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2. Intramolecular Vinylsilane−Oxocarbenium Condensations:  Concise Assembly of Cis-Bicyclic Ether Arrays.

Author

Stephen Philip Fearnley and Pedro Lory

Subjects
*ETHER (Anesthetic), *ACID-base chemistry, *ORGANIC compounds, *PHYSICAL & theoretical chemistry
Abstract

Lewis acid-mediated intramolecular attack of vinylsilanes at tethered oxonium precursors 1results in a rapid assembly of the cis-fused bicyclic ether species 3, with complete regio- and stereospecific control, and in some cases near-quantitative yield. Continued investigation suggests a general approach to a variety of such ether frameworks. [ABSTRACT FROM AUTHOR]

Published
2007
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