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In the last century, a blue–green colored gemstone known as Larimar with a special sea-wave pattern was discovered in the Dominican Republic. Larimar is composed of the mineral pectolite, which has a chemical composition of NaCa2Si3O8(OH) and is usually white in color. Cu2+ has always been considered to be the primary genesis of the blue color shown in Larimar, because native copper often grows together with Larimar. To clarify whether copper is the main reason for the origin of blue–green pectolite, we utilized laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) techniques to analyze trace elements in the pectolite samples and compared the relationship between elements and colors. The results show that vanadium and iron are the main origins of the sky-blue and green color of Larimar. We also discovered that it is not only the chemical elements that affect the color shades of the mineral, but the orientation of the radial fiber crystals also plays a critical role. The sea-wave pattern and the changes in the color saturation of radial pectolite are due to the transmittance of visible light through different viewed angles under changing crystal orientations. Our results reveal the chemical and physical factors behind the color and sea-wave pattern of Larimar. In addition, to our knowledge, this is the first time that the formation age of Larimar has been proven to be approximately equal to or younger than 40 ka, using the U-Th dating of calcite growth together with pectolite. [ABSTRACT FROM AUTHOR]

Abstract Background The prevalence of resistance to fusidic acid of methicillin-resistant Staphylococcus aureus (MRSA) was increased each year in a Taiwan hospital. Thirty-four MRSA clinical isolates collected in 2007 and 2008 with reduced susceptibility to FA were selected for further evaluation the presence of resistance determinants. Results The most common resistance determinant was fusC, found in 25 of the 34 MRSA isolates. One of the 25 fusidic acid-resistant MRSA harboured both fusB and fusC, which is the first time this has been identified. Mutations in fusA were found in 10 strains, a total of 3 amino-acid substitutions in EF-G (fusA gene) were detected. Two substitutions with G556S and R659L were identified for the first time. Low-level resistance to fusidic acid (MICs, ≤ 32 μg/ml) was found in most our collection. All collected isolates carried type III SCCmec elements. MLST showed the isolates were MRSA ST239. PFGE revealed nine different pulsotypes in one cluster. Conclusions Our results indicate that the increase in the number of fusidic acid resistant among the MRSA isolates in this hospital is due mainly to the distribution of fusC determinants. Moreover, more than one fusidic acid-resistance mechanism was first detected in a same stain in our collection.

The northwestern Pacific Ocean and South China Sea are where tropical cyclones occur most frequently. Many climatologists also study the formation of Pacific Ocean warm pools and typhoons in this region. This study collected data of paleotyphoons found in China's official historical records over the past 2000 years that contained known typhoon activity reports. The collected data are then subjected to statistical analyses focusing on typhoon activity in coastal regions of southeastern China to garner a better understanding of the long-term evolution of moving paths and occurrence frequency, especially regarding those typhoons making landfall in mainland China. We analyzed the data with the year and month of each typhoon event, as well as the number of events in a 10-year period. The result shows that (1) north–southward migration of typhoon paths corresponds to the north–southward migration of the Intertropical Convergence Zone (ITCZ) during the Medieval Warm Period (MWP) and Little Ice Age (LIA) and (2) paleotyphoons made landfall in mainland China 1 month earlier during the MWP than during the LIA. This implies a northward shift in ITCZ during the MWP. Typhoons tend to make landfall in Japan during El Niño-like periods and strike the southern coastal regions of China during La Niña-like stages. According to paleotyphoon records over the last 2000 years, typhoons made landfall in southeastern China frequently around 490–510, 700–850, and after 1500 CE The number of typhoons striking Guangdong Province peaked during the coldest period in 1660–1680 CE; however, after 1700 CE, landfall has migrated farther north. The track of tropical cyclones (TCs) in the northwestern Pacific Ocean is affected by the North Atlantic Oscillation (NAO) and the Pacific Decadal Oscillation (PDO), which shows a nearly 30-year and a 60-year cycle during the LIA. [ABSTRACT FROM AUTHOR]

ABSTRACT SHV-12 is the most widespread resistance determinant of Enterobacter cloacae in Taiwan; however, blaSHV-12 has rarely been mobilized. Six multidrug-resistant E. cloacae isolates were collected. After conjugal transfer, plasmid profiling and analysis of incompatibility groups was performed to characterize the genetic context of blaSHV-12-containing fragments. The presence of mobile genetic elements was demonstrated by PCR, cloning, sequencing and bioinformatics analyses. Four different β-lactamase genes ( blaTEM-1, blaSHV-12, blaCTX-M-3 and/or blaCTX-M-14) were observed in the conjugative plasmids belonging to the IncHI2 ( n = 4), IncI1 or IncP incompatibility groups. The IS 26-blaSHV-12-IS 26 locus was located in five different genetic environments. A novel structural organization of a class 1 integron with the aac(6')-IIc cassette truncated by IS 26 was identified in one isolate. Thus, blaSHV-12 was obtained from different plasmids through IS 26-mediated homologous recombination. IS 26 plays a vital role in the distribution of mobile resistance elements between different plasmids found in multidrug-resistant E. cloacae isolates. [ABSTRACT FROM AUTHOR]

