Search

The mid-Pleistocene transition (MPT) [~1.25 to 0.85 million years ago (Ma)] marks a shift in the character of glacial-interglacial climate ( 1 , 2 ). One prevailing hypothesis for the origin of the MPT is that glacial deep ocean circulation fundamentally changed, marked by a circulation "crisis" at ~0.90 Ma (marine isotope stages 24 to 22) ( 3 ). Using high-resolution paired neodymium, carbon, and oxygen isotope data from the South Atlantic Ocean (Cape Basin) across the MPT, we find no evidence of a substantial change in deep ocean circulation. Before and during the early MPT (~1.30 to 1.12 Ma), the glacial deep ocean variability closely resembled that of the most recent glacial cycle. The carbon storage facilitated by developing deep ocean stratification across the MPT required only modest circulation adjustments.

Atmospheric CO2 variability on the glacial–interglacial (G–IG) timescale reflects a balance between oceanic and terrestrial processes involving carbon uptake and release. The Southern Ocean CO2 uptake is considered as an important modulator for the G–IG atmospheric CO2 variability, while the role of tropical ocean ventilation remains enigmatic. We present critical evidence for CO2 ventilation from the tropical Indian Ocean through the reconstruction of the Arabian Sea‐surface pCO2 for the past ∼136 ka utilizing boron isotope (δ11B) record of planktic foraminifera, Globigerinoides ruber. Our site in the Arabian Sea presently acts as a significant source of CO2. The reconstructed ΔpCO2 (ΔpCO2 = pCO2 Seawater − pCO2 Atmosphere) record shows an enhanced CO2 degassing up to ∼50 ppm during the major cooling events, such as the Last Glacial Maximum, Younger Dryas, and Heinrich‐Stadials. Our investigation based on multiproxy records of sea‐surface temperature, salinity, and productivity suggests that the northward invasion and shoaling of southern source CO2‐rich water, coupled with stronger upwelling, resulted in CO2 degassing during these cold intervals. This finding is in align with the tropical Atlantic which also demonstrated an enhanced CO2 degassing during the cold intervals; however, most of the upwelled CO2 was consumed as the water moved away from the upwelling sites. Therefore, our finding, when considered alongside tropical Atlantic records, suggests that tropical oceans played a minor role in reducing atmospheric CO2 levels during the cold intervals of the last glacial cycle, supporting the prevailing hypothesis. Key Points: Foraminifera δ11B‐based CO2 record of Arabian Sea surface for the past ∼136 kaEnhanced CO2 degassing during the cold climate events, that is, Heinrich‐Stadials, Younger Dryas, and Last Glacial MaximumThis degassing was caused by more export of southern‐sourced water and its upwelling [ABSTRACT FROM AUTHOR]

Global overturning circulation underwent significant changes in the late Miocene, driven by tectonic forcing, and impacted the global climate. Prevailing hypotheses related to the late Miocene deep water circulation (DWC) changes driven by the closure of the Central American Seaways (CAS) and its widespread impact remains untested due to the paucity of suitable records away from the CAS region. Here, we test the hypothesis of the large-scale circulation changes by providing a high-resolution record of DWC since the late Miocene (11.3 to ~2 Ma) from the north-western Indian Ocean. Our investigation reveals a progressive shift from Pacific-dominated DWC before ~9.0 Ma to the onset of a modern-like DWC system in the Indian Ocean comprising of Antarctic bottom water and northern component water during the Miocene-Pliocene transition (~6 Ma) caused by progressive shoaling of the CAS and suggests its widespread impact., (© 2022. The Author(s).)

Atmospheric CO2 rise in post‐industrial era has resulted in decline in surface ocean pH, commonly known as "ocean acidification (OA)," which has become a threat to marine calcifiers. Instrumental records of ocean pH and its reconstruction utilizing boron isotope (δ11B) composition of corals demonstrate a long‐term OA trend characterized by large spatio‐temporal variability in both Pacific and Atlantic oceans. However, no such record exists to elucidate long‐term OA trend of the Indian Ocean. We report the first sub‐annually resolved pH record (1990–2013) from the Arabian Sea based on δ11B measurements on Porites coral from Lakshadweep coral reefs. This pH record is characterized by large variability ranging from 7.93 to 8.65 with no long‐term discernable trend. The long‐term declining trend expected from the ∼50 ppm increase in atmospheric CO2 during the coral growth interval appears to be obscured by large surface pH variability in the Arabian Sea. Our investigation reveals that physical oceanographic processes for example, upwelling, downwelling and convective mixing modulated by El Niño‐Southern Oscillation (ENSO) largely control surface pH variability and masked expected long‐term OA trend resulting from anthropogenic CO2 rise. Combining the model‐based predictions of increase in frequency and amplitude of ENSO events in a future warming scenario and the observed ENSO dependency of surface water pH, we predict more frequent and large pH variability ("pH extremes") in this region. Such pH extremes and their occurrences might be critical for the resilience and adaptability of corals and other calcifiers in Arabian Sea and other similar oceanic settings elsewhere. Plain Language Summary: Increase in the atmospheric CO2 concentration since the industrial revolution (∼1850) has resulted in decrease in ocean pH, known as ocean acidification (OA). Only limited number of pH records are avalable to assess the impacts of OA on marine ecosystems. The available pH records from the Pacific and Atlantic oceans, based on both instrumental observations and coral boron isotope records, demonstrate a long‐term declining trend with significant internal variability. However, no such records are available from the Indian Ocean. Here, we provide the first seasonally resolved record of Indian Ocean pH for a 23 year period (1990–2013) based on boron isotope study of corals collected from the Lakshadweep, Arabian Sea. pH variability in the Arabian Sea is domiantly controlled by ENSO modulated oceanographic processes such as upwelling and mixing. We did not observe any long‐term declining trend corresponding to the ∼50 ppm rise in atmospheric CO2 during the studied interval. The OA trend is possibly obscured by large surface pH variability in the Arabian Sea. Based on our observation and model based simulation showing an increase in ENSO frequency and amplitude for future scenarios, we expect that pH extremes are likely to increase, which is critical for resilience and adaptability of calcifying marine organisms. Key Points: We provide the first coral δ11B‐pH record (1990–2013) from the Indian Ocean at sub‐annual resolutionLong‐term ocean acidification trend expected from atmospheric CO2 rise is obscured by large surface pH variability in the Arabian SeaPhysical oceanographic processes modulated by El Niño‐Southern Oscillation control large inter‐annual surface pH variability in the Arabian Sea [ABSTRACT FROM AUTHOR]

Prior to ~1 million years ago (Ma), variations in global ice volume were dominated by changes in obliquity; however, the role of precession remains unresolved. Using a record of North Atlantic ice rafting spanning the past 1.7 million years, we find that the onset of ice rafting within a given glacial cycle (reflecting ice sheet expansion) consistently occurred during times of decreasing obliquity whereas mass ice wasting (ablation) events were consistently tied to minima in precession. Furthermore, our results suggest that the ubiquitous association between precession-driven mass wasting events and glacial termination is a distinct feature of the mid to late Pleistocene. Before then (increasing), obliquity alone was sufficient to end a glacial cycle, before losing its dominant grip on deglaciation with the southward extension of Northern Hemisphere ice sheets since ~1 Ma.

