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Abstract Mars' dayside ionosphere is maintained primarily by ionization from solar ultraviolet photons and subsequent chemical reactions, with small contributions from other mechanisms such as impact ionization and charge exchange. In December 2023, the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission observed the impact of an interplanetary coronal mass ejection (ICME) on Mars' ionosphere, including strongly enhanced fluxes of suprathermal electrons. We show that this enhancement in suprathermal electron fluxes increased ion production from electron impact, so that dayside electron impact ionization rates exceeded photoionization rates during the ICME. This change in ion production mechanisms led to unusually high densities of the minor ions C+ and O++. Space weather events are known to increase ion escape rates, so changes in ion composition during space weather events have important implications for atmospheric evolution. We show that scaling nominal loss rates to account for space weather may underestimate carbon loss from Mars' atmosphere.

In this series of papers, we present statistical maps of mirror-mode-like (MM) structures in the magnetosheaths of Mars and Venus and calculate the probability of detecting them in spacecraft data. We aim to study and compare them with the same tools and a similar payload at both planets. We consider their dependence on extreme ultraviolet (EUV) solar flux levels (high and low) and, specific to Mars, on Mars Year (MY) as well as atmospheric seasons (four solar longitudes Ls). We first use magnetic-field-only criteria to detect these structures and present ways to mitigate ambiguities in their nature. In line with many previous studies at Earth, this technique has the advantage of using one instrument (a magnetometer) with good time resolution, facilitating comparisons between planetary and cometary environments. Applied to the magnetometer data of the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft from November 2014 to February 2021 (MY32–MY35), we detect events closely resembling MMs lasting in total more than 170 000 s, corresponding to about 0.1 % of MAVEN's total time spent in the Martian plasma environment. We calculate MM-like occurrences normalised to the spacecraft's residence time during the course of the mission. Detection probabilities are about 1 % at most for any given controlling parameter. In general, MM-like structures appear in two main regions: one behind the shock and the other close to the induced magnetospheric boundary, as expected from theory. Detection probabilities are higher on average in low-solar-EUV conditions, whereas high-solar-EUV conditions see an increase in detections within the magnetospheric tail. We tentatively link the former tendency to two combining effects: the favouring of ion cyclotron waves the closer to perihelion due to plasma beta effects and, possibly, the non-gyrotropy of pickup ion distributions. This study is the first of two on the magnetosheaths of Mars and Venus.

Solar wind protons can interact directly with the hydrogen corona of Mars through charge exchange, resulting in energetic neutral atoms (ENAs) able to penetrate deep into the upper atmosphere of Mars. ENAs can undergo multiple charge changing interactions, leading to an observable beam of penetrating protons in the upper atmosphere. We seek to characterize the behavior of these protons in the presence of magnetic fields using data collected by the Mars Atmosphere and Volatile EvolutioN spacecraft. We find that backscattered penetrating proton flux is enhanced in regions where the magnetic field strength is greater than 200 nT. We also find a strong correlation at CO 2 column densities less than 5.5 × 10 14  cm -2 between magnetic field strength and the observed backscattered and downward flux. We do not see significant changes in penetrating proton flux with magnetic field strengths on the order of 10 nT., (© 2022. The Authors.)

We present an in-depth analysis of a time interval when quasi-linear mirror mode structures were detected by magnetic field and plasma measurements as observed by the NASA/Mars Atmosphere and Volatile EvolutioN spacecraft. We employ ion and electron spectrometers in tandem to support the magnetic field measurements and confirm that the signatures are indeed mirror modes. Wedged against the magnetic pile-up boundary, the low-frequency signatures last on average ∼ 10  s with corresponding sizes of the order of 15-30 upstream solar wind proton thermal gyroradii, or 10-20 proton gyroradii in the immediate wake of the quasi-perpendicular bow shock. Their peak-to-peak amplitudes are of the order of 30-35 nT with respect to the background field, and appear as a mixture of dips and peaks, suggesting that they may have been at different stages in their evolution. Situated in a marginally stable plasma with β ‖  ∼ 1, we hypothesize that these so-called magnetic bottles, containing a relatively higher energy and denser ion population with respect to the background plasma, are formed upstream of the spacecraft behind the quasi-perpendicular shock. These signatures are very reminiscent of magnetic bottles found at other unmagnetized objects such as Venus and comets, also interpreted as mirror modes. Our case study constitutes the first unmistakable identification and characterization of mirror modes at Mars from the joint points of view of magnetic field, electron and ion measurements. Up until now, the lack of high-temporal resolution plasma measurements has prevented such an in-depth study., (©2021. The Authors.)

Coupling between the lower and upper atmosphere, combined with loss of gas from the upper atmosphere to space, likely contributed to the thin, cold, dry atmosphere of modern Mars. To help understand ongoing ion loss to space, the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft made comprehensive measurements of the Mars upper atmosphere, ionosphere, and interactions with the Sun and solar wind during an interplanetary coronal mass ejection impact in March 2015. Responses include changes in the bow shock and magnetosheath, formation of widespread diffuse aurora, and enhancement of pick-up ions. Observations and models both show an enhancement in escape rate of ions to space during the event. Ion loss during solar events early in Mars history may have been a major contributor to the long-term evolution of the Mars atmosphere., (Copyright © 2015, American Association for the Advancement of Science.)

The Mars Atmosphere and Volatile Evolution (MAVEN) mission, during the second of its Deep Dip campaigns, made comprehensive measurements of martian thermosphere and ionosphere composition, structure, and variability at altitudes down to ~130 kilometers in the subsolar region. This altitude range contains the diffusively separated upper atmosphere just above the well-mixed atmosphere, the layer of peak extreme ultraviolet heating and primary reservoir for atmospheric escape. In situ measurements of the upper atmosphere reveal previously unmeasured populations of neutral and charged particles, the homopause altitude at approximately 130 kilometers, and an unexpected level of variability both on an orbit-to-orbit basis and within individual orbits. These observations help constrain volatile escape processes controlled by thermosphere and ionosphere structure and variability., (Copyright © 2015, American Association for the Advancement of Science.)