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Your search keyword '"Mockus, Nicholas V."' showing total 7 results
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7 results on '"Mockus, Nicholas V."'

2. Subnanosecond isomerization in an osmium-dimethyl sulfoxide complex

Author

Mockus, Nicholas V., Petersen, Jeffrey L., and Rack, Jeffrey J.

Subjects
Excited state chemistry -- Research, Osmium -- Structure, Osmium -- Chemical properties, Ruthenium -- Structure, Ruthenium -- Chemical properties, Chemistry
Abstract

The examination of phototriggered excited-state isomerization in osmium-polypyridyl complexes containing ruthenium-dimethyl sulfoxide (DMSO) is done to study the role of ligand-field states in DMSO photochromic complexes. That DMSO isomerization occurs on osmium suggests that this reaction does not require intervention of photoreactive ligand-field states.

Published
2006

3. Photochromic ruthenium sulfoxide complexes: evidence for isomerization through a conical intersection

Author

McClure, Beth Anne, Mockus, Nicholas V., Butcher,Dennis P., Jr., Lutterman, Daniel A., Turro, Claudia, Petersen, Jeffrey L., and Rack, Jeffrey J.

Subjects
Density functionals -- Usage, Isomerization -- Analysis, Propylene -- Chemical properties, Propylene -- Structure, Ruthenium -- Chemical properties, Ruthenium -- Structure, Silver compounds -- Chemical properties, Silver compounds -- Structure, Sulfur dioxide -- Chemical properties, Sulfur dioxide -- Structure, Chemistry
Published
2009

4. Room-temperature photochroism in cis- and trans-[Ru(bpy) (sub)2 (dmso) (sub)2] (super)2+

Author

Rack, Jeffrey J. and Mockus, Nicholas V.

Subjects
Isomerization -- Analysis, Ruthenium, Photochemistry -- Research, Inorganic compounds -- Composition, Chemistry, Inorganic -- Research, Chemistry
Abstract

Research has been conducted on cis- and trans-[Ru(bpy) (sub)2 (dmso) (sub)2] (super)2+. The authors describe phototriggered Ry-D (approaches) Ru-O and thermal Ru-O (approaches) Ru-S intramolecular linkage isomerization in this complex.

Published
2003

6. Room-Temperature Photochromism in cis- and trans-[Ru(bpy)[sub 2](dmso)[sub 2]][sup 2+].

Author

Rack, Jeffrey J. and Mockus, Nicholas V.

Subjects
*RUTHENIUM, *SULFUR, *OXYGEN, *ISOMERIZATION
Abstract

Reports on phototriggered Ruthenium-sulphur to ruthenium-oxygen and ruthenium-oxygen to ruthenium-sulphur intramolecular linkage isomerization in cis- and trans-[Ru(bpy)[sub 2](dmso)sub 2]][sup 2+]. Thermal reversion to the ground state in ionic liquid; Absorption spectra.

Published
2003
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