The dominant feature of large-scale mass transfer in the modern ocean is the Atlantic meridional overturning circulation (AMOC). The geometry and vigour of this circulation influences global climate on various timescales. Palaeoceanographic evidence suggests that during glacial periods of the past 1.5 million years the AMOC had markedly different features from today 1 ; in the Atlantic basin, deep waters of Southern Ocean origin increased in volume while above them the core of the North Atlantic Deep Water (NADW) shoaled 2 . An absence of evidence on the origin of this phenomenon means that the sequence of events leading to global glacial conditions remains unclear. Here we present multi-proxy evidence showing that northward shifts in Antarctic iceberg melt in the Indian-Atlantic Southern Ocean (0-50° E) systematically preceded deep-water mass reorganizations by one to two thousand years during Pleistocene-era glaciations. With the aid of iceberg-trajectory model experiments, we demonstrate that such a shift in iceberg trajectories during glacial periods can result in a considerable redistribution of freshwater in the Southern Ocean. We suggest that this, in concert with increased sea-ice cover, enabled positive buoyancy anomalies to 'escape' into the upper limb of the AMOC, providing a teleconnection between surface Southern Ocean conditions and the formation of NADW. The magnitude and pacing of this mechanism evolved substantially across the mid-Pleistocene transition, and the coeval increase in magnitude of the 'southern escape' and deep circulation perturbations implicate this mechanism as a key feedback in the transition to the '100-kyr world', in which glacial-interglacial cycles occur at roughly 100,000-year periods.

To decipher sediment provenance, understand dispersal pattern and its controlling factors in the Indian Ocean, we have studied major and trace element abundances and isotope compositions of Sr (87Sr/86Sr) and Nd (εNd) in silicate fractions of 38 surface sediment samples collected at ~1.5° interval from India (~10°N) to Antarctica (~70°S). The 87Sr/86Sr ratio and εNd vary from 0.70527 and 0.1 near Crozet Island to 0.77854 and −34.8 near Antarctica, respectively. Higher 87Sr/86Sr ratio and lower εNd near Antarctica indicate source of old granitic rocks, and the opposite is observed in sediments from the Central and the Southwest Indian Ridges indicating source of seafloor spreading and mid‐ocean ridge hydrothermal activity. Chondrite normalized Rare Earth Elements (REEs) pattern reveals positive Europium anomaly for Central and Southwest Indian Ridge sediments, while positive Gadolinium anomaly is observed in Indian and Antarctic coastal sediments. Sediments in the Indian sector of Southern Ocean and coastal Antarctica are highly dispersed through deep, bottom, and Antarctic circumpolar currents. The εNd spatial map generated for the entire Indian Ocean based on compilation of present study and results from literature shows dominance of terrigenous inputs from continental erosion with minor contribution from the ridges in the Indian Ocean. The εNd map together with trace elements can be employed for reconnaissance for mineral exploration associated with hydrothermal deposits. Further, comparison of detrital εNd with its counter phases, that is, authigenic fractions and modern seawater at the sampling sites, would enhance our knowledge of benthic exchange processes, with an implication in using Nd isotopes as a water mass circulation proxy. Key Points: Sediment provenance and dispersal pattern were studied in the Indian Ocean based on Sr and Nd isotope compositions of surface sediment collected along N‐S transect (10°N–70°S) from India to AntarcticaIn the entire study region, the 87Sr/86Sr ratio and εNd vary from 0.70527 and 0.10 near Crozet Island to 0.77854 and − 34.8 near Antarctic coast, respectivelyThe εNd surface plot generated for the entire Indian Ocean shows dominance of terrigenous inputs from continental erosion with minor contribution from Indian Ocean ridges [ABSTRACT FROM AUTHOR]

The current study aims to understand the speciation and fate of Cu complexes in hydrothermally altered sediments from the Central Indian Ocean Basin and assess the probable impacts of deep-sea mining on speciation of Cu complexes and assess the Cu flux from this sediment to the water column in this area. This study suggests that most of the Cu was strongly associated with different binding sites in Fe-oxide phases of the hydrothermally altered sediments with stabilities higher than that of Cu-EDTA complexes. The speciation of Cu indicates that hydrothermally influenced deep-sea sediments from Central Indian Ocean Basin may not significantly contribute to the global Cu flux. However, increasing lability of Cu-sediment complexes with increasing depth of sediment may increase bioavailability and Cu flux to the global ocean during deep-sea mining. [ABSTRACT FROM AUTHOR]

Future climate and sea level projections depend sensitively on the response of the Antarctic Ice Sheet to ocean-driven melting and the resulting freshwater fluxes into the Southern Ocean. Circumpolar Deep Water (CDW) transport across the Antarctic continental shelf and into cavities beneath ice shelves is increasingly recognised as a crucial heat source for ice shelf melt. Quantifying past changes in the temperature of CDW is therefore of great benefit for modelling ice sheet response to past warm climates, for validating paleoclimate models, and for putting recent and projected changes in CDW temperature into context. Here we compile the available bottom water temperature reconstructions representative of CDW over the past 800 kyr. Estimated interglacial warming reached anomalies of +0.6 ± 0.4 °C (MIS 11) and +0.5 ± 0.5 °C (MIS 5) relative to present. Glacial cooling typically reached anomalies of ca. -1.5 to -2 °C , therefore maintaining positive thermal forcing for ice shelf melt even during glacials in the Amundsen Sea region of West Antarctica. Despite high variance amongst a small number of records and poor (4 kyr) temporal resolution, we find persistent and close relationships between our estimated CDW temperature and Southern Ocean sea surface temperature, Antarctic surface air temperature, and global deep-water temperature reconstructions at glacial-cycle timescales. Given the important role that CDW plays in connecting the world's three main ocean basins and in driving Antarctic Ice Sheet mass loss, additional temperature reconstructions targeting CDW are urgently needed to increase temporal and spatial resolution and to decrease uncertainty in past CDW temperatures – whether for use as a boundary condition, for model validation, or for understanding past oceanographic changes. [ABSTRACT FROM AUTHOR]

