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This work controlled the polymerization reaction, melting, and mixing processing of a mixture including epoxy resin and polyethylene glycol (PEG) by a pulverizer, to effectively develop high-performance shape memory epoxy/PEG (EPP) filaments. The process parameters of polymerization-melting-mixing-drawing were determined through the extrusion force investigation. The results showed that EPP mixtures could be developed into filaments through polymerization-melting-mixing-drawing process, reducing the spinning temperature and filament diameter from 300°C and 31 mm to 235°C and 13 mm, respectively. The Fourier transform infrared spectra confirmed the complete polymerization of epoxy resin and the stable existence of PEG. EPP filaments developed through the polymerization-melting-mixing-drawing process have exhibited controllable dynamic thermal mechanical properties and Tg, excellent shape recovery effects, and adjustable stimulus temperature. This work developed shape memory EPP filaments through a polymerization-melting-mixing-drawing process, with controllable spinnability and adjustable stimulus temperature, providing a reference for high-performance filament fabrication and process optimization. [ABSTRACT FROM AUTHOR]

Modern observations have determined the presence of hyperpycnal flows; however, their presence in ancient rocks is scarcely reported in the literature, particularly with respect to continental strata. The present study is the first to use core and thin-section analyses and examination of physical reservoir properties to identify hyperpycnal flow sediment from the lower section of the Oligocene Huagang Formation in the central Xihu Sag, East China Sea Shelf Basin. The multiple fine sandy layers are characterized by lower reverse-graded and upper normal-graded bedding with horizontal bedding, climbing-ripple lamination, wavy bedding, and small foreset laminae. Microerosion surfaces are occasionally present between the reverse-graded and normal-graded bedding, and plant fragments are sometimes visible in the deposits. The same grain size sequence changes are observed in the thin sections. This lithologic combination is considered to be related to hyperpycnal flow sedimentation caused by flood events. The lower reverse-graded and upper normal-graded bedding sequences indicate that the flood energy first increased then decreased and the microerosion surfaces were formed through erosion of lower sediments by the flood. Hyperpycnal flows can directly transport deposits from an estuary to a deep-water basin, which distinguishes them from typical turbidity currents. This study also establishes a sedimentary model of the hyperpycnal flow in lacustrine basin, which can be used as a reference for future hyperpycnal deposit studies. Key words: hyperpycnal flow deposit model, lacustrine basin, paleoclimate, Huagang Formation, Xihu Sag. Si des observations ont permis d'établir l'existence actuelle de courants hyperpycnaux, la présence de tels courants dans des roches anciennes est rarement signalée dans la documentation, particulièrement dans des contextes de strates continentales. La présente étude est la première à utiliser l'analyse de carottes et de lames minces et l'examen des propriétés physiques de réservoirs pour cerner la présence de sédiments de courants hyperpycnaux dans la séquence inférieure de la Formation oligocène de Huagang, du centre de la dépression de Xihu, dans le bassin de la plateforme de la mer de Chine orientale. Les multiples couches de sable fin définissent des strates inférieures à classement inverse et supérieures à classement normal, avec une stratification horizontale, des laminations à rides ascendantes, une stratification ondulée et de petites laminations frontales. Des microsurfaces d'érosion sont occasionnellement présentes entre les strates à classement inverse et celles à classement normal, et des fragments de plantes sont parfois visibles dans les sédiments. Les mêmes variations du classement au fil de la séquence sont observées en lames minces. Cette combinaison lithologique est considérée être reliée à la sédimentation associée à des courants hyperpycnaux causés par des épisodes de crues. Les séquences à classement inverse inférieure et à classement normal supérieure indiquent que l'énergie des crues est d'abord allée en augmentant, puis en diminuant et les microsurfaces d'érosion se sont formées par l'érosion par les crues de sédiments plus bas dans la séquence. Les courants hyperpycnaux peuvent transporter des sédiments directement d'un estuaire à un bassin d'eau profonde, ce qui les distingue de courants de turbidité typiques. L'étude établit également un modèle sédimentaire du courant hyperpycnal dans un bassin lacustre qui peut servir de référence pour les études futures de dépôts hyperpycnaux. [Traduit par la Rédaction] Mots-clés : modèle de dépôt de courants hyperpycnaux, bassin lacustre, paléoclimat, Formation de Huagang, dépression de Xihu., Introduction A hyperpycnal flow is a stable turbidity flow that occurs during periods of flooding when water transports sediment from an estuary to shallow sea, slope, or deep-water regions without [...]

