of police officers carrying Tasers, it is important that nurses in pre-hospital, emergency department and police custody settings understand how Tasers work, and the physiological effects. This article describes Tasers, their mechanisms and physiological effects, and explains how nurses should undertake assessment of people who have been subjected to Taser discharge. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
17. Opportunities to preserve forensic evidence in emergency departments.
- Author
-
Peel, Matthew
- Subjects
- *
WOUND & injury classification , *LEGAL evidence , *COLLECTION & preservation of biological specimens , *EMERGENCY medical services , *EMERGENCY nursing , *PATIENTS , *SUDDEN infant death syndrome , *INFORMATION resources , *FORENSIC nursing - Abstract
Victims of violence often seek assistance from emergency departments, so emergency nurses are ideally placed to identify them, and other 'forensic' patients, and protect the evidence that could support any ensuing legal process. Emergency nurses who are trained to identify, collect and preserve forensic evidence can support the identification, elimination and prosecution of suspects. This article gives an overview of forensic evidence, and explains how emergency nurses can preserve and collect samples effectively. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
18. The Resilience of Pastoral Care in Australian Catholic Aged Care Services.
- Author
-
Laverty, Martin J., Callaghan, Elizabeth M., Mersiades, Nicolas G., Peel, Matthew, and Sullivan, Susan
- Subjects
PASTORAL care ,ELDER care ,PASTORAL counseling - Abstract
The majority of regulated residential aged care in Australia is provided by faith-based providers, with the Catholic Church in Australia providing one in ten of all such services. Despite challenges caused by the decline in active involvement of clergy and religious and government regulatory and financial constraints, pastoral care in Catholic residential aged care is present, evolving, and thriving. Fostering a holistic pastoral environment is also essential to the viability and effectiveness of pastoral care in aged care. A new approach to government funding is needed to foster innovation and a holistic response to the needs of older Australians. [ABSTRACT FROM PUBLISHER]
- Published
- 2012
- Full Text
- View/download PDF
19. Physiological Stress in Rescued Wild Koalas (Phascolarctos cinereus) Being Held in a Rehabilitation Sanctuary: A Pilot Study.
- Author
-
Charalambous, Renae, Simonato, Troy, Peel, Matthew, and Narayan, Edward J.
- Subjects
KOALA ,PHYSIOLOGICAL stress ,WILDLIFE rehabilitation ,PSYCHOLOGICAL stress ,HYDROCORTISONE - Abstract
Simple Summary: Koalas (Phascolarctos cinereus) are one of Australia's most charismatic native small marsupial species, but populations are rapidly declining throughout Australia as they continue to face increasing pressure from a changing ecosystem. In response to stressors, koalas will use their hypothalamic–pituitary–adrenal (HPA) axis to produce catecholamines and glucocorticoids (e.g., cortisol). In this pilot study, we set out to quantify faecal and fur cortisol metabolites in wild rescued koalas undergoing wildlife rehabilitation. Sampling occurred sporadically over four months (the start of September 2018 to the end of December 2018), and was performed on three rescued koalas (Maree, Tai, and Solstice) being held at the rehabilitation centre. Results of this study show that between the three koalas, the highest recorded faecal cortisol result was 241 ng/g, and the lowest recorded faecal cortisol result was 4 ng/g, whereas the highest recorded fur cortisol result was 1.75 ng/g, and the lowest recorded fur cortisol result was 0.10 ng/g. Statistically, there was a significant difference between all three koalas and their faecal cortisol responses, as well as their fur cortisol responses. Statistically for Maree and Solstice, there was a significant difference in their faecal cortisol response between days when a stressor was recorded, and days when a stressor was not recorded. However, statistically for Tai, this was not the case, as there was no significant difference in his faecal cortisol response between days when a stressor was recorded, and days when a stressor was not recorded. In summary, the hypothesis that faecal glucocorticoids and fur glucocorticoids between koalas will differ based on individual responses to stressors was true as a whole but individually, this hypothesis was true for Maree and Solstice, but untrue for