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Validating the satellite soil moisture products is always an active research topic for the application of the products and improvement of the retrieval algorithms, attracting extensive attention. Nevertheless, seldom existing validation activities focus on the validation of high-resolution soil moisture products at the fine scale. To this end, an experiment was conducted in the middle stream of the Heihe River Basin in northwestern China in August to October of 2021, aiming to validate high-resolution satellite remote sensing products of soil moisture. The paper introduces the design, composite, and preliminary results of the experiment. A soil moisture observation network was established with two kinds of sensors (CS616 and Stevens Hydra Probe) validated against soil core measurements. Several synchronized campaigns were performed, and data were collected to validate the SMAP/Sentinel-1 L2 Radiometer/Radar 30-Second Scene 3 and 1 km EASE-Grid Soil Moisture (SPL2SMAP_S) products. Besides, an optical trapezoid model (OPTRAM) and collected Sentinel-2 data were applied to estimate soil moisture and to map irrigated area. Preliminary analyses show that: 1) Steven probes perform best, with an RMSE = 0.040 m3m−3 and ubRMSE=0.034 m3m−3; 2) Both the SPL2SMAP_S products at 3 km and 1 km show large RMSE (0.128 m3m−3 for 3 km and 0.158 m3m−3 for 1 km) and ubRMSE (0.115 m3m−3 for 3 km and 0.158 m3m−3 for 1 km); 3) The OPTRAM retrievals over bare surface present relatively smaller RMSE (0.06 m3m−3) and ubRMSE (0.057 m3m−3), while retrievals over vegetated croplands present a relatively large RMSE/ubRMSE (0.083/0.083 m3m−3), and the retrievals can identify the irrigated area at field scale. Overall, the experiment provides fruitful methodologies and datasets for the validation of high-resolution remote sensing products, benefiting the development and improvement of soil moisture retrieval algorithms and products to support irrigation scheduling and management at a precision agricultural scale in the future.

The North China Craton underwent extensive and widespread crustal reworking (or decratonization) during the Mesozoic. However, how the decratonization operated is not well understood. Zircon compositions are widely used by the scientific community to reconstruct crustal thicknesses. In this study, we sampled 13 magmatic rocks in the Jiaodong Peninsula and used zircon Eu/Eu* to constrain the crustal thickness of the Jiaodong area and reveal decratonization processes in the Mesozoic time. The reconstructed crustal thickness using zircon Eu/Eu* is approximately 70 km in the Jurassic, and this value is 89 km at around 130 Ma, after which the crustal thickness drops to 30–40 km at ca. 110 Ma. These results are generally compatible with or slightly higher than the calculation results using a whole-rock La/Yb proxy for the Jurassic and ∼130 Ma rocks. Crustal thickness estimated using a whole-rock La/Yb proxy for the ∼110 Ma rocks is thicker than 70 km, which is not consistent with the geological facts and the result given by zircon proxy. The whole-rock proxy failed in estimating crustal thickness because of amphibole fractionation for the ∼110 Ma rocks. The crustal thickening from Jurassic to ∼130 Ma was probably related to the westward subduction of the Paleo-Pacific slab. The thinning of the crust from 130 to 110 Ma is not a rapid process but occurs more slowly than expected, which might be explained by the chemical erosion process rather than a mechanical delamination model. The chemical erosion was most likely induced by a rollback of the subducting slab and an upwelling of the asthenosphere.