The purpose of this study is to improve prehistoric knowledge of paleo-typhoon and winter monsoon activity in the western North Pacific after 8 cal. ka BP. We examine two sediment cores derived from lakes located to the south and north of the Ilan Plain in northeastern Taiwan. Seasonal and typhoon rainfall data over the past several decades are collected for this study region. We also use mineral indicators, K/Rb ratios and grain size to estimate sediment sources, intensity of chemical weathering and rainfall intensity. The results show that the chemical weathering index (K/Rb ratio) of Meihua Lake indicates the continuing effects of autumn rainfall, while coarse grain sizes of Dahu Lake sediments suggest increased intensity in typhoon rainfall. Grain size results reveal that increasing El Niño-Southern Oscillation intensity in the tropical Pacific has intensified the activity of super typhoons in the western North Pacific. Finally, we find that frequent activity of super paleo-typhoons occurred in Taiwan during the La Niña-like state, and the strengthening winter monsoon activity and higher sea surface temperature enhanced plentiful autumn rainfall in El Niño-like state. After comparing our results with the paleo-typhoon data in Japan and south China, we suggest that the tracks of super typhoon are mainly affected by variations in the warm pool and subtropical Northwestern Pacific High in the western Pacific. Copyright © 2012 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Abstract: Dissolution of the glasses with compositions of Na2O·CaO· nSiO2 (n =2.5–6) in 0.5M Na2CO3 solution was studied experimentally. The experiments were carried out with autoclaves under the conditions of the autogeneous pressure, 150°C, and durations from 16 hours to 60 days. Experimental results show that the dissolution rate is increased with the increase of silica-content of the glass, especially in long-term ones. By comparison, the dissolution rate is significantly slower in long-term experiments than in short-term ones. During dissolution, the surface reaction generally plays the main role in short-term experiments, whereas in long-term ones, the solid diffusion and the surface reaction may both act significantly. In this kind of alkaline solution, percentage of Ca would be rich on the glass surface, and Na/Si depletion occurred. As the solution was renewed in short-term systems, the dissolution rate of Na was faster than Si on the glass surface. While the precipitation occurred, Si were consumed by the precipitated phases continuously and therefore the depletion of Si became more obviously. In addition, the high-Si glasses own higher dissolution rates than low-Si ones in long-term experiments, because the minerals growing on the low-Si glasses are closed and they prevent the reaction solution and glass. [Copyright &y& Elsevier]

Serpentinites associated with metamafic and metaplagiogranitic rocks occur sporadically within metasedimentary schists in the Yuli belt. Such metaigneous rocks are considered to represent ophiolitic protoliths and some contain high-pressure (HP) metamorphic minerals or assemblages. However, the origin and metamorphism of these serpentinites have long been a mystery. This study systematically investigates the four major serpentinite-bearing exposures at the Fengtien, Wanjung, Tsunkuanshan, and Chinshuichi. The results reveal that the serpentinites are of two different protoliths on the basis of relict chromian spinel composition. Cr-spinel compositions of the Fengtien and Tsunkuanshan samples are characterised by moderate Cr# [Cr/(Cr + Al)] (0.45–0.57), relatively high Mg# [Mg/(Mg+Fe2+)] (0.59–0.79), but low Fe3+# [Fe3+/(Fe3++Cr+Al)] (0.02–0.06), reflecting an abyssal peridotite type protolith. By contrast, Cr-spinel compositions of the Wanjung and Chinshuichi samples show high Cr# (up to 0.74) and Fe3+# (0.03–0.08), but low Mg# (<0.6), indicating a forearc mantle peridotite origin. Peak metamorphic conditions of the serpentinites are represented by the assemblage of antigorite + magnetite + chlorite + olivine + diopside, which is estimated as up to 550°C but the pressure cannot be constrained quantitatively. Based on field relations, it is inferred that the serpentinites, associated HP metaigneous rocks, and garnet-bearing metasedimentary schists were metamorphosed isofacially. Despite two origins, the peridotitic protoliths were all subjected to hydration and subduction processes. We suggest that precursors of the serpentinites, metaigneous rocks, and metasedimentary schists were juxtaposed and metamorphosed at intermediate to great depths (~35–55 km) of a subduction zone. Therefore, the Yuli belt serpentinites and associated rocks likely represent exhumed materials from a palaeo-subduction interface. [ABSTRACT FROM AUTHOR]