Tai. Measuring faecal and fur glucocorticoids is the first step in understanding how koalas undergoing wildlife rehabilitation respond to stressors. Koalas (Phascolarctos cinereus) are one of Australia's most charismatic native small marsupial species. Unfortunately, populations of koalas are rapidly declining throughout Australia as they continue to face increasing pressure from a changing ecosystem. All wildlife species to some degree will use their hypothalamic–pituitary–adrenal (HPA) axis in response to stress. Depending on the duration of activation, the stress response can lead to either acute or chronic side effects and is modulated through the neuroendocrine stress system with the release of catecholamines and glucocorticoids (e.g., cortisol). It is well known that rehabilitation sanctuaries are inherently stressful for all animals, in particular for rescued wild koalas, as it is an unfamiliar environment where the animals cannot predict or control what will happen to them. In this pilot study, we set out to quantify faecal and fur cortisol metabolites in wild rescued koalas undergoing wildlife rehabilitation. Absolute levels of acute and chronic stress were indexed non-invasively, with faecal samples taken to evaluate acute stress, and fur samples taken to evaluate chronic stress. Sampling occurred sporadically over four months (the start of September 2018 to the end of December 2018), and was performed on three rescued koalas (Maree, Tai, and Solstice) being held at the rehabilitation centre. Results of this study show that between the three koalas, the highest recorded faecal cortisol result was 241 ng/g, and the lowest recorded faecal cortisol result was 4 ng/g, whereas the highest recorded fur cortisol result was 1.75 ng/g, and the lowest recorded fur cortisol result was 0.10 ng/g. Statistically, there was a significant difference between all three koalas and their faecal cortisol responses, as well as their fur cortisol responses. Statistically for Maree and Solstice, there was a significant difference in their faecal cortisol response between days when a stressor was recorded, and days when a stressor was not recorded. However, statistically for Tai, this was not the case, as there was no significant difference in his faecal cortisol response between days when a stressor was recorded, and days when a stressor was not recorded. In summary, the hypothesis that faecal glucocorticoids and fur glucocorticoids between koalas will differ based on individual responses to stressors was true as a whole, but individually, this hypothesis was true for Maree and Solstice, but untrue for Tai. The use of biological samples such as faeces and fur to obtain readings of glucocorticoids is a method of measuring absolute levels of physiological stress that is still evolving for koalas, and there is no current glucocorticoid baseline with which to compare the results of this study; although, measuring faecal and fur glucocorticoids is the first step in understanding how koalas undergoing wildlife rehabilitation respond to stressors. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
20. Assessing an individual's fitness to be interviewed in police custody.
- Author
-
Peel, Matthew
- Subjects
- *
INTERVIEWING , *LIFE skills , *MEDICAL history taking , *NURSE-patient relationships , *POLICE , *PRISON psychology , *FUNCTIONAL assessment - Abstract
Nurses working in police custody settings may be called on to assess a detainee's fitness to be interviewed by police, for example where the person is thought to have a mental disorder or vulnerability. This article outlines the role of the custody nurse in the fitness-to-interview assessment. This assessment is complex and multifaceted. It requires custody nurses to assess a detainee's medical, mental health, educational and social history, as well as any substance misuse. It should include a mental state examination and, where appropriate, a physical examination. Fitness-to-interview decisions should be rigorous to prevent miscarriages of justice or significant harm to detainees. Custody nurses should advocate for detainees who are mentally vulnerable and ensure appropriate safeguards are in place, where necessary. Further work is required to reduce the subjectivity of the fitness-to-interview assessment, along with increased investment in appropriate adult services. Equally, custody nurses working at this advanced level of practice require relevant postgraduate knowledge and skills. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