This study investigates the corrosion behavior of Ni-Cr binary alloys, including Ni-10Cr, Ni-15Cr, Ni-20Cr, Ni-25Cr, and Ni-30Cr, in a NaCl-KCl-MgCl2 molten salt mixture through gravimetric analysis. Corrosion tests were conducted at 700 °C, with the maximum immersion time reaching up to 100 h. The corrosion rate was determined by measuring the mass loss of the specimens at various time intervals. Verifying corrosion rates by combining mass loss results with the determination of element dissolution in molten salts using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). Detailed examinations of the corrosion products and morphology were conducted using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Micro-area elemental analysis on the corroded surfaces was performed using an energy dispersive spectrometer (EDS), and the elemental distribution across the corrosion cross-sections was mapped. The results indicate that alloys with lower Cr content exhibit superior corrosion resistance in the NaCl-KCl-MgCl2 molten salt under an argon atmosphere compared to those with higher Cr content; no corrosion products were retained on the surfaces of the lower Cr alloys (Ni-10Cr, Ni-15Cr). For the higher Cr alloys (Ni-20Cr, Ni-25Cr, Ni-30Cr), after 20 h of corrosion, a protective layer was observed in certain areas. The formation of a stable Cr2O3 layer in the initial stages of corrosion for high-Cr content alloys, which reacts with MgO in the molten salt to form a stable MgCr2O4 spinel structure, provides additional protection for the alloys. However, over time, even under argon protection, the MgCr2O4 protective layer gradually degrades due to chloride ion infiltration and chemical reactions at high temperatures. Further analysis revealed that chloride ions play a pivotal role in the corrosion process, not only facilitating the destruction of the Cr2O3 layer on the alloy surfaces but also possibly accelerating the corrosion of the metallic matrix through electrochemical reactions. In conclusion, the corrosion behavior of Ni-Cr alloys in the NaCl-KCl-MgCl2 molten salt environment is influenced by a combination of factors, including Cr content, chloride ion activity, and the formation and degradation of protective layers. This study not only provides new insights into the corrosion resistance of Ni-Cr alloys in high-temperature molten salt environments but also offers significant theoretical support for the design and optimization of corrosion-resistant alloy materials. [ABSTRACT FROM AUTHOR]

In this study, a novel fabrication method was used to synthesize phenolic resin/phosphate hybrid coatings using aluminum dihydrogen phosphate (Al(H2PO4)3, hereafter denoted as Al), SC101 silica sol (Si) as the primary film-forming agent, and phenolic resin (PF) as the organic matrix. This approach culminated in the formation of Al+Si+PF organo–inorganic hybrid coatings. Fourier-transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) results confirmed the successful integration of hybrid structures within these coatings. The crystalline structure of the coatings post-cured at various temperatures was elucidated using X-ray diffraction (XRD). Additionally, the surface and cross-sectional morphologies were meticulously analyzed using scanning electron microscopy (SEM), offering insights into the microstructural properties of the coatings. The coatings' porosities under diverse thermal and temporal regimes were quantitatively evaluated using advanced image processing techniques, revealing a significant reduction in porosity to a minimum of 5.88% following a thermal oxidation process at 600 °C for 10 h. The antioxidant efficacy of the phosphate coatings was rigorously assessed through cyclic oxidation tests, which revealed their outstanding performance. Specifically, at 300 °C across 300 h of cyclic oxidation, the weight losses recorded for phosphate varnish and the phenolic resin-infused phosphate coatings were 0.15 mg·cm−2 and 0.09 mg·cm−2, respectively. Furthermore, at 600 °C and over an identical period, the weight reduction was noted as 0.21 mg·cm−2 for phosphate varnish and 0.085 mg·cm−2 for the hybrid coatings, thereby substantiating the superior antioxidation capabilities of the phenolic resin hybrid coatings in comparison to the pure phosphate varnish. [ABSTRACT FROM AUTHOR]