Relative palaeointensity (RPI) records can reflect the evolution of the Earth's axial dipole field and provide a suitable template for global stratigraphic correlation. Current RPI records are primarily obtained from the Atlantic and Pacific Oceans, particularly in the mid-latitudes of the Northern Hemisphere. Fewer RPI records originate from the Indian Ocean, particularly in low latitude areas, which limits sediment dating and geomagnetic evolution studies in these regions. In this study, we conduct a palaeomagnetic study on four sediment cores recovered from the western equatorial Indian Ocean (WEIO) to establish a new regional RPI stack from the past 500 ka for the global coverage of palaeointensity data, as well as a regional reference for palaeointensity-assisted stratigraphy. To estimate the RPI, the isothermal remanent magnetization is used as a normalizer. A chronological framework is constructed by correlating RPI records and environmental magnetic parameters (anhysteretic remanent magnetizationsaturation/isothermal remanent magnetization, ARM/SIRM) with PISO-1500 and LR04 δ18O curves, respectively. Our RPI stacked curve (WEIO-500) varies according to global and other regional high-resolution records. The five lows in the obtained RPI curve can be correlated with previously reported excursions. In addition, the mean inclination direction of each core is similar to the expected hypothetical geocentric axial dipole direction, with a negative inclination anomaly (mean Δ I) of −2.18° to −4.86°. The low mean Δ I and its reproducibility reflect the reliability of our chronological framework and stacked curve, thereby providing a new reference for correlating and calibrating RPI records from WEIO as well as other equatorial areas. [ABSTRACT FROM AUTHOR]

The Bengal Fan covers the entire floor of the Bay of Bengal (BoB) and has accumulated erosional material from the Himalayas since the Early Eocene. The fan architecture is constructed by turbidity current deposits via channel levee systems during active fan progradation and hemipelagic sedimentation during periods of local fan inactivity. In the present study, we document the fan development, sedimentation history, and depositional processes in the lower Bengal Fan and present a site-to-site comparison of stratigraphy and channel migration since the Late Tortonian (ca. 7.5 Ma) from sedimentological and physical property records at Site U1451 of IODP Expedition 354 to 8°N in the lower Bengal Fan. Fine sediment (Sortable Silt, SS) textural and sorting records are used to reconstruct the current skinfriction shear stress in the Benthic Boundary Layer (BBL) of the BoB. Also, a distinction in shear stress environment between turbidity dominated active fan and background hemipelagic fan growth is presented. A criterion is set in the following paper to validate the use of SS records in hemipelagic deposits in the BoB to decipher the shear stress regimes of depositing flows on the basis of sand weight percentage and mean SS sizes (S͞S) variation. This study will enhance our understanding of the Bengal Fan deposition dynamics and fan development with the reconstructed shear stress regimes associated with various depositing flows (turbidity current and/or deep water circulation). It will provide a strong base to model fan internal processes and material flux to the BoB. [ABSTRACT FROM AUTHOR]

Mean Sortable Silt (SS) size records in the hemipelagic deposits at Site U1452 (IODP 354) in the lower Bengal Fan are presented here to reconstruct the bottom water circulation strengths in the Bay of Bengal (BoB) during the last 200 ka (Marine Isotopic Stage 1 to 6). To eliminate possible amplitude shifts in SS size due to terrestrial sediment flux or turbiditic interventions, sedimentation history at the site is decomposed using End Member Analysis (EMA). SS size record in the BoB is mostly unimpacted by the terrestrial sediment flux and turbidity current deposition; hence the size sorting signature in SS records is best described to have arisen from benthic boundary layer current intensity. SS size record in the BoB indicates reduced bottom water flow speed during glacials (MIS 2 and 6), concomitant with the greater import of Antarctic/ Southern Ocean (SO) derived deep waters and increased speed during interglacials (MIS 1, 3 and 5) corresponding to an increased proportion of Northern Atlantic derived deep water mass in the northern Indian Ocean. Glacial and stadial decline in flow speed reflects on the density reversal between two deep water mass end members in the SO and a shoaled Atlantic meridional overturning circulation (AMOC). On the other hand, faster flow speed during the climate optima at MIS 5.5 and other warm substages of MIS 5 as well as during the Holocene present a deep and strong AMOC. Reduced bottom water circulation strength in the BoB during the MIS 5.5 to 5.4 transition might have contributed to atmospheric CO2 drawdown and global cooling during the early stages of glacial inception along with deep circulation changes in the SO. Also, millennial-scale variability in circulation strength in the BoB is linked to oceanic frontal shift in high northern latitudes and deepwater formation manifesting in reduced flow strength associated with local cold anomalies (C28-C23), successively culminating into glacial inception at MIS 5.4. Reduced flow speed is also observed during some of the Heinrich events indicating a strong teleconnection between deep North Atlantic and BoB. Productivity changes in the BoB might as well have been influenced by variable fluxes of northern and southern sourced water mass during the last 200 ka. [ABSTRACT FROM AUTHOR]

Reconstructing the strength and depth boundary of oxygen minimum zones (OMZs) in the glacial ocean advances our understanding of how OMZs respond to climate changes. While many efforts have inferred better oxygenation of the glacial Arabian Sea OMZ from qualitative indices, oxygenation and vertical extent of the glacial OMZ is not well quantified. Here we present glacial‐Holocene oxygen reconstructions in a depth transect of Arabian Sea cores ranging from 600 to 3,650 m water depths. We estimate glacial oxygen concentrations using benthic foraminiferal surface porosity and benthic carbon isotope gradient reconstructions. Compared to the modern Arabian Sea, glacial oxygen concentrations were approximately 10–15 μmol/kg higher in the shallow OMZ (<1,000 m), and 5–80 μmol/kg lower at greater depths (1,500–3,650 m). Our results suggest that the OMZ in the glacial Arabian Sea was slightly better oxygenated but remained in the upper 1,000 m. We propose that the small increase in oxygenation of the Arabian Sea OMZ during the last glacial period was due to weaker upper ocean stratification induced by stronger winter monsoon winds coupled with an increase in oxygen solubility due to lower temperatures, counteracting the effects of more oxygen consumption resulting from higher primary productivity. Large‐scale changes in ocean circulation may have also contributed to better ventilation of the glacial Arabian Sea OMZ. Key Points: The glacial Arabian Sea oxygen minimum zone (OMZ) was slightly weaker but spanned the same depth range as modernEnhanced oxygen supply locally and/or from the Southern Ocean likely explained the weaker OMZ in the glacial Arabian SeaBottom water oxygen in the deep glacial Arabian Sea ranged between 50 and 100 μmol/kg [ABSTRACT FROM AUTHOR]