21. Assessing fitness to detain in police custody.
- Author
-
Peel, Matthew
- Subjects
- *
COMPETENCY assessment (Law) , *CRIMINALS , *MEDICAL needs assessment , *FORENSIC medicine , *NURSING specialties , *PRISON nurses , *PATIENT discharge instructions - Abstract
This article outlines the role of the custody nurse in assessing an individual's fitness to be detained. It addresses all aspects of the assessment, including consent, responsibilities and the structure of the clinical examination. It explores ways to ensure that the detainee's rights and welfare are maintained and their healthcare needs are met. It offers guidance on preparing a care plan for detained individuals that the police can implement. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
22. WESTERN REPROACHES.
- Author
-
Peel, Matthew
- Subjects
- PETER Gunn (TV program), STEVENS, Craig
- Published
- 2020
23. Hydrogen environmentally assisted cracking of aerospace aluminium : an investigation on the increased susceptibility of novel aircraft alloys to cracking in moist air under static loads
- Author
-
De Francisco, Unai, Peel, Matthew, and Larrosa, Nicolas
- Subjects
Hydrogen environmentally assisted cracking ,Aluminium alloys ,AA7075-T651 ,AA7449-T7651 ,Moist air ,Fracture mechanics ,Microstructure ,Micro-XCT ,Hydrogen embrittlement - Abstract
Recently, a new generation of 7xxx alloys used for aircraft structural components has been found to be sensitive to intergranular hydrogen environmentally assisted cracking (HEAC) in moist air environments. HEAC can cause subcritical crack growth at stress levels significantly below yield. Thus, some components have been found to be at risk of in-service cracking. The higher sensitivity of these novel alloys has been ascribed to their composition; notably a high Zn/Mg ratio and a low Cu content. There has been substantial research regarding the environmentally assisted cracking behaviour of 7xxx alloys exposed to moist air and other aqueous solutions. However, there is a paucity of data for the cracking behaviour of these novel 7xxx alloys. Additionally, most research has been performed on large pre-cracked fracture mechanics samples. These neglect crack nucleation and microstructurally short cracking, despite these stages dominating the lifetime of components. The work done in this study can be divided up into five different sections, including three different experiments and the development of two Abaqus models. The first experiment involved the use of static 4-point bending to analyse the propensity to form cracks from smooth samples of AA7075-T651 and AA7449-T7651 exposed to warm moist air. AA7449-T7651 was found to be much more prone to crack formation. For the second experiment, fracture mechanics samples were used to estimate the HEAC crack growth rates of AA7449-T7651 in moist air for range of temperatures. Increasing the temperature was found to increase the crack growth rates and decrease the threshold stress intensity factor for cracking. The third experiment involved in-situ X-ray tomography imaging of small tensile samples of AA7449-T7651 during HEAC. This technique was used to correlate the microstructure with the HEAC crack growth behaviour. Finally, two cohesive zone models (CZM) were developed to be able to simulate the HEAC behaviour for the DCB and in-situ tensile tests. These models were useful to understand how hydrogen was distributed within the samples during the tests.
- Published
- 2022
24. Crack initiation in carburised 316H stainless steels, with relevance to high temperature low-cycle fatigue
- Author
-
James, Andrew, Peel, Matthew, and Knowles, David
- Abstract
Crack initiation mechanism changes induced by environmentally driven carburisation are poorly understood. Physical restrictions on practical sample production volumes and a historical focus on macroscopic phenomena has limited the data available for practical use in mechanistic investigations. Following preliminary studies conducted by EDF Energy, experiments are presented that were undertaken to address this knowledge gap. In this thesis microstructural changes caused by oxidation in a simulated reactor gas, previously developed by EDF Energy, are presented for two 316H stainless steels formed via different processing routes. The oxidation process leads to the formation of a thick duplex oxide layer