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Coral‐based stable oxygen isotopes (δ18O) have been used as a proxy for sea surface temperature (SST) since the 1970s, and δ18O–SST calibration studies have been fundamental to assure robust and faithful SST reconstructions. Paleoclimatic studies based on corals from the tropical western South Atlantic (TWSA) are scarce, and the available coral species need to be calibrated to improve climate and environmental reconstructions. Siderastrea stellata, a slow‐growing coral, is a potential species to be explored as a coral archive in the TWSA. We provide the first multi‐site δ18O–SST calibration for the coral S. stellata from three locations at the TWSA: Todos os Santos Bay, Tamandaré and the Rocas Atoll. Pseudo‐coral δ18O calculations derived from gridded SSS and SST show that the contributions of SSS and SST to coral δ18O are expected to be different at each site. Weighted least squares linear regressions performed between the δ18O and SST generated the following calibrations equations: δ18O = −0.18 (±0.02) × SST (°C) + 1.90 (±0.47) for Todos os Santos Bay; δ18O = −0.18 (±0.02) × SST (°C) + 1.54 (±0.67) for Tamandaré; and δ18O = −0.16 (±0.03) × SST (°C) + 1.24 (±0.71) for the Rocas Atoll. The δ18O‐SST sensitivity of S. stellata from the TWSA is similar to that of other slow‐growing species of the genus and consistent with the expected δ18O‐SST sensitivity of other species reported in the literature. These calibrations will allow future SST reconstructions based on δ18O records from sub‐fossil and fossil S. stellata, an abundant species in the TWSA. Plain Language Summary: Corals continuously biomineralize calcium carbonate, storing environmental information within their exoskeletons in geochemical and isotopic records that span hundreds of years and making them suitable for high‐resolution climate reconstructions. The stable oxygen isotopes (δ18O) found in corals are an important proxy for revealing past sea surface temperatures (SST) and sea surface salinities (SSS). However, to ensure that this proxy is applicable to reconstruct past SST, further δ18O–SST calibration studies are needed on various regions and species. In this study, we carried out three field work experiments to provide the first multi‐site δ18O–SST calibration of the slow‐growing coral Siderastrea stellata from the western South Atlantic. Despite the slow growth nature of S. stellata corals that poses a challenge to high temporal resolution sampling, we successfully provided new calibration equations for SST reconstruction from three different locations in the western South Atlantic. Our calibration equations can now be applied to reconstruct SST based on coral δ18O records from sub‐fossil and fossil coral cores. Key Points: First multi‐site δ18O‐SST calibrations for the slow‐growing coral Siderastrea stellata from the western South Atlanticδ18O–SST sensitivity for S. stellata varied from −0.15 to −0.19‰ per °C across the different reef environmentsThis study paves the way for using S. stellata δ18O from fossil and subfossil corals for paleoclimate reconstructions from the western South Atlantic [ABSTRACT FROM AUTHOR]

The stable carbon isotope composition (δ13C) of plant components such as plant wax biomarkers is an important tool for reconstructing past vegetation. Plant wax δ13C is mainly controlled by photosynthetic pathways, allowing for the differentiation of C4 tropical grasses and C3 forests. Proxy interpretations are however complicated by additional factors such as aridity, vegetation density, elevation, and the considerable δ13C variability found among C3 plant species. Moreover, studies on plant wax δ13C in tropical soils and plants have focused on Africa, while structurally different South American savannas, shrublands and rainforests remain understudied. Here, we analyze the δ13C composition of long-chain n-alkanes and fatty acids from tropical South American soils and leaf litter to assess the isotopic variability in each vegetation type and to investigate the influence of climatic features on δ13C. Rainforests and open vegetation types show distinct values, with rainforests having a narrow range of low δ13C values (n-C29 alkane: -34.4+-0.7+0.9 ‰ (Q2575); Suess-effect corrected). This allows for the detection of even minor incursions of savanna (δ13C n-C29 alkane -29.2-2.1+3.7 ‰) into rainforests. While Cerrado savannas and semi-arid Caatinga shrublands grow under distinctly different climates, they can yield indistinct δ13C values for most compounds. Cerrado soils and litter show pronounced isotopic spreads between the n-C33 and n-C29 alkanes, while Caatinga shrublands show consistent values across the two homologs, thereby enabling the differentiation of these vegetation types. The same multihomolog isotope analysis can be extended to differentiate African shrublands from savannas. [ABSTRACT FROM AUTHOR]