In this work, Raman spectroscopic experiments are conducted on zeolites, including a total of 33 varieties and seven groups with different secondary structural frameworks, for which characteristic vibration modes are studied. Most of the zeolites show prominent Raman peaks in the spectral range between 200–1200 cm−1. Different groups of zeolites can be recognized by differences in the wavenumbers of the T-O-T (T = Si and Al, O = oxygen) modes in the range 379–538 cm−1, the M-O (M = metal,) modes in the range 250–360 cm−1 and the T-O bending modes in the range 530–575 cm−1. All zeolites show characteristic Raman peaks in the range 379–529 cm−1, except for natrolite group (fibrous) zeolites, which are characterized by T-O-T modes in the 433–447 cm−1 range and T-O bending modes in the 528–538 cm−1 range. The analcime group (with singly connected four-ring chains) zeolites show T-O-T modes in the 379–392 cm−1 and 475–497 cm−1 ranges. The gismondine group (with doubly connected four-ring chains) zeolites have T-O-T modes in the 391–432 cm−1 and 463–497 cm−1 ranges. The chabazite group (with a six-cyclic ring) zeolites are characterized by M-O modes in the 320–340 cm−1 range and T-O-T modes in the 477–509 cm−1 range. The Raman modes of mordenite group zeolites (397–410 cm−1 and 470–529 cm−1) overlap with those of heulandite group zeolites (402–416 cm−1 and 480–500 cm−1). Moreover, the mordenite group has a characteristic peak in the 502–529 cm−1 range, and an additional peak in the 800–965 cm−1 range. Another recognizable peak for the heulandite group is in the 612–620 cm−1 range. The unknown zeolites (cowlesite) have unique characteristic peaks at 534 cm−1, which can aid in the verification of their identity. [ABSTRACT FROM AUTHOR]

We investigated the ammonium removal abilities of natural and synthetic zeolites with distinct Si/Al ratios and various surface areas to study how adsorption and ion exchange processes in zeolites perform under different ammonium concentrations and different temperatures. Five zeolites—natural mordenite, chabazite, erionite, clinoptilolite, and synthetic merlinoite—were immersed in 20, 50, and 100 mg/kg ammonium solutions. The results demonstrate that zeolites under high ammonium concentrations (100 mg/kg) possess higher physical adsorption capacity (0.398–0.468 meq/g), whereas those under lower ammonium concentrations (20 mg/kg) possess greater ion exchange properties (64–99%). The ion exchange ability of zeolites is extremely dependent on the cation content of the zeolites, and the cation content is affected by the Si/Al ratio. The surface area of zeolites also has a partial influence on its physical adsorption ability. When the surface area is less than 100 m2/g, the adsorption ability of zeolite increases obviously with surface area; however, adsorption ability is saturated as the surface area becomes larger than this critical value of 100 m2/g. When we placed the zeolites in 50 mg/kg ammonium concentration at different temperatures (5–50 °C), we found that the zeolites exhibited the highest ammonium removal ability at 30 °C and the potassium release was enhanced at 30–40 °C. [ABSTRACT FROM AUTHOR]

Lacustrine record of marine aerosol input has rarely been documented. Here, we present the sulfur geochemistry during the last deglaciation and early Holocene of a sediment core retrieved from the Dongyuan Lake in southern Taiwan. An unusually high sulfur peak accompanying pyrite presence is observed at 10.5 ka BP. Such high sulfur content in lacustrine record is unusual. The δ34S of sulfur varied from +9.5 to + 17.1‰ with two significant positive shifts at 10.5 and 9.4 ka BP. The sources of sulfur and potential processes involving the sulfur isotope variation including bacterial sulfate reduction, volcanic emissions, in-catchment sulfide oxidation and marine aerosol input are discussed. Enhanced marine aerosol input is the most likely explanation for such sulfur peaks and δ34S shifts. The positive δ34S shifts appeared concurrently with the maximum landslide events over Taiwan resulted from enhanced typhoon activities. The synchronicity among records suggests that increased typhoon activities promoted sea spray, and consequently enhanced the marine aerosol input with 34S-enriched sulfate. Our sulfur geochemistry data revealed sea spray history and marine influence onto terrestrial environment at coastal regions. Wider coverage of spatial-temporal lacustrine sulfur geochemistry record is needed to validate the applicability of sulfur proxy in paleoenvironmental research. [ABSTRACT FROM AUTHOR]

Abstract: To investigate the coseismic frictional temperature in seismogenic fault zones, we examine the characteristics of clays in the Chelungpu-fault zones with isothermal heating experiments, scanning electron microscope coupled to an energy dispersive spectrometer (SEM/EDX), and thermogravimetry analysis (TGA). In the TCDP case (Taiwan Chelungpu fault Drilling Project), three fault zones of the Chelungpu-fault system were identified at the depth of 1111m, 1153m, and 1222m (described as FZ1111, FZ1