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Nano-TiO2 was prepared with butyl titanate as a precursor by sol-gel method. The samples were analysed by TG-DTA, X-ray diffraction, TEM and so on to assess the effects of different temperatures on the crystal structure, grain size, and microstructure of nano-TiO2. Meanwhile, the catalytic effect of heat treatment temperature on the degradation performance of TiO2 to methyl orange was investigated. The dynamic process of grain growth was preliminarily analysed by Eastman’s particle growth theory. The result shows that TiO2 particle size gradually increases with the heat treatment temperature. At 450 to 550°C, the grain is mainly anatase phase, a mixture of anatase and rutile phase was found at 650°C (mass ratio A:R = 9:1), and the degradation rate of nano-TiO2 on methyl orange reaches 97.75%. When the calcination temperature exceeds 850°C, TiO2 particles almost entirely are composed of rutile phase, and the photocatalytic activity decreases significantly. At 730°C, half of the crystalline TiO2 is transformed from anatase to rutile form. The apparent activation energies of the anatase and rutile crystals of nano-TiO2 are 18.15 kJ/mol and 42.56 kJ/mol, and the fastest grain growth occurs at 546°C and 1280°C respectively.

BACKGROUND: To analyze the clinical data and next generation sequencing (NGS) results from a child with 22q11.2 deletion syndrome (22q11DS) complicated with pulmonary alveolar proteinosis (PAP) who was admitted to the Department of Pediatrics of Fuyang People's Hospital and to present a review of the literature. CASE PRESENTATION: A 9-year-old male child, whose face had a small mandible and higharched palate, but lacked a cleft palate, had repeated respiratory tract infections and bronchiectasis. Clinical examination, computer tomography, and electronic bronchoscopy were performed. Genetic testing via NGS was undertaken. PAP was confirmed by Periodic Acid Schiff staining of milky white alveolar lavage fluid isolated by electronic bronchoscopy. A deletion of approximately 2.46 Mbp on chromosome 22q11.2 was confirmed by NGS. During hospitalization, anti-infection, nebulization, alveolar lavage, and regular application of thymosin were administered to the patient. The condition of the patient stabilized following treatment. CONCLUSIONS: 22q11DS and PAP are both rare diseases, and the manifestation of 22q11DS combined with PAP has not been previously reported. The diagnosis and treatment of this case will be a reference for future clinical work. [ABSTRACT FROM AUTHOR]

In this paper, a pot experiment was conducted to simulate different degrees of saline-alkali stress to explore the response mechanism of Pennisetum giganteum Z. X. Lin to salt stress concerning its growth and physiological characteristics. The results showed that: (1) the growth of plant height decreased obviously with the increase of salt solution concentration; (2) with the increase of concentration, MDA content accumulated intermittently, P. giganteum reduced oxidative damage and maintained normal plant physiological metabolism through the complementary action of antioxidant enzymes SOD and CAT; (3) when the concentration of mixed salt solution was low, all osmotic regulatory substances accumulated slowly, and with the continuous increase of concentration, free proline content increased rapidly, which played a leading role in the process of plant osmotic regulation to ensure its physiological activities; (4) under mixed saline-alkali stress, the roots and stems of P. giganteum absorbed most of the Na+ , and transported K+ to the leaves at the same time. [ABSTRACT FROM AUTHOR]