The reconstruction of accurate sea‐surface temperatures (SST) is of utmost importance due to the ocean's central role in the global climate system. Yet, a number of environmental processes might bias reliable SST estimations. Here, we investigate the fidelity of SST reconstructions for the western tropical South Atlantic (WTSA) for the interval covered by Marine Isotope Stages (MIS) 6–5, utilizing a core collected off eastern Brazil at ∼20°S. This interval was selected as previous SST estimates based on Mg/Ca ratios of planktic foraminifera suggested a peculiar pooling of warm surface waters in the WTSA during MIS 6 despite glacial boundary conditions. To ground‐truth the Mg/Ca‐based SST data we generated SST reconstructions on the same core material using the alkenone and TEX86 paleothermometers. Comparison with alkenone‐based temperature estimates corroborate the previous Mg/Ca‐based SST reconstructions, supporting the suggestion of a warm‐water anomaly during MIS 6. In contrast, TEX86‐derived temperatures, albeit representing annual mean SST in recent core top samples, are up to 6°C colder than Mg/Ca‐ and alkenone‐based SST reconstructions. We interpret the periods of anomalously cold TEX86‐temperatures as a result of a vertical migration of the TEX86 producers (heterotrophic marine Thaumarchaeota) toward greater water depths, following food availability during phases of enhanced fluvial suspension input. Likewise, the data suggest that alkenone‐based SST are, albeit to a minor degree when compared to TEX86, affected by river run‐off and/or a seasonal bias in the growth season of haptophyte algae. Plain Language Summary: In this study, we investigate the accuracy of sea‐surface temperature (SST) reconstructions for the western tropical South Atlantic (WTSA) for the interval covered by Marine Isotope Stages (MIS) 6–5—the penultimate glacial‐interglacial cycle (ca. 190,000 to 70,00 years before present). This time interval was selected because previous SST estimates based on Mg/Ca ratios of planktic foraminifera suggested a pooling of warm surface waters in the WTSA during late MIS 6 despite the cold glacial conditions. To verify the Mg/Ca‐based SST data, we generated temperature reconstructions from a core located off Eastern Brazil using two common paleothermometers that based on lipid biomarkers: alkenone and TEX86. The alkenone‐based temperature estimates agree with previous Mg/Ca‐based SST reconstructions, supporting the existence of a warm‐water anomaly in the WTSA during MIS 6. On the other hand, TEX86‐derived temperatures were up to 6°C colder than Mg/Ca‐ and alkenone‐based SST reconstructions. This discrepancy might be a result of a vertical migration of the TEX86 producers toward greater water depths where they feed on particles of organic matter. These migrations into deeper waters occurred during phases of increased river run‐off fluvial suspension input which enhanced surface primary productivity and facilitated vertical particle flux through the water column. Key Points: Parallel Mg/Ca (Globigerinoides ruber), alkenone and TEX86‐based temperature estimates in the western tropical South Atlantic (WTSA) across Marine Isotope Stages (MIS) 6–5Mg/Ca and alkenones represent annual mean sea surface temperatures, but most TEX86‐based temperatures deviate to colder valuesAnomalous sea surface warming in the WTSA during late MIS 6 appears as a robust signal [ABSTRACT FROM AUTHOR]