and carburisation of the steel behind the oxidation front. Because of the complicated interactions and property variations introduced at the surface of the steel, focus is given to chemical distributions in the oxides formed on a cast steel along with grain boundary morphology changes in the carburised layer on a sample taken from a forged bar. Auger electron spectroscopy measurements conducted on a transverse section through the oxidised surface compliment previous observations of carburisation in Type 316H. Observations on the cast steel show the complex chemistry and structure of the spinel oxide along with the elevated levels of dissolved carbon in the near surface. Similar oxide depths are identified in samples from the cast and forged materials, however, measurements of carbide morphology changes in the forged material indicate that it is thermal ageing, a consequence of prolonged exposure to elevated temperature during oxidation, that drives these changes rather than the carburisation itself. Laboratory and synchrotron X-ray diffraction measurements are utilised to interrogate stresses generated during thermal cycling and mechanical loading of conditioned samples. During thermal cycling stresses measured in the oxide show disagreement with simple models, that are based on estimated oxide properties. Synchrotron measurements appear to indicate the presence of a compressive triaxial stress field in the carburised layer behind the oxide. Currently, it is not known if this stress state persists at elevated temperatures. Understanding of the stress state in the carburised layer is important for making meaningful predictions of component life and critical to the understanding of potential cracking mechanisms operating in the near surface of a component during operation. The diffraction results are supported by post-test microscopic investigations conducted on the cracked surfaces of the carburised layer. During repeated thermal cycling cracks appear at defects in the oxide layer are thought to be initiated from tensile stresses generated from local creep of the substrate. From room-temperature mechanical tests, oxide fracture initiates at an applied bulk strain between 0:45% to 0:9%. The cracks generated being identified as intergranular cracks that propagate to a depth just beyond the carburised zone. The results of a micro-tensile test conducted at 500 °C, with in-situ observations conducted on the outer oxide, confirm that a critical strain must be applied to the sample before cracking occurs. The value of the critical strain reported at this temperature is between 0:06% to 0:1%, i ii much lower than at ambient temperature, presumably due to the absence of high compressive stresses that protect the oxide at lower temperatures. Uncertainty on the initiation strain values are expected to be high because of complications posed by the experimental apparatus. The combination of high temperature micro-scale testing, in conjunction with other analytical techniques, appears the logical future avenue for investigating the mechanical properties of the carburised layer in conditioned components.
- Published
- 2021
25. Diamond photocathodes in gaseous environments
- Author
-
Foord, John S., Bennett, Andrew, Peel, Matthew, and Jackman, Richard B.
- Subjects
- *
DIAMONDS , *PHOTOCATHODES , *ULTRAVIOLET radiation , *FIELD emission cathodes - Abstract
The performance of UV diamond photocathodes in gaseous environments has been explored with regard to the potential applications, which exist for such devices. Stable performance is exhibited even at gas pressures approximately 0.5 bar for hydrogenated diamond, in gaseous environments such as He, H2, O2, CH4 and CF4. However, for chlorocarbon gases, UV stimulated photodissociation of the ambient gas causes the adsorption of chlorine on the diamond surface, and rapidly degrades device performance. Thermal dissociation of ambient gases brings about a similar effect. Thus, although diamond photocathodes do have potential use in gaseous environments, it is clear that care is required to ensure that the hydrogenated surface layer is not destroyed when in use. [Copyright &y& Elsevier]
- Published
- 2004
- Full Text
- View/download PDF
26. Physiological Stress in Rescued Wild Koalas ( Phascolarctos cinereus ) Being Held in a Rehabilitation Sanctuary: A Pilot Study.