Lower crust-derived granitic rocks provide constraints on the crustal reworking process and consequently give hints on the destruction mechanism of the cratons. The North China Craton (NCC) underwent extensive crustal melting in the Mesozoic. This study investigated granitic intrusions in the Dazeshan region of the Jiaodong Peninsula. Whole-rock major and trace element analyses and zircon U-Pb ages coupled with Hf isotopes were used to reveal the crustal reworking processes. Zircons separated from the quartz porphyry, Linglong granite, rhyolite porphyry, and biotite granite showed weighted mean 206Pb-238U ages of 119.2 ± 1.0 Ma, 140.2 ± 1.0 Ma, 120.6 ± 0.5 Ma, and 119.9 ± 0.7 Ma, respectively. The quartz porphyry, rhyolite porphyry, and biotite granite had high silica contents (SiO2 = 74–77 wt.%) but low MgO, Co, and Ni concentrations. The calculated εHf(t) values for the rhyolite porphyry and the biotite granite ranged from −18.3 to −20.0 and −17.8 to −20.2, respectively. These geochemical features imply ancient crust sources. The quartz porphyry showed distinct primitive mantle-normalized rare earth element (REE) patterns and was characterized by lower ΣREE content and lack of pronounced negative Eu anomalies. Whole-rock and zircon Dy/Yb ratios showed no correlation with whole-rock Rb/Sr ratios and zircon Hf contents, reflecting limited effects of crystal fractionation. The Ba/La ratios were also high (>150), but the Sr/Y and La/Yb ratios were low (Sr/Y < 50; La/Yb < 15). These features likely indicate that the quartz porphyry was generated by water-fluxed melting without differentiation. The rhyolite porphyry and biotite granite shared many geochemical similarities, denoting a unified source. The high La/Yb (>30) but low Sr/Y (

AbstractThe North China Craton (NCC) has thick lithosphere in the Paleozoic (>200 km) but appears to be decratonized in the Mesozoic. However, the actual processes operated in the lower crust-deep mantle are still unclear. The Mesozoic granitic rocks can provide important clues to the NCC decratonization mechanism. Here, we conducted trace element modeling to check whether partial melting of the Archean lower crust can generate these Mesozoic magmatic suites. Meanwhile, zircon Hf isotope analysis was conducted to reveal crust-mantle interaction processes and further give constraints on the decratonization of the NCC. Zircon Hf isotope data of the Linglong, Guojialing, and Aishan suites, the mafic microgranular enclaves (MMEs) in the Guojialing suite, and mafic dykes display minor differences: the Linglong (160–150 Ma), Guojialing (~130 Ma), and Aishan (118–116 Ma) suites have zircon εHft=–25.4 to –14.5, –15.3 to –10.4, and –23.1 to –11.9, respectively. The Cretaceous mafic dyke (126 Ma) has a highly negative εHft value (–22.8 to –17.7). Meanwhile, the MMEs (in the Guojialing granodiorite, DCW-2A, 129 Ma) have zircon εHft=–13.0 to –8.9. Temperature-pressure conditions calculated using amphibole compositions for both the Guojialing granodiorite and its MMEs are basically identical, implying possible magma mixing. Our modeling results show that certain trace elements (e.g., Tb, Yb, and Y) have to be retained in the source to match the composition of the Linglong suite, which requires substantial garnet residues (high-pressure melting) in the Jurassic. The Early Cretaceous garnet-dominated lower crust is Yb-/Y-enriched but depleted in elements like Sr and La. Therefore, it could not form geochemical features like high Sr/Y and La/Yb ratios akin to the Guojialing suite. Integrating the modeling results and zircon Hf isotope data, we propose that the crust in the eastern NCC had thickened and partially melted by dehydration to produce an eclogitic residue containing a large amount of garnet (>50% by weight) during the Jurassic (Linglong granite), whereas upwelling of hot and hydrous mafic magma from the asthenospheric mantle induced fluxed melting of both the lower crust and lithospheric mantle in the Early Cretaceous, during which the lithospheric mantle and part of the lower crust in the Jiaodong were removed by the convective mantle. About 10 Mys later while the Aishan suite formed, the crust was not thick anymore, and melting occurred under moderate pressure which does not necessarily require abundant garnet as the residue phase.