Particulate pyrogenic carbon (PyC) transported by rivers and aerosols, and deposited in marine sediments, is an important part of the carbon cycle. The chemical composition of PyC is temperature dependent and levoglucosan is a source‐specific burning marker used to trace low‐temperature PyC. Levoglucosan associated to particulate material has been shown to be preserved during riverine transport and marine deposition in high‐ and mid‐latitudes, but it is yet unknown if this is also the case for (sub)tropical areas, where 90% of global PyC is produced. Here, we investigate transport and deposition of levoglucosan in suspended and riverbed sediments from the Amazon River system and adjacent marine deposition areas. We show that the Amazon River exports negligible amounts of levoglucosan and that concentrations in sediments from the main Amazon tributaries are not related to long‐term mean catchment‐wide fire activity. Levoglucosan concentrations in marine sediments offshore the Amazon Estuary are positively correlated to total organic content regardless of terrestrial or marine origin, supporting the notion that association of suspended or dissolved PyC to biogenic particles is critical in the preservation of PyC. We estimate that 0.5–10 × 106 g yr−1 of levoglucosan is exported by the Amazon River. This represents only 0.5–10 ppm of the total exported PyC and thereby an insignificant fraction, indicating that riverine derived levoglucosan and low‐temperature PyC in the tropics are almost completely degraded before deposition. Hence, we suggest caution in using levoglucosan as tracer for past fire activity in tropical settings near rivers. Plain Language Summary: During plant organic matter burning, most of the carbon is emitted to the atmosphere as CO2, but a fraction is retained as pyrogenic biomass. The chemical composition of pyrogenic biomass depends on fire temperature and allows to differentiate between high and low‐temperature pyrogenic biomass. Here, we analyzed if low‐temperature pyrogenic biomass is preserved during transport in the Amazon River and deposited in western tropical Atlantic sediments. We found that only negligible amounts of low‐temperature pyrogenic biomass reach the Atlantic through riverine transport. While most pyrogenic carbon (PyC) originates in the tropics, our study suggests that only an insignificant fraction of low‐temperature PyC is permanently stored in marine sediments, where it would be removed from the short‐term carbon cycle. Key Points: Only negligible amounts of the source‐specific low‐temperature biomass burning tracer levoglucosan are exported by the Amazon River systemMarine sediment levoglucosan yields are controlled by organic carbon content regardless of marine or terrestrial source of organic matterDust and river derived levoglucosan escape burial in the tropical Atlantic, despite the dominant tropical source of pyrogenic carbon [ABSTRACT FROM AUTHOR]

Modern precipitation over northeastern (NE) South America is strongly controlled by the seasonal meridional migration of the Intertropical Convergence Zone (ITCZ). Ample evidence from the Northern Hemisphere suggests a mid‐ to late Holocene southward migration of the ITCZ. Such a shift would be expected to increase precipitation over semi‐arid northern NE Brazil (Southern Hemisphere). However, the most robust precipitation record from northern NE Brazil shows a drying trend throughout the Holocene. Here, we address this issue presenting a high‐temporal resolution reconstruction of precipitation over northern NE Brazil based on data from a marine sediment core, together with analyses of mid‐ and late Holocene simulations performed with the fully coupled climate model FGOALS‐s2. Both, our data and the climate model simulations show a decrease in precipitation over northern NE Brazil from the mid‐ to the late Holocene. The model outputs further indicate a latitudinal contraction of the seasonal migration range of the ITCZ that, together with an intensification of the regional Walker circulation, were responsible for the mid‐ to late Holocene changes in precipitation over NE South America. Our results reconcile apparently conflicting precipitation records and climate mechanisms used to explain changes in precipitation over NE South America. Plain Language Summary: The tropical rainbelt impacts food and water security for 1 billion people. Knowing its dynamics is of utmost importance. The suggestion of a southward migration of the tropical rainbelt through the Holocene (last 11,700 years) has influenced paleoclimatology for two decades. However, most of the available evidence supporting this suggestion comes from tropical Northern Hemisphere precipitation reconstructions like northernmost South America. They systematically show a decrease in precipitation through the Holocene. In the tropical Southern Hemisphere like northeastern Brazil, at the opposite side of the tropical rainbelt, precipitation reconstructions are, however, rare. We reconstructed mid‐ to late Holocene (last 5,200 years) changes in precipitation over northeastern Brazil (tropical Southern Hemisphere), where modern precipitation is associated with the southern border of the tropical rainbelt. We analyzed three independent indicators of changes in precipitation recorded in marine sediments collected off northeastern Brazil. All indicators suggest a decrease in precipitation over northeastern Brazil from the mid‐ to the late Holocene. Together with climate model simulations, our results indicate a latitudinal contraction of the tropical rainbelt. A Holocene contraction of the rainbelt, in contrast to a southward migration, reconciles apparently conflicting precipitation reconstructions and provides valuable insights into the dynamics of the tropical rainbelt. Key Points: Precipitation over northern northeastern Brazil decreased from the mid‐ to the late HoloceneThe meridional migration range of the Intertropical Convergence Zone contracted from the mid‐ to the late HoloceneTogether with the intensification of the regional Walker circulation, our results reconcile previously conflicting records [ABSTRACT FROM AUTHOR]