The Tibetan Plateau is an important area for studying global climate change, but the answers to many scientific problems remain unknown. Here, we present new information from the lacustrine sedimentary record in the western Tibetan Plateau, related to the third most‐recent glaciations. Continuous sediment data, including sporopollen, particle size, total organic carbon, mass susceptibility, CaCO3, CaSO4, BaSO4 contents and chronological data, were reconstructed and revealed that climate and environmental conditions obviously and distinctly changed between 600 and 700 thousand years ago. In comparison, the data obtained from the Guliya ice core in this area also corresponds to the global glacial climatic characteristics recorded in basin sediments in the eastern and southeastern regions of the plateau and to the information obtained from ice cores in the Antarctic and Arctic regions. In this study, we conclude that the main reason for the glaciations and new tectonic movement must be a geomagnetic polarity reversal 774 thousand years ago (from Matuyama to Brunhes). Indeed, the results of this study suggest that the described reversal event might have influenced the current global climate pattern and will continue to impact climatic changes in the future. [ABSTRACT FROM AUTHOR]

In biogeography, vicariance and long-distance dispersal are often characterised as competing scenarios. However, they are related concepts, both relying on collective geological, ecological, and phylogenetic evidence. This is illustrated by freshwater fishes, which may immigrate to islands either when freshwater connections are temporarily present and later severed (vicariance), or by unusual means when ocean gaps are crossed (long-distance dispersal). Marine barriers have a strong filtering effect on freshwater fishes, limiting immigrants to those most capable of oceanic dispersal. The roles of vicariance and dispersal are debated for freshwater fishes of the Greater Antilles. We review three active hypotheses [Cretaceous vicariance, Greater Antilles-Aves Ridge (GAARlandia), long-distance dispersal] and propose long-distance dispersal to be an appropriate model due to limited support for freshwater fish use of landspans. Greater Antillean freshwater fishes have six potential source bioregions (defined from faunal similarity): Northern Gulf of México, Western Gulf of México, Maya Terrane, Chortís Block, Eastern Panamá, and Northern South America. Faunas of the Greater Antilles are composed of taxa immigrating from many of these bioregions, but there is strong compositional disharmony between island and mainland fish faunas (>90% of Antillean species are cyprinodontiforms, compared to <10% in Northern Gulf of México and Northern South America, and ≤50% elsewhere), consistent with a hypothesis of long-distance dispersal. Ancestral-area reconstruction analysis indicates there were 16 or 17 immigration events over the last 51 million years, 14 or 15 of these by cyprinodontiforms. Published divergence estimates and evidence available for each immigration event suggests they occurred at different times and by different pathways, possibly with rafts of vegetation discharged from rivers or washed to sea during storms. If so, ocean currents likely provide critical pathways for immigration when flowing from one landmass to another. On the other hand, currents create dispersal barriers when flowing perpendicularly between landmasses. In addition to high salinity tolerance, cyprinodontiforms collectively display a variety of adaptations that could enhance their ability to live with rafts (small body size, viviparity, low metabolism, amphibiousness, diapause, self-fertilisation). These adaptations likely also helped immigrants establish island populations after arrival and to persist long term thereafter. Cichlids may have used a pseudo bridge (Nicaragua Rise) to reach the Greater Antilles. Gars (Lepisosteidae) may have crossed the Straits of Florida to Cuba, a relatively short crossing that is not a barrier to gene flow for several cyprinodontiform immigrants. Indeed, widespread distributions of Quaternary migrants (Cyprinodon, Gambusia, Kryptolebias), within the Greater Antilles and among neighbouring bioregions, imply that long-distance dispersal is not necessarily inhibitory for well-adapted species, even though it appears to be virtually impossible for all other freshwater fishes., (© 2024 Cambridge Philosophical Society.)

Climate during the last glacial period was marked by abrupt instability on millennial timescales that included large swings of temperature in and around Greenland (Daansgard–Oeschger events) and smaller, more gradual changes in Antarctica (AIM events). Less is known about the existence and nature of similar variability during older glacial periods, especially during the early Pleistocene when glacial cycles were dominantly occurring at 41 kyr intervals compared to the much longer and deeper glaciations of the more recent period. Here, we report a continuous millennially resolved record of stable isotopes of planktic and benthic foraminifera at IODP Site U1385 (the "Shackleton Site") from the southwestern Iberian margin for the last 1.5 million years, which includes the Middle Pleistocene Transition (MPT). Our results demonstrate that millennial climate variability (MCV) was a persistent feature of glacial climate, both before and after the MPT. Prior to 1.2 Ma in the early Pleistocene, the amplitude of MCV was modulated by the 41 kyr obliquity cycle and increased when axial tilt dropped below 23.5 ∘ and benthic δ18O exceeded ∼3.8 ‰ (corrected to Uvigerina), indicating a threshold response to orbital forcing. Afterwards, MCV became focused mainly on the transitions into and out of glacial states (i.e. inceptions and terminations) and during times of intermediate ice volume. After 1.2 Ma, obliquity continued to play a role in modulating the amplitude of MCV, especially during times of glacial inceptions, which are always associated with declining obliquity. A non-linear role for obliquity is also indicated by the appearance of multiples (82, 123 kyr) and combination tones (28 kyr) of the 41 kyr cycle. Near the end of the MPT (∼0.65 Ma), obliquity modulation of MCV amplitude wanes as quasi-periodic 100 kyr and precession power increase, coinciding with the growth of oversized ice sheets on North America and the appearance of Heinrich layers in North Atlantic sediments. Whereas the planktic δ18O of Site U1385 shows a strong resemblance to Greenland temperature and atmospheric methane (i.e. Northern Hemisphere climate), millennial changes in benthic δ18O closely follow the temperature history of Antarctica for the past 800 kyr. The phasing of millennial planktic and benthic δ18O variation is similar to that observed for MIS 3 throughout much of the record, which has been suggested to mimic the signature of the bipolar seesaw – i.e. an interhemispheric asymmetry between the timing of cooling in Antarctica and warming in Greenland. The Iberian margin isotopic record suggests that bipolar asymmetry was a robust feature of interhemispheric glacial climate variations for at least the past 1.5 Ma despite changing glacial boundary conditions. A strong correlation exists between millennial increases in planktic δ18O (cooling) and decreases in benthic δ13C , indicating that millennial variations in North Atlantic surface temperature are mirrored by changes in deep-water circulation and remineralization of carbon in the abyssal ocean. We find strong evidence that climate variability on millennial and orbital scales is coupled across different timescales and interacts in both directions, which may be important for linking internal climate dynamics and external astronomical forcing. [ABSTRACT FROM AUTHOR]