Soil moisture is a key factor in the water and heat exchange and energy transformation of the ecological systems and is of critical importance to the accurate obtainment of the soil moisture content for supervising water resources and protecting regional and global eco environments. In this study, we selected the soil moisture monitoring networks of Naqu, Maqu, and Tianjun on the Qinghai–Tibetan Plateau as the research areas, and we established a database of surface microwave scattering with the AIEM (advanced integral equation model) and the mathematical expressions for the backscattering coefficient, soil moisture, and surface roughness of the VV and VH polarizations.We proposed the soil moisture retrieval models of empirical and machine learnings algorithms (backpropagation neural network (BPNN), support vector machine (SVM), K-nearest neighbors (KNN), and random forest (RF)) for the ascending and descending orbits using Sentinel-1 and measurement data, and we also validated the accuracies of the retrieval model in the research areas. According to the results, there is a substantial logarithmic correlation among the backscattering coefficient, soil moisture, and combined roughness. Generally, we can use empirical models to estimate the soil moisture content, with an R² of 0.609, RMSE of 0.08, and MAE of 0.064 for the ascending orbit model and an R² of 0.554, RMSE of 0.086, and MAE of 0.071 for the descending orbit model. The soil moisture contents are underestimated when the volumetric water content is high. The soil moisture retrieval accuracy is improved with machine learning algorithms compared to the empirical model, and the performance of the RF algorithm is superior to those of the other machine learning algorithms. The RF algorithm also achieved satisfactory performances for the Maqu and Tianjun networks. The accuracies of the inversion models for the ascending orbit in the three soil moisture monitoring networks were better than those for the descending orbit.

Abstract The absolute crystallization ages of minerals from hydrothermal fluids measured in situ can unravel the timing of key events leading to the formation of, for instance, ore deposits and hydrothermally derived geological terrains. In this study, a skarn iron deposit from northwest (NW) China is shown to have U-Pb garnet and U-Pb zircon ages of 254.2 ± 1.7 Ma and 255.5 ± 1.0 Ma, respectively, which are both significantly younger than magmatism and metamorphism of the region. This skarn age instead correlates with the occurrence of strike-slip and thrust faulting in the region. The water/rock mass ratio of 0.065~0.115 suggests the δ18O garnet composition is ~1‰ at temperatures ranging from 250–450 °C. The low oxygen isotopic composition indicates the role of meteoric water in the garnet formation. These measurements can be interpreted as the shear along faults circulating meteoric water ~10 km below the hanging wall of meta-volcanic sedimentary rock. Meteoric water in this hydrothermal system would leach cations from the meta-volcano-sedimentary rocks necessary for mineralization. Silica-rich hydrothermal fluid reacts with calcic-rich materials in the meta-volcano-sedimentary rocks, depositing the garnet and magnetite. Our work suggests that the shear zone is rich in ores, rendering this deposit for NW China a prospective source for future mineral resource exploration.

A comprehensive review is carried out on the models and correlations for solid/fluid reactions that result from a complex multi-scale physicochemical process. A simulation of this process with CFD requires various complicated submodels and significant computational time, which often makes it undesirable and impractical in many industrial activities requiring a quick solution within a limited time frame, such as new product/process design, feasibility studies, and the evaluation or optimization of the existing processes, etc. In these circumstances, the existing models and correlations developed in the last few decades are of significant relevance and become a useful simulation tool. However, despite the increasing research interests in this area in the last thirty years, there is no comprehensive review available. This paper is thus motivated to review the models developed so far, as well as provide the selection guidance for model and correlations for the specific application to help engineers and researchers choose the most appropriate model for feasible solutions. Therefore, this review is also of practical relevance to professionals who need to perform engineering design or simulation work. The areas needing further development in solid–fluid reaction modelling are also identified and discussed.