Magnetic signals in deep‐sea sediments have the potential to unravel past continental environmental changes, via changes in primary terrigenous magnetic supply, but also record past marine environmental conditions, via in situ formation of secondary magnetic minerals, particularly when complemented by independent proxies. By combining environmagnetic, geochemical, and siliciclastic grain size data, we investigated marine sediment core GL‐1090 (24.92°S, 42.51°W, 2,225 m water depth) aiming to unravel changes in terrigenous sediment input and bottom water conditions during the last ∼184 ka at the western South Atlantic middepth. The Al/Si, Fe/κ and siliciclastic grain size data show that terrigenous sediments at this core location derived from the Plata River (southeastern South America). This material was transported northwards by the Brazilian Coastal Current and their delivery to our core site was modulated by sea‐level oscillations. Periods of low sea‐level were characterized by the input of coarser and more abundant terrigenous sediments. Environmagnetic parameters indicate significant downcore variations in the magnetic domain state, which we interpret as changes in the content of biogenic magnetite following glacial‐interglacial cycles. Coeval negative excursions in magnetic grain size and benthic δ13C suggests that concentrations of single domain magnetite (possibly magnetotactic bacterial magnetite) vary in response to middepth water ventilation. We suggest that reduced ventilation in the middepth western South Atlantic bottom waters during peak glaciations triggered a decrease in the production of biogenic magnetite. Peak glaciations were, in turn, linked with increases in the residence time of North Atlantic Deep Water (or its glacial counterpart). Key Points: Multi‐proxy approach points to the Plata River as the main lithogenic sediment source to tropical SE South American continental margin, modulated by sea‐levelReduced biogenic magnetite formation coeval with negative benthic δ13C anomalies during glaciationsBiogenic magnetite formation hampered by decreased bottom water ventilation during glaciations [ABSTRACT FROM AUTHOR]

Late Holocene hydroclimate variations have been extensively recognized in Amazonia, but the effects of such changes on riverine discharge within the Amazon lowlands are still poorly understood. We investigated a sediment core covering circa 4,000 to 300 cal yr BP collected in the lower valley of the Xingu River (Xingu Ria) in an area under the influence of the Amazon River. Our results indicate a decrease in precipitation in the Amazon lowlands throughout the studied period and reduced input of coarser and potassium‐rich Amazon River sediments to the confluence from about 2,600 to 1,400 cal yr BP. We suggest that lower temperatures in the extratropical Southern Hemisphere weakened the South American Summer Monsoon and led to a decrease in the water discharge of the Amazon River during this period. Plain Language Summary: The variability of the Amazon River water discharge over the last millennia is still poorly understood. Sediments deposited in the lower valley of the Xingu River, a major eastern tributary of the Amazon River, allowed for the identification of a decrease in rainfall over the Amazon lowlands throughout the last 4,000 years. Changes in the relative input of Amazon and Xingu sediments in an area affected by both rivers indicate that the water discharge of the Amazon River decreased from about 2,600 to 1,400 years ago. We suggest that anomalously low temperatures in the Southern Hemisphere led to drier conditions in Amazonia during this period. Key Points: Sediments in fluvial rias reveal hydrological changes in Amazonia during the last millenniaCompound‐specific plant wax isotope records suggest a decrease in rainfall in Amazon lowlands over the last 4,000 yrA shift in the extratropical temperature gradient from 2,600 to 1,400 cal yr BP potentially led to lower Amazon River water discharge [ABSTRACT FROM AUTHOR]