The evolution and driving mechanism of the South Asian summer monsoon (SASM) are still poorly understood. We here present a 12-Myr long SASM record by analyzing the strontium and neodymium isotopic composition of detrital components at IODP Exp. 359 Site U1467 from the northern Indian Ocean. The provenance investigation demonstrates that more dust enriched in εNd from northeastern Africa and the Arabian Peninsula was transported to the study site by monsoonal and Shamal winds during the summer monsoon season. A two-step weakening of the SASM wind since ~12 Ma is proposed based on the εNd record. This observational phenomenon is supported by climate modeling results, demonstrating that the SASM evolution was mainly controlled by variations in the gradient between the Mascarene High and the Indian Low, associated with meridional shifts of the Hadley Cell and the Intertropical Convergence Zone, which were caused by interhemispheric ice-sheet growth since the Middle Miocene.The εNd record from the IODP Exp. 359 Site U1467 in the northern Indian Ocean, along with climate modeling, reveals a two-step weakening of the South Asian summer monsoon (SASM) wind since 12 Ma. The SASM evolution was mainly caused by interhemispheric ice-sheet growth since the Middle Miocene. [ABSTRACT FROM AUTHOR]

The Indian Ocean (IO) is witnessing acidification as a direct consequence of the continuous rising of atmospheric CO2 concentration and indirectly due to rapid ocean warming, which disrupts the pH of the surface waters. This study investigates the pH seasonality and trends over various bio‐provinces of the IO and regionally assesses the contribution of each of its controlling factors. Simulations from a global and a regional ocean model coupled with biogeochemical modules were validated with pH measurements over the basin and used to discern the regional response of pH seasonality (1990–2010) and trend (1961–2010) to changes in Sea Surface Temperature (SST), Dissolved Inorganic Carbon (DIC), Total Alkalinity (ALK), and Salinity (S). DIC and SST are significant contributors to the seasonal variability of pH in almost all bio‐provinces. Total acidification in the IO basin was 0.0675 units from 1961 to 2010, with 69.3% contribution from DIC followed by 13.8% contribution from SST. For most of the bio‐provinces, DIC remains a dominant contributor to changing trends in pH except for the Northern Bay of Bengal and Around India (NBoB‐AI) region, wherein the pH trend is dominated by ALK (55.6%) and SST (16.8%). Interdependence of SST and S over ALK is significant in modifying the carbonate chemistry and biogeochemical dynamics of NBoB‐AI and a part of tropical, subtropical IO bio‐provinces. A strong correlation between SST and pH trends infers an increasing risk of acidification in the bio‐provinces with rising SST and points out the need for sustained monitoring of IO pH in such hotspots. Plain Language Summary: As CO2 increases in the atmosphere due to anthropogenic activities, more and more CO2 dissolves in the ocean. This increases the acidity of seawater leading to a phenomenon known as ocean acidification. Indian Ocean (IO) is a mild sink of CO2 and its strength is decreasing owing to acidification. In this study, the seasonal variation of surface pH in IO and its long‐term changes are studied, over eight different IO bio‐provinces. Here, using 50 years of model data and observations, we found that acidification is occurring more rapidly in the IO. We have also found a high correlation between sea surface temperature (SST) and pH suggesting that the pH would continue to decrease with increase in SST due to global warming. The study helps to quantify the individual contribution of factors causing this decrease in pH and identify acidification hotspots. It is found that dissolved inorganic carbon and SST dominate the seasonal variation of pH and counterbalance each other. Key Points: Controlling factors of the seasonal variability of pH and its trends over various Indian Ocean (IO) bio‐provinces are investigatedDissolved Inorganic Carbon and Sea Surface Temperature (SST) are major driving forces contributing to the seasonal variability and trends in pH and counterbalance over the IOSST trends directly correlate with acidification trends in IO bio‐provinces, indicating that ocean warming enhances acidification [ABSTRACT FROM AUTHOR]

A new matrix‐matched reference material has been developed – NFHS‐2‐NP (NIOZ Foraminifera House Standard‐2‐Nano‐Pellet) – with element mass fractions, and isotope ratios resembling that of natural foraminiferal calcium carbonate. A 180–355 µm size fraction of planktic foraminifera was milled to nano‐particles and pressed to pellets. We report reference and information values for mass fractions of forty‐six elements measured by six laboratories as well as for 87Sr/86Sr (three laboratories), δ13C, δ18O (five laboratories) and 206,207,208Pb/204Pb isotope ratios (one laboratory) determined by ICP‐MS, ICP‐OES, MC‐ICP‐MS, isotope ratio mass spectrometry, WD‐XRF and TIMS. Inter‐ and intra‐pellet elemental homogeneity was tested using multiple LA‐ICP‐MS analyses in two laboratories applying spot sizes of 60 and 70 µm. The LA‐ICP‐MS results for most of the elements relevant as proxies for palaeoclimate research show RSD values < 3%, demonstrating a satisfactory homogeneous composition. Homogeneity of 87Sr/86Sr ratios of the pellet was verified by repeated LA‐MC‐ICP‐MS by two laboratories. Information values are reported for Pb isotope ratios and δ13C, δ18O values. The homogeneity for these isotope systems remains to be tested by LA‐MC‐ICP‐MS and secondary‐ion mass spectrometry. Overall, our results confirm the suitability of NFHS‐2‐NP for calibration or monitoring the quality of in situ geochemical techniques. [ABSTRACT FROM AUTHOR]

Anthropogenic CO2 emission has resulted in lowering of surface ocean pH referred as ‘Ocean acidification (OA)’ which posed a serious threat to calcifying marine organisms. Several attempts have been made to assess the role of anthropogenic CO2 forcing against oceanographic factors/processes contributing to the recent OA trend; however, such attempts were hindered by the dearth of long-term pH records. Boron isotopic composition (δ11B) of corals has been used as a robust proxy for seawater pH records. In the present study, we have compiled available coral δ11B-pH records from the Indian, Pacific and Atlantic oceans and assessed regional trends, variability, forcing factors and their relative roles. Most of these δ11B-pH records show a discernable decline trend in recent decades with large variability. Our assessment of the Pacific records reveals that atmospheric CO2 forcing explains maximum pH variability followed by physical oceanographic factors/processes modulated by Pacific oscillations, e.g., ENSO and PDO. In addition, coral metabolic processes might control a large portion of the pH variability; however, they require detailed laboratory-based studies. Further, our investigation reveals a significant increase in pH variability (pH extremes) since ~1970s associated with ENSO events which might be critical for the resilience and adaptability of corals and other calcifiers. Research Highlights: Since the industrial era (~1850), Coral δ11B-pH records show a discernible decreasing trend and a rapid decline since 1970. Oceanographic processes control large inter-annual pH variability, whereas the long-term declining trend is driven by atmospheric CO2 forcing. The pH extremes are predicted to increase in future warming scenarios, a threat to coral ecosystem. [ABSTRACT FROM AUTHOR]