Soil moisture and salinity are crucial parameters of the Earth’s ecosystem; how to understand the radiation properties of them is of great significance for remote sensing monitoring. In this study, the application of mixed soil dielectric models (Dobson and generalized refractive mixing dielectric model (GRMDM)) and saline soil dielectric models (Dobson-S, HQR (Qingrong Hu), and WYR (Yueru Wu)) were analyzed to select the optimal models to simulate brightness temperature based on observational data. The brightness temperature of the soil moisture and multilevel salinity was simulated by using the Q-H (parameter of polarization mixing and parameter of characterizing height) model and Holmes parameterization scheme of soil effective temperature. The results show that both the Dobson model and the GRMDM model can well reproduce the real part and imaginary part of the dielectric constant of non-saline soil, and the GRMDM model was better. With the increase of the frequency, the simulation error of the dielectric constant of the saline soil by using the Dobson-S model, HQR model, and WYR model also increased, and the simulation result of the WYR model was better in the L band. The simulated result of the brightness temperature of soil moisture between the observation value and simulation value presented a high correlation both in the horizontal polarization and vertical polarization, with R greater than 0.967 and 0.948, and the root mean square error smaller than 3.998 K and 2.766 K, respectively. Meanwhile, the correlation coefficients of the brightness temperature of the saline soil in the horizontal polarization and vertical polarization were 0.935 and 0.971, and the root mean square errors were 5.808 K and 4.65 K, respectively. The brightness temperature decreased as the soil salinity increased, and the higher the salinity content was, the quicker the brightness temperature decreased. We expect that the experimental results can be used as a reference for algorithm developers to further enhance the accuracy of soil moisture and soil salinity retrievals.

AIM:To investigate the effect of temperature, humidity and the concentration of ambient air pollution on the hospitalization of AECOPD. METHOD:Hospitalization record was obtained from Shenyang Medical Insurance Bureau, concluding patient's age, gender, income hospital time, outcome hospital; Generalized additive model was used to analyze the relationship between temperature, humidity, the concentration of ambient air pollution and the hospitalization of AECOPD. RESULT:The effect of ozone on admission rate in male group was higher than that in female group. Ambient air pollution had a weak influence on age≤50 group. It was found that the optimal lag day for daily relative 40 humidity to age≤50 group, 5070 group was on lag5, lag4, lag4 and lag5, respectively. CONCLUSION:Air pollution, relative humidity and temperature can increase the risk of admission for acute exacerbation of COPD, and in this process there was a lag effect.

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This paper deals with the effect of termination restraint due to end fitting on the stress evaluation of tensile armors in unbonded flexible pipes under axial tension. The problem is characterized by one single armoring tendon helically wound on a cylindrical supporting surface subjected to traction. The deviation from the initial helical angle is taken to describe the armor wire path as the pipe is stretched. The integral of this angle change gives the lateral displacement of the wire, which is determined by minimizing the energy functional that consists of the strain energy due to axial strain, local bending and torsion, and the energy dissipated by friction, leading to a variational problem with a variable endpoint. The governing differential equation of the wire lateral displacement, together with the supplementary condition, is derived using the variational method and solved analytically. The developed model is verified with a finite element (FE) simulation. Comparisons between the model predictions and the FE results in terms of the change in helical angle and transverse bending stress show good correlations. The verified model is then applied to study the effects of imposed tension and friction coefficient on the maximum bending stress. The results show that the response to tension is linear, and friction could significantly increase the stress at the end fitting compared with the frictionless case. [ABSTRACT FROM AUTHOR]

Analytical formulations are presented to determine the bending moment-curvature relationship of a helical layer in unbonded flexible pipes. Explicit expressions describing the variation of both bending stiffness and moment as a function of the applied curvature are given. The approach takes into account the nonlinearity of the response caused by the interlayer slip. The contribution of local bending and torsion of individual helical elements to the bending behavior of helical layers is included. Theoretical results for a typical unbonded flexible pipe using the nonlinear formulation for helical layers are compared with experimental data from the available literature. Encouraging correlations are found and the importance of the initial interlayer pressures is seen. The influence of local bending and torsion of individual helical elements on the bending behavior of the entire pipe is also evaluated. The results show that the inclusion of this local behavior significantly influences the full-slip bending stiffness. [ABSTRACT FROM AUTHOR]