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We present chemical kinetics measurements of the luminol oxydation chemiluminescence reaction at the interface between two aqueous solutions, using liquid jet technology. Free-flowing iquid microjets are a relatively recent development that has found its way into a growing number of applications in spectroscopy and dynamics. A variant thereof, called flat-jet, is obtained when two cylindrical jets of a liquid are crossed, leading to a chain of planar leaf-shaped structures of the flowing liquid. We here show that in the first leaf of this chain the fluids do not exhibit turbulent mixing, providing a clean interface between the liquids from the impinging jets. We also show, using the example of the luminol chemiluminescence reaction, how this setup can be used to obtain kinetics information from friction-less flow and by circumventing the requirement for rapid mixing but by intentionally suppressing all turbulent mixing and instead relying on diffusion.

Review of scientific instruments 93(1), 015101 (2022). doi:10.1063/5.0072346, We present a unique experimental design that enables the measurement of photoelectron circular dichroism (PECD) from chiral molecules in aqueous solution. The effect is revealed from the intensity difference of photoelectron emission into a backward-scattering angle relative to the photon propagation direction when ionizing with circularly polarized light of different helicity. This leads to asymmetries (normalized intensity differences) that depend on the handedness of the chiral sample and exceed the ones in conventional dichroic mechanisms by orders of magnitude. The asymmetry is largest for photon energies within several electron volts above the ionization threshold. A primary aim is to explore the effect of hydration on PECD. The modular and flexible design of our experimental setup EASI (Electronic structure from Aqueous Solutions and Interfaces) also allows for detection of more common photoelectron angular distributions, requiring distinctively different detection geometries and typically using linearly polarized light. A microjet is used for liquid-sample delivery. We describe EASI���s technical features and present two selected experimental results, one based on synchrotron-light measurements and the other performed in the laboratory, using monochromatized He-II �� radiation. The former demonstrates the principal effectiveness of PECD detection, illustrated for prototypic gas-phase fenchone. We also discuss the first data from liquid fenchone. In the second example, we present valence photoelectron spectra from liquid water and NaI aqueous solution, here obtained from a planar-surface microjet (flatjet). This new development features a more favorable symmetry for angle-dependent photoelectron measurements., Published by American Institute of Physics, [S.l.]

A novel traveling-wave Zeeman decelerator based on a double-helix coil geometry capable of decelerating paramagnetic molecules with high efficiency is presented. Moving magnetic traps are generated by applying time-dependent currents through the decelerator coils. Paramagnetic molecules in low-field-seeking Zeeman states are confined inside the moving traps which are decelerated to lower forward velocities. As a prototypical example, we demonstrate the deceleration of OH radicals from an initial velocity of 445 m s-1 down to various final velocities. The experimental results are analyzed and numerically reproduced with the help of trajectory simulations confirming the phase-space stability and efficiency of the deceleration of the molecules in the new device.

Focusing of molecular beams using an electrostatic hexapole is a mature technique to produce samples of state-selected molecules. The ability to efficiently focus molecules depends on the properties of the molecular species of interest, the length of the hexapole state selector, as well as on the maximum electric field strength that can be achieved in these devices. In particular for species with a small effective dipole moment such as nitric oxide (NO), hexapole state selectors of several meters in length are required to focus the beam. We report on a novel design for an electrostatic hexapole state-selector that allows for a maximum electric field strength of 260 kV/cm, reducing significantly the length of the hexapole that is required to focus the beam. We demonstrate the focusing of a molecular beam of NO radicals (X 2Π1/2, v = 0, J = 1/2, f) using a hexapole of only 30 cm length. A beamstop is integrated inside the hexapole at the geometric center of the device where the molecular trajectories have the largest deviation from the beam axis, effectively blocking the carrier gas of the molecular beam at minimum loss of NO density. The performance of the hexapole state-selector is investigated by state-selective laser induced fluorescence detection, as well as by two-dimensional imaging of the focused packet of NO radicals. The resulting packet of NO radicals has a density of 9 ± 3 × 1010 cm-3 and a state purity of 99%

Focusing optics for neutral molecules finds application in shaping and steering molecular beams. Here we present an electrostatic elliptical mirror for polar molecules consisting of an array of microstructured gold electrodes deposited on a glass substrate. Alternating positive and negative voltages applied to the electrodes create a repulsive potential for molecules in low-field-seeking states. The equipotential lines are parallel to the substrate surface, which is bent in an elliptical shape. The mirror is characterized by focusing a beam of metastable CO molecules and the results are compared to the outcome of trajectory simulations., Comment: 5 pages, 4 figures

We have designed and implemented a new Stark decelerator based on wire electrodes, which is suitable for ultrahigh vacuum applications. The 100 deceleration stages are fashioned out of 0.6 mm diameter tantalum and the array's total length is 110 mm, approximately 10 times smaller than a conventional Stark decelerator with the same number of electrode pairs. Using the wire decelerator, we have removed more than 90% of the kinetic energy from metastable CO molecules in a beam., updated version, added journal reference