- Author
-
Charalambous R, Simonato T, Peel M, and Narayan EJ
- Abstract
Koalas ( Phascolarctos cinereus ) are one of Australia's most charismatic native small marsupial species. Unfortunately, populations of koalas are rapidly declining throughout Australia as they continue to face increasing pressure from a changing ecosystem. All wildlife species to some degree will use their hypothalamic-pituitary-adrenal (HPA) axis in response to stress. Depending on the duration of activation, the stress response can lead to either acute or chronic side effects and is modulated through the neuroendocrine stress system with the release of catecholamines and glucocorticoids (e.g., cortisol). It is well known that rehabilitation sanctuaries are inherently stressful for all animals, in particular for rescued wild koalas, as it is an unfamiliar environment where the animals cannot predict or control what will happen to them. In this pilot study, we set out to quantify faecal and fur cortisol metabolites in wild rescued koalas undergoing wildlife rehabilitation. Absolute levels of acute and chronic stress were indexed non-invasively, with faecal samples taken to evaluate acute stress, and fur samples taken to evaluate chronic stress. Sampling occurred sporadically over four months (the start of September 2018 to the end of December 2018), and was performed on three rescued koalas (Maree, Tai, and Solstice) being held at the rehabilitation centre. Results of this study show that between the three koalas, the highest recorded faecal cortisol result was 241 ng/g, and the lowest recorded faecal cortisol result was 4 ng/g, whereas the highest recorded fur cortisol result was 1.75 ng/g, and the lowest recorded fur cortisol result was 0.10 ng/g. Statistically, there was a significant difference between all three koalas and their faecal cortisol responses, as well as their fur cortisol responses. Statistically for Maree and Solstice, there was a significant difference in their faecal cortisol response between days when a stressor was recorded, and days when a stressor was not recorded. However, statistically for Tai, this was not the case, as there was no significant difference in his faecal cortisol response between days when a stressor was recorded, and days when a stressor was not recorded. In summary, the hypothesis that faecal glucocorticoids and fur glucocorticoids between koalas will differ based on individual responses to stressors was true as a whole, but individually, this hypothesis was true for Maree and Solstice, but untrue for Tai. The use of biological samples such as faeces and fur to obtain readings of glucocorticoids is a method of measuring absolute levels of physiological stress that is still evolving for koalas, and there is no current glucocorticoid baseline with which to compare the results of this study; although, measuring faecal and fur glucocorticoids is the first step in understanding how koalas undergoing wildlife rehabilitation respond to stressors.
- Published
- 2021
- Full Text
- View/download PDF
27. Rupture of Stochastically Occurring Vesicle Clusters Limits Bilayer Formation on Alkane-PEG-Type Supports: Uncoupling Clustering from Surface Coverage.
- Author
-
Peel MJ, Cross SJ, Birkholz O, Aladağ A, Piehler J, and Peel S
- Subjects
- Adsorption, Diffusion, Lipid Bilayers chemistry, Silicon Dioxide chemistry, Stochastic Processes, Surface Properties, Alkanes chemistry, Lipid Bilayers chemical synthesis, Polyethylene Glycols chemistry
- Abstract
Polymer-supported bilayers (PSBs) are a recognized tool for drug discovery through function-interaction analysis of membrane proteins. While silica-supported bilayers (SSBs) spontaneously form from surface-adsorbed vesicles, successful PSB formation via a similar method has thus far been limited by an insufficient understanding of the underlying vesicle-remodelling processes. Here, we generated a polymer support through the incubation of poly-L-lysine conjugated to alkyl-chain-terminated poly(ethylene)glycol on silica. This polymer-coated silica substrate yielded efficient vesicle adsorption and spontaneous bilayer formation, thereby providing a rare opportunity to address the mechanism of PSB formation and compare it to that of SSB. The combined use of super-resolution imaging, kinetics, and simulations indicates that the rupture of stochastically formed vesicle clusters is the rate-limiting step, which is an order of magnitude higher for silica than for polymer-coated silica. This was confirmed by directly demonstrating increased rupture rates for surface adsorbed multivesicle assemblies formed by vesicle cross-linking in solution. On the basis of this key insight we surmised that a low propensity of cluster rupture can be compensated for by an increase in the number density of clusters: the deposition of a mixture of oppositely charged vesicles resulted in bilayer formation on another alkane-PEG type of interface, which despite efficient vesicle adsorption otherwise fails to support spontaneous bilayer formation. This potentially provides a universal strategy for promoting bilayer formation on resistant surfaces without resorting to modifying the surface itself. Therefore, multivesicle assemblies with tailored geometries not only could facilitate bilayer formation on polymers with interesting functional properties but also could instigate the exploration of vesicle architecture for other processes involving vesicle remodelling such as drug delivery.
- Published
- 2015
- Full Text
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