Surface ocean circulation in the western equatorial Atlantic is mainly wind driven and plays a major role for the transport of warm waters to the North Atlantic. Past changes in the strength and direction of the trade winds are well documented, but the response of the western equatorial Atlantic circulation and water column structure to these changes is unclear. Here we used the difference between the stable isotopic oxygen composition of two species of planktonic foraminifera (Globigerinoides ruber white and Neogloboquadrina dutertrei) from two sediment cores collected off northeastern Brazil to investigate millennial‐ and orbital‐scale changes in upper ocean stratification since the Last Interglacial. Our records indicate enhanced upper ocean stratification during several Heinrich stadials, partly due to a shoaling of the thermocline, which was linked to a decrease in the strength of southeast trades winds. In addition, we show that a decrease in wind zonality induced by increases in Northern Hemisphere low‐latitude summer insolation causes a shoaling of the thermocline in the western equatorial Atlantic. These ocean‐atmosphere changes contributed to a reduction in the cross‐equatorial transport of warm waters, particularly during Heinrich stadials and Marine Isotope Stage 4. Key Points: Changes in western equatorial Atlantic thermocline depth were recorded on millennial and orbital time scalesShoaling of the thermocline during Heinrich stadials was associated with weak southeast trade windsShoaling of the thermocline during periods of low‐latitude boreal summer insolation maxima occurred due to decreased wind zonality [ABSTRACT FROM AUTHOR]

The modern state of the Atlantic meridional overturning circulation promotes a northerly maximum of tropical rainfall associated with the Intertropical Convergence Zone (ITCZ). For continental regions, abrupt millennial–scale meridional shifts of this rainbelt are well documented, but the behavior of its oceanic counterpart is unclear due the lack of a robust proxy and high temporal resolution records. Here we show that the Atlantic ITCZ leaves a distinct signature in planktonic foraminifera assemblages. We applied this proxy to investigate the history of the Atlantic ITCZ for the last 30,000 years based on two high temporal resolution records from the western Atlantic Ocean. Our reconstruction indicates that the shallowest mixed layer associated with the Atlantic ITCZ unambiguously shifted meridionally in response to changes in the strength of the Atlantic meridional overturning with a southward displacement during Heinrich Stadials 2–1 and the Younger Dryas. We conclude that the Atlantic ITCZ was located at ca. 1°S (ca. 5° to the south of its modern annual mean position) during Heinrich Stadial 1. This supports a previous hypothesis, which postulates a southern hemisphere position of the oceanic ITCZ during climatic states with substantially reduced or absent cross-equatorial oceanic meridional heat transport. [ABSTRACT FROM AUTHOR]

This article presents the scientific rationale for an ambitious ICDP drilling project to continuously sample Late Cretaceous to modern sediment in four different sedimentary basins that transect the equatorial Amazon of Brazil, from the Andean foreland to the Atlantic Ocean. The goals of this project are to document the evolution of plant biodiversity in the Amazon forests and to relate biotic diversification to changes in the physical environment, including climate, tectonism, and the surface landscape. These goals require long sedimentary records from each of the major sedimentary basins across the heart of the Brazilian Amazon, which can only be obtained by drilling because of the scarcity of Cenozoic outcrops. The proposed drilling will provide the first long, nearly continuous regional records of the Cenozoic history of the forests, their plant diversity, and the associated changes in climate and environment. It also will address fundamental questions about landscape evolution, including the history of Andean uplift and erosion as recorded in Andean foreland basins and the development of west-to-east hydrologic continuity between the Andes, the Amazon lowlands, and the equatorial Atlantic. Because many modern rivers of the Amazon basin flow along the major axes of the old sedimentary basins, we plan to locate drill sites on the margin of large rivers and to access the targeted drill sites by navigation along these rivers. [ABSTRACT FROM AUTHOR]