The Banded Gneissic Complex (BGC) of the Aravalli Craton (India) comprises Archean BGC‐I (3.3–2.5 Ga) and Proterozoic BGC‐II. The BGC‐II is a mosaic of amphibolite facies namely, (a) Mangalwar Gneissic Complex (MGC), (b) Mangalwar Metasedimentary Complex (MMC), and (c) granulite‐facies Sandmata Metamorphic Complex. Here we present field, petrography and geochemical study of the Proterozoic amphibolites from the MGC and MMC. Based on field and geochemical data, the amphibolites have been characterized into three types related to rift settings (G1, G2 and G3). The G1 type occurs as dykes in the MGC and bears ocean island basalt‐type rare earth element (REE) patterns along with negative Nb and Ti anomalies, negative to positive values of εNd(t) (−0.02 to +3.96) and slightly variable initial 87Sr/86Sr (ISr) ratios. They are derived from deep mantle sources and correspond to the pre‐rift magmatic phase. The G2 type occurs as isolated patches associated with chert and is characterized by light REE (LREE) depleted and almost flat heavy REE (HREE) patterns suggesting that they were emplaced in an oceanic setting and were derived from a shallower mantle bearing positive εNd(t) (+2.87 to +6.27) and ISr = 0.7002–0.7083. This phase corresponds to the opening of the Mangalwar sedimentary basin (MMC). The G3 type occurs intercalated with metasedimentary rocks of the MMC and marked by LREE‐enriched and HREE‐depleted to flat patterns that resemble Upper Continental Crust signature, their εNd(t) mostly negative values and variable ISr also corroborate this explanation. They are believed to be derived from heterogeneous sources and represent syn‐sedimentary volcanic phases. All these signatures indicate that the amphibolites distinctly represent three phases of magmatism that occurred during pre‐rift (1.72 Ga), opening of basin (1.62 Ga) and syn‐sedimentary volcanism (1.6–1.3 Ga) in the rift‐basin and they were formed during the Proterozoic. These rifting events might have been connected with the fragmentation of Columbia. [ABSTRACT FROM AUTHOR]

Smear slide petrography has been a standard technique during scientific ocean drilling expeditions to characterize sediment composition and classify sediment types, but presentation of these percent estimates to track downcore trends in sediment composition has become less frequent over the past 2 decades. We compare semi-quantitative smear slide composition estimates to physical property (natural gamma radiation, NGR) and solid-phase geochemical (calcium carbonate, CaCO 3 %) measurements from a range of marine depositional environments in the northern Indian Ocean (Bay of Bengal, Andaman Sea, Ninetyeast Ridge) collected during International Ocean Discovery Program (IODP) Expedition 353. We show that presenting smear slide estimates as percentages, rather than abundance categories, reveals similar downcore variation in composition to the more quantitative core analyses. Overall downcore trends in total calcareous components from smear slides (foraminifers + nannofossils + shell fragments + authigenic carbonate) follow similar downcore trends to samples measured by CaCO 3 coulometry. Total lithogenic components (clay + mica + quartz + feldspars + lithic grains + vitric grains + glauconite + heavy minerals + iron oxides) and clay from smear slides track reasonably well with NGR measurements. Comparison of site averages of absolute percentages of total calcium carbonate from coulometry and total calcareous components from smear slide observations reveals an overestimation in carbonate percentages in smear slides (likely due in part to underestimation of the clay fraction), especially in sediments rich in smectite clays. Differences in sediment color between sites and settling of clay particles during slide preparation may contribute to this discrepancy. Although smear slide estimates range in accuracy depending on the training of the operator, we suggest that sedimentologists describing cores obtained during scientific drilling can use the percent estimates of sedimentary components in smear slides to identify trends and cyclicity in marine sediment records. [ABSTRACT FROM AUTHOR]

Sentinel-1 C-band synthetic aperture radar (SAR) images can be used to observe the drift of icebergs over the Southern Ocean with around 1–3 d of temporal resolution and 10–40 m of spatial resolution. The Google Earth Engine (GEE) cloud-based platform allows processing of a large quantity of Sentinel-1 images, saving time and computational resources. In this study, we process Sentinel-1 data via GEE to detect and track the drift of iceberg B43 during its lifespan of 3 years (2017–2020) in the Southern Ocean. First, to detect all candidate icebergs in Sentinel-1 images, we employ an object-based image segmentation (simple non-iterative clustering – SNIC) and a traditional backscatter threshold method. Next, we automatically choose and trace the location of the target iceberg by comparing the centroid distance histograms (CDHs) of all detected icebergs in subsequent days with the CDH of the reference target iceberg. Using this approach, we successfully track iceberg B43 from the Amundsen Sea to the Ross Sea and examine its changes in area, speed, and direction. Three periods with sudden losses of area (i.e., split-offs) coincide with periods of low sea ice concentration, warm air temperature, and high waves. This implies that these variables may be related to mechanisms causing the split-off of the iceberg. Since the iceberg is generally surrounded by compacted sea ice, its drift correlates in part with sea ice motion and wind velocity. Given that the bulk of the iceberg is under water (∼30 –60 m freeboard and ∼150 –400 m thickness), its motion is predominantly driven by the westward-flowing Antarctic Coastal Current, which dominates the circulation of the region. Considering the complexity of modeling icebergs, there is a demand for a large iceberg database to better understand the behavior of icebergs and their interactions with surrounding environments. The semi-automated iceberg tracking based on the storage capacity and computing power of GEE can be used for this purpose. [ABSTRACT FROM AUTHOR]

