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Photocatalytically active heterojunctions based on metal halide perovskites (MHPs) are drawing significant interest for their chameleon ability to foster several redox reactions. The lack of mechanistic insights into their performance, however, limits the ability of engineering novel and optimized materials. Herein, a report is made on a composite system including a double perovskite, Cs2AgBiCl6/g‐C3N4, used in parallel for solar‐driven hydrogen generation and nitrogen reduction, quantified by a rigorous analytical approach. The composite efficiently promotes the two reactions, but its activity strongly depends on the perovskite/carbon nitride relative amounts. Through advanced spectroscopic investigation and density function theory (DFT) modeling the H2 and NH3 production reaction mechanisms are studied, finding perovskite halide vacancies as the primary reactive sites for hydrogen generation together with a positive contribution of low loaded g‐C3N4 in reducing carrier recombination. For nitrogen reduction, instead, the active sites are g‐C3N4 nitrogen vacancies, and the heterojunction best performs at low perovskites loadings where the composites maximize light absorption and reduce carrier losses. It is believed that these insights are important add‐ons toward universal exploitation of MHPs in contemporary photocatalysis.

We report here a novel series of halide alloyed Ge-containing 2D perovskites including decylammonium as organic spacer, namely DA2Ge(Br1−xIx)4. This system forms a continuous solid solution on the halide site with a modulation of the bandgap from 2.74 to 2.17 eV with a rapid decrease up to x = 0.5 followed by a plateau. Iodide-rich compositions show enhanced broad room temperature (RT) photoluminescence (PL) that narrows at low temperature with maximum quantum yields for mixed compositions. The replacement of Ge with Pb and Sn in DA2GeBr4 and DA2GeI4 provides a tuning of the bandgap in the whole visible spectrum with a marked blue-shift when lead is present and, opposite, a red-shift for Sn replacement. The RT PL progressively broadens moving from Pb to Sn and to Ge covering an emission range from 400 to 800 nm. Finally, the air stability of lead-free 2D perovskites of this work has been determined indicating its improvement by increasing the hardness of the halide.

Metal halide perovskites (MHPs), in particular lead-based perovskites, have earned recognized fame in several fields for their outstanding optoelectronic properties, including direct generation of free charge carriers, optimal ambipolar charge carrier transport properties, high absorption coefficient, point-defect tolerance, and compositional versatility. Nowadays, this class of materials represents a real and promising alternative to silicon for photovoltaic technologies. This worthy success led to a growing interest in the exploration of MHPs in other hot research fields, such as solar-driven photocatalytic water splitting towards hydrogen production. Nevertheless, many of these perovskites show air and moisture instability problems that considerably hinder their practical application for photocatalytic water splitting. Moreover, if chemical instability is a problem that can be in part mitigated by the optimization of the chemical composition and crystal structure, the presence of lead represents a real problem for the practical application of MHPs in commercial devices due to environmental and healthcare issues. To successfully overcome these problems, lead-free metal halide perovskites (LFMHPs) have gained increasing interest thanks to their optoelectronic properties, comparable to lead-based materials, and their more eco-friendly nature. Among all the lead-free perovskite alternatives, this mini-review considers bismuth-based perovskites and perovskite derivatives with a specific focus on solar-driven photocatalysis application for H2 evolution. Special attention is dedicated to the structure and composition of the different materials and to the advantage of heterojunction engineering and the relative impact on the photocatalytic process.

A forecasting and hazard assessment system for oil dispersion from Italian oil rigs was set up within the framework of a national research project. The system is based on 3D hydrodynamic, mesoscale resolving models providing forcing fields for a Lagrangian module of oil dispersion and slick evolution (oil transport and transformation). The tool provides,daily, the outputs of numerical simulations of possible oil spills from extraction platform sites. In this work we present the results for the 3 platforms closest to the Italian coast. Aside the operational usage, the numerical outputs are also stored and adopted to compute statistics of the slick distributions in the coastal and marine areas of interest. The hazard was assessed by means of two different indices (Hazard Index and Occurrence Index) based on the operational system outputs, for the estimation of the hazard at sea (marine hazard or aerial hazard). As short forecasts (2 days long) often do not allow the oil to reach the coast, an extra set of long-period simulations has been performed in order to compute a third Hazard Index (Coastal Hazard Index) suitable to estimate the hazard along the shorelines. The adopted methodology allowed, as a whole, to assess both coastal and marine oil spill hazard due to oil spill extraction activities. The indices constitute a basic informative layer on which the environmental risk could be also evaluated, once opportunely combined with coastal vulnerability and sensitivity layers.

Oil extraction platforms are potential sources of oil spills. For this reason, an oil spill forecasting system was set up to support the management of emergencies from the oil fields in the Italian seas. The system provides ready-to-use products to the relevant response agencies and optimizes the anti-pollution resources by assessing hazards and risks related to this issue. The forecasting system covers seven working oil platforms in the Sicily Channel and middle/low Adriatic Sea. It is composed of a numerical chain involving nested ocean models from regional to coastal spatial scales and an oil spill model. The system provides two online services, one automatic and a second dedicated to possible real emergencies or exercises on risk preparedness and responding. The automatic service produces daily short-term simulations of hypothetical oil spill dispersion, transport, and weathering processes from each extraction platform. Products, i.e., risk maps, animations, and a properly called bulletin, are available on a dedicated web-portal. The hazard estimations are computed by performing geo-statistical analysis on the daily forecasts database. The second service is activated in near-real-time producing oil spill simulations for the following 48 h.