During Termination 1, millennial-scale weakening events of the Atlantic meridional overturning circulation (AMOC) supposedly produced major changes in sea surface temperatures (SSTs) of the western South Atlantic, and in mean air temperatures (MATs) over southeastern South America. It has been suggested, for instance, that the Brazil Current (BC) would strengthen (weaken) and the North Brazil Current (NBC) would weaken (strengthen) during slowdown (speed-up) events of the AMOC. This antiphase pattern was claimed to be a necessary response to the decreased North Atlantic heat piracy during periods of weak AMOC. However, the thermal evolution of the western South Atlantic and the adjacent continent is so far largely unknown. Here we address this issue, presenting high-temporal-resolution SST and MAT records from the BC and southeastern South America, respectively. We identify a warming in the western South Atlantic during Heinrich Stadial 1 (HS1), which is followed first by a drop and then by increasing temperatures during the Bølling-Allerød, in phase with an existing SST record from the NBC. Additionally, a similar SST evolution is shown by a southernmost eastern South Atlantic record, suggesting a South Atlantic-wide pattern in SST evolution during most of Termination 1. Over southeastern South America, our MAT record shows a twostep increase during Termination 1, synchronous with atmospheric CO2 rise (i.e., during the second half of HS1 and during the Younger Dryas), and lagging abrupt SST changes by several thousand years. This delay corroborates the notion that the long duration of HS1 was fundamental in driving the Earth out of the last glacial. [ABSTRACT FROM AUTHOR]

The stable hydrogen isotope composition of lipid biomarkers, such as alkenones, is a promising new tool for the improvement of paleosalinity reconstructions. Laboratory studies confirmed the correlation between lipid biomarker δD composition (δDLipid), water δD composition (...) and salinity. Yet, there is limited insight into the applicability of this proxy in oceanic environments. To fill this gap, we test the use of the δD composition of alkenones (...) and palmitic acid (δDPA) as salinity proxies using samples of surface suspended material along the distinct salinity gradient induced by the Amazon Plume. Our results indicate a positive correlation between salinity and ..., while the relationship between ... and δDLipid is more complex: δDPA correlates strongly with ... (r² = 0.81) and shows a salinity dependent isotopic fractionation factor. δ only correlates with δ in samples with alkenone concentrations > 10ngL-1 (r² = 0.51). These findings are mirrored by alkenone based temperature reconstructions, which are inaccurate for samples with alkenone concentrations < 10ngL-1. Deviations in ... and temperature are likely to be caused by limited haptophyte algae growth due to low salinity and light limitation imposed by the Amazon Plume. Our study confirms the applicability of δDLipid as a salinity proxy in oceanic environments. But it raises a note of caution concerning regions where low alkenone production can be expected due to very low salinity conditions. To circumvent these limitations, we suggest the complementary use of ... and δDPA. [ABSTRACT FROM AUTHOR]

During Termination 1, millennial-scale weakening events of the Atlantic meridional overturning circulation (AMOC) supposedly produced major changes in sea surface temperatures (SST) of the western South Atlantic, and in mean air temperatures (MAT) over southeastern South America. It was suggested, for instance, that the Brazil Current (BC) would strengthen (weaken) and the North Brazil Current (NBC) would weaken (strengthen) during slowdown (speed-up) events of the AMOC. This anti-phase pattern was claimed to be a necessary response to the decreased North Atlantic heat piracy during periods of weak AMOC. However, the thermal evolution of the western South Atlantic and the adjacent continent is largely unknown and a compelling record of the BC-NBC anti-phase behavior remains elusive. Here we address this issue, presenting high temporal resolution SST and MAT records from the BC and southeastern South America, respectively. We identify a warming in the western South Atlantic during Heinrich Stadial 1 (HS1), which is followed first by a drop and then by increasing temperatures during the Bølling--Allerød, in-phase with an existing NBC record. Additionally, a similar SST evolution is shown by a southernmost eastern South Atlantic record, suggesting a South Atlantic-wide pattern in SST evolution during most of Termination 1. Over southeastern South America, our MAT record shows a two-step increase during Termination 1, synchronous with atmospheric CO2 rise (i.e., during the second half of HS1 and during the Younger Dryas), and lagging abrupt SST changes by several thousand years. This delay corroborates the notion that the long duration of HS1 was fundamental to drive the Earth out of the last glacial. [ABSTRACT FROM AUTHOR]