Following a high-end projection for mass loss from the Greenland and Antarctic ice-sheets, a freshwater forcing was applied to the ocean surface in the coupled climate model EC-Earthv2.2 to study the response to meltwater release assuming an RCP8.5 emission scenario. The meltwater forcing results in an overall freshening of the Atlantic that is dominated by advective changes, strongly enhancing the freshening due to dilution by Greenland meltwater release. The strongest circulation change occurs in the western North Atlantic subpolar gyre and in the gyre in the Nordic Seas, leaving the North Atlantic subpolar gyre the region where most advective salt export occurs. Associated with counteracting changes in both gyre systems, the response of the Atlantic Meridional Overturning Circulation is rather weak over the 190 years of the experiment; it reduces with only 1 Sv ( = 10 6 m 3 s - 1 ), compared to changes in the subpolar gyre of 5 Sv. This relative insensitivity of the AMOC to the forcing is attributed to enhanced convection in the Nordic Seas and stronger overflows that compensate reduced convection in the Labrador and Irminger Seas, and lead to higher sea surface temperatures (SSTs) in the former and lower SSTs in the latter region. The weakened subpolar gyre in the west also shifts the North Atlantic Current and the subpolar-subtropical gyre boundary; with the subtropical gyre expanding, and the western subpolar gyre contracting. The SST changes are associated with obduction of Atlantic waters in the Nordic Seas that would otherwise obduct in the western subpolar gyre. The anomalous SSTs also induce a coupled ocean-atmosphere feedback that further strengthens the Nordic Seas circulation and weakens the western subpolar gyre. This occurs because the anomalous SST-gradient enhances the westerlies, especially between 65 ∘ N and 70 ∘ N; the associated increase in windstress curl consequently enhances the gyre in the Nordic Seas. This feedback is driven by the Greenland mass loss; Antarctic meltwater discharge causes a weaker, opposite response and more particularly affects the South Atlantic salinity budget through northward advection of low-salinity waters from the Southern Ocean. This effect, however, becomes visible only hundred years after the onset of Antarctic mass loss. We conclude that the response to freshwater forcing from both ice caps can lead to a complex response in the Atlantic circulation systems with opposing effects in different subbasins. The relative strength of the response is time-dependent and largely governed by internal feedbacks; the forcing acts mainly as a trigger and is decoupled from the response. [ABSTRACT FROM AUTHOR]

This study provides a Miocene‐to‐recent history of Tasman Leakage (TL), driving surface‐to‐intermediate waters from the Pacific into the Indian Ocean. TL, in addition to Indonesian ThroughFlow (ITF), constitutes an important part of the Southern Hemisphere Supergyre. Here, we employ deep‐sea benthic δ13C timeseries from the southwestern Pacific and eastern Indian Oceans to identify the history of Tasman Leakage. The δ13C results combined with sedimentary evidence show that an inter‐ocean connection south of Australia existed from 7 Ma onward. A southward shift in Westerlies combined with a northward movement of Australia created the oceanic corridor necessary for Tasman Leakage (between Australia and the sub‐Antarctic Front) at this time. Furthermore, changes in the northern limb of the Supergyre (ITF) are evident in the sedimentary record on Broken Ridge from ∼3 to 2 Ma when Banda Sea intermediate waters started originating from the North Pacific. Plain Language Summary: Global ocean circulation allows for the distribution of heat between different latitudes and different water depths. It has long been understood that much of the return flow from the Pacific to the Atlantic occurs through the Indonesian Throughflow, but more recently, oceanographers have identified another, deeper pathway south of Australia: the Tasman Leakage. This connection consists of Pacific waters that leave the Tasman Sea by flowing southwest around Australia, into the Indian Ocean and ultimately back into the Atlantic. We use carbon isotopes of benthic foraminifera, coupled with sedimentation patterns around Australia and the Indian Ocean, to determine the onset of this new pathway in global thermohaline circulation: This occurred around 7 Ma. This onset was coincident with major global climatic and oceanographic change and was controlled by the position of the Australian continent and the sub‐Antarctic Front. TL onset was only able to occur when Australia had moved far enough north to allow for westward flow. Key Points: Benthic δ13C time‐series from the southwestern Pacific and eastern Indian Ocean suggest onset of Tasman Leakage at 7 MaLatitudinal movement of the Australian continent away from the sub‐Antarctic Front creates the oceanic corridor necessary for Tasman LeakageThe Late Miocene onset of Tasman Leakage completed the Southern Hemisphere Supergyre and ushered in the near‐modern ocean circulation style [ABSTRACT FROM AUTHOR]

In this study, we interpret the role played by ocean circulation in sediment distribution on the southwestern Atlantic margin using radiogenic Nd and Pb isotopes. The latitudinal trends for Pb and Nd isotopes reflect the different current systems acting on the margin. The utilization of the sediment fingerprinting method allowed us to associate the isotopic signatures with the main oceanographic features in the area. We recognized differences between Nd and Pb sources to the Argentinean shelf (carried by the flow of Subantarctic Shelf Water) and slopes (transported by deeper flows). Sediments from Antarctica extend up to the Uruguayan margin, carried by the Upper and Lower Circumpolar Deep Water. Our data confirm that, for shelf and intermediate areas (the upper 1200 m), the transfer of sediments from the Argentinean margin to the north of 35 ∘ S is limited by the Subtropical Shelf Front and the basin-wide recirculated Antarctic Intermediate Water. On the southern Brazilian inner and middle shelf, it is possible to recognize the northward influence of the Río de la Plata sediments carried by the Plata Plume Water. Another flow responsible for sediment transport and deposition on the outer shelf and slope is the southward flow of the Brazil Current. Finally, we propose that the Brazil–Malvinas Confluence and the Santos Bifurcation act as boundaries of geochemical provinces in the area. A conceptual model of sediment sources and transport is provided for the southwestern Atlantic margin. [ABSTRACT FROM AUTHOR]

The exchange of water masses between the Indian Ocean and the Atlantic constitutes an integral interocean link in the global thermohaline circulation. Long‐term changes in deep water flow have been studied using seismic reflection profiles but the seismic stratigraphy was poorly constrained and not resolved for the time period from the late Miocene onward. Here we present results from International Ocean Discovery Program Site U1475 (Agulhas Plateau) located over a sediment drift proximal to the entrance of North Atlantic Deep Water into the Southern Ocean and South Indian Ocean. Site U1475 comprises a complete carbonate‐rich stratigraphic section of the last ~7 Ma that provides an archive of climate‐induced variations in ocean circulation. Six marker reflectors occurring in the upper 300 m of the drift are identified here for the first time. The formation of these reflectors is mainly due to density changes that are mostly caused by changes in biogenic versus terrigenous sediment deposition. Synthetic seismograms allow age assignments for the horizons based on biostratigraphy and magnetostratigraphy. Prominent reflectors are related to late Pleistocene glacial/interglacial variability, the middle and early Pleistocene transitions, and the onset of the northern hemisphere glaciation. A peculiar early Pliocene interval (~5.3–4.0 Ma) bounded by two reflectors is characterized by fourfold elevated sedimentation rates (>10 cm/kyr) and the occurrence of sediment waves. We argue that this enhanced sediment transport to the Agulhas Plateau was caused by a reorganization of the bottom current circulation pattern due to maximized inflow of North Atlantic Deep Water. Key Points: A new seismic stratigraphy has been derived for the late Miocene to Pleistocene at the Agulhas Plateau (IODP Site U1475)Reflectors are associated with the onset of the northern hemisphere glaciation, the middle Pleistocene transition, and the late Pleistocene climate variabilityA major reorganization of the bottom current circulation pattern at ~5.3 Ma is likely due to maximized inflow of North Atlantic Deep Water [ABSTRACT FROM AUTHOR]