The mid-Holocene (6000 calibrated years before present) is a key period in palaeoclimatology because incoming summer insolation was lower than during the late Holocene in the Southern Hemisphere, whereas the opposite happened in the Northern Hemisphere. However, the effects of the decreased austral summer insolation over South American climate have been poorly discussed by palaeodata syntheses. In addition, only a few of the regional studies have characterised the mid-Holocene climate in South America through a multiproxy approach. Here, we present a multiproxy compilation of mid-Holocene palaeoclimate data for eastern South America. We compiled 120 palaeoclimatological datasets, which were published in 84 different papers. The palaeodata analysed here suggest a water deficit scenario in the majority of eastern South America during the mid- Holocene if compared to the late Holocene, with the exception of northeastern Brazil. Low mid-Holocene austral summer insolation caused a reduced land-sea temperature contrast and hence a weakened South American monsoon system circulation. This scenario is represented by a decrease in precipitation over the South Atlantic Convergence Zone area, saltier conditions along the South American continental margin, and lower lake levels. [ABSTRACT FROM AUTHOR]

We investigate changes in the delivery and oceanic transport of Amazon sediments related to terrestrial climate variations over the last 250 ka. We present high-resolution geochemical records from four marine sediment cores located between 5 and 12°N along the northern South American margin. The Amazon River is the sole source of terrigenous material for sites at 5 and 9° N, while the core at 12° N receives a mixture of Amazon and Orinoco detrital particles. Using an endmember unmixing model, we estimated the relative proportions of Amazon Andean material ("%-Andes", at 5 and 9°N) and of Amazon material ("%-Amazon", at 12°N) within the terrigenous fraction. The %-Andes and %-Amazon records exhibit significant precessional variations over the last 250 ka that are more pronounced during interglacials in comparison to glacial times. High %-Andes values observed during periods of high austral summer insolation reflect the increased delivery of suspended sediments by Andean tributaries and enhanced Amazonian precipitation, in agreement with western Amazonian speleothem records. However, low %-Amazon values obtained at 12°N during the same periods seem to contradict the increased delivery of Amazon sediments. We propose that reorganisations in surface ocean currents modulate the northwestward transport of Amazon material. In agreement with published records, the seasonal North Brazil Current retroflection is intensified (or prolonged in duration) during cold substages of the last 250 ka (which correspond to intervals of high DJF or low JJA insolation) and deflects eastward the Amazon sediment and freshwater plume. [ABSTRACT FROM AUTHOR]

The Mid-Holocene (6 ka BP) is a key period to the study of climate, since it presented lower than present incoming summer insolation in the Southern Hemisphere, and the opposite in the Northern Hemisphere. This happened due to a different than present configuration of the orbital parameters. To investigate the effects of insolation on the Mid-Holocene climate, some global and regional multiproxy palaeodata compilations have been elaborated. However, few global studies have focused on the Southern Hemisphere, and none of the regional ones have characterized the Mid-Holocene climate in South America through a multiproxy approach. Here we present the first multiproxy compilation to the Mid-Holocene climate in eastern South America. We have compiled 120 palaeoclimatological data, published in 84 different papers. The palaeo-data analyzed suggest a water deficit scenario in great part of eastern South America during Mid-Holocene, except for Northeastern Brazil. Nonetheless, further sampling is mandatory in South America and in the adjacent ocean basins. [ABSTRACT FROM AUTHOR]

Seafloor methane release can significantly affect the global carbon cycle and climate. Appreciable quantities of methane are stored in continental margin sediments as shallow gas and hydrate deposits, and changes in pressure, temperature and/or bottom-currents can liberate significant amounts of this greenhouse gas. Understanding the spatial and temporal dynamics of marine methane deposits and their relationships to environmental change are critical for assessing past and future carbon cycle and climate change. Here we present foraminiferal stable carbon isotope and sediment mineralogy records suggesting for the first time that seafloor methane release occurred along the southern Brazilian margin during the last glacial period (40-20 cal ka BP). Our results show that shallow gas deposits on the southern Brazilian margin responded to glacial-interglacial paleoceanographic changes releasing methane due to the synergy of sea level lowstand, warmer bottom waters and vigorous bottom currents during the last glacial period. High sea level during the Holocene resulted in an upslope shift of the Brazil Current, cooling the bottom waters and reducing bottom current strength, reducing methane emissions from the southern Brazilian margin.