The hydrochemistry of meltwater from the Sutri Dhaka Glacier, Western Himalaya, has been studied to understand the influence of the factors controlling the weathering processes of the glaciers during the peak ablation period. The high solar irradiance prompted intense melting, which has raised the stream flow of the glacier. The meltwater has been observed as slightly alkaline (mean pH 8.2) and contains the major anions (HCO > SO > NO > Cl) and cations (Ca > Mg > K > Na > NH ) with Ca (78.5%) and HCO (74.5%) as the dominant species. The piper diagram indicates the category of stream meltwater as Ca-HCO type. In addition, it is evident from the Gibbs diagram that the interaction between the meltwater and bedrock controls the ionic concentrations of the glacial meltwater. The high ratio value (~ 0.75) of HCO /(HCO + SO ) indicates that the carbonate weathering is dominant. Fe and Al followed by Mn, Sr, and Ti are the most dominant trace elements present in the meltwater. The significant negative correlation exhibited by the major ions and Sr with the discharge is recommended for the enrichment of these solutes during the lean discharge periods. However, the insignificant correlation of Fe, Al, Mn, and Ti with discharge suggests their physicochemical control. The principal component analysis (PCA) carried has highlighted three dominant composites, i.e., the water-rock interaction, atmospheric dust inputs, and physicochemical changes in the meltwater. Hence, the present study elucidates the export of geochemical solutes from Sutri Dhaka Glacier and factors governing the water chemistry, which helps in the better understanding of hydrochemical processes of the Himalayan glaciers and substantial improvement of our understanding about the glacio-hydrological environments and their response in the scenario of global warming. [ABSTRACT FROM AUTHOR]

This study aimed to respond to the national "carbon peak" mid-and long-term policy plan, comprehensively promote energy conservation and emission reduction, and accurately manage and predict carbon emissions. Firstly, the proposed method analyzes the Yangtze River Economic Belt as well as its "carbon peak" and carbon emissions. Secondly, a support vector regression (SVR) machine prediction model is proposed for the carbon emission information prediction of the Yangtze River Economic Zone. This experiment uses a long short-term memory neural network (LSTM) to train the model and realize the experiment's prediction of carbon emissions. Finally, this study obtained the fitting results of the prediction model and the training model, as well as the prediction results of the prediction model. Information indicators such as the scale of industry investment, labor efficiency output, and carbon emission intensity that affect carbon emissions in the "Yangtze River Economic Belt" basin can be used to accurately predict the carbon emissions information under this model. Therefore, the experiment shows that the SVR model for solving complex nonlinear problems can achieve a relatively excellent prediction effect under the training of LSTM. The deep learning model adopted herein realized the accurate prediction of carbon emission information in the Yangtze River Economic Zone and expanded the application space of deep learning. It provides a reference for the model in related fields of carbon emission information prediction, which has certain reference significance. [ABSTRACT FROM AUTHOR]

A study on seasonal phytoplankton abundance and composition in a mangrove estuary, Matang Mangrove Forest Reserve (MMFR), Malaysia, was carried out to determine the phytoplankton structure in this ecosystem, and to identify potential indicators of environmental changes. Phytoplankton samples were collected bimonthly from June 2010 to April 2011, to cover both dry (June to October) and wet (November to April) seasons, at four selected sampling sites along the river. Diatoms showed the highest number of species (50 species) from a total of 85 phytoplankton species from 76 genera. Diatoms contributed more than 90% of the total phytoplankton abundance during the dry season (southwest monsoon) and less than 70% during the wet season (northeast monsoon) as dinoflagellates became more abundant during the rainy season. Two diatoms were recorded as dominant species throughout the sampling period; Cyclotella sp. and Skeletonema costatum. Cyclotella sp. formed the most abundant species (62% of total phytoplankton) during the dry period characterized by low nutrients and relatively low turbidity. Skeletonema costatum contributed 93% of the total phytoplankton in October, which marked the end of the dry season and the beginning of the wet season, characterized by strong winds and high waves leading to the upwelling of the water column. Massive blooms of Skeletonema costatum occurred during the upwelling when total nitrogen (TN) and total phosphorus (TP) concentrations were highest (p < 0.05) throughout the year. The abundance of diatom species during the wet season was more evenly distributed, with most diatom species contributing less than 12% of the total phytoplankton. Autotrophic producers such as diatoms were limited by high turbidity during the northeast monsoon when the rainfall was high. During the wet season, Cyclotella and Skeletonema costatum only contributed 9% and 5% of the total phytoplankton, respectively, as dinoflagellates had more competitive advantage in turbid waters. This study illustrates that some diatom species such as Cyclotella sp. and Skeletonema costatum could be used as indicators of the environmental changes in marine waters. [ABSTRACT FROM AUTHOR]

The geochemical and mineralogical characteristics of pelagic sediments collected from the Interoceanmetal Joint Organization (IOM) claim area, located in the eastern part of the Clarion-Clipperton Fracture Zone (CCFZ; eastern tropical Pacific), are described in this paper. The concentrations of rare earth elements (REE), as well as other selected critical elements contained in 135 sediment samples of siliceous clayey silts, are presented. The vertical and spatial variabilities of elements, with particular emphasis on REE as well as metals of the highest economic interest such as Cu, Ni, and Co, are detailed. The applied methods include grain size analysis by laser diffraction, geochemistry examination using ICP-MS, XRF, AAS, and CNS spectrometry, and XRD analysis of mineral composition (Rietveld method). Additionally, statistical methods such as factor analysis (FA) and principal components analysis (PCA) were applied to the results. Finally, a series of maps was prepared by geostatistical methods (universal kriging). Grain size analysis showed poor sorting of the examined fine-grained silts. ICP-MS indicated that total REE contents varied from 200 to 577 ppm, with a mean of 285 ppm, which is generally low. The contents of critical metals such as Cu, Ni, and Co were also low to moderate, apart from some individual sampling stations where total contents were 0.15% or more. Metal composition in sediments was dominated by Cu, Ni, and Zn. A mineral composition analysis revealed the dominance of amorphous biogenic opaline silica (27–58%), which were mostly remnants of diatoms, radiolarians, and sponges associated with clay minerals (23% to 48%), mostly Fe-smectite and illite, with mixed-layered illite/smectite. The high abundance of diagenetic barite crystals found in SEM−EDX observations explains the high content of Ba (up to 2.4%). The sediments showed complex lateral and horizontal fractionation trends for REE and critical metals, caused mostly by clay components, early diagenetic processes, admixtures of allogenic detrital minerals, or scavenging by micronodules. [ABSTRACT FROM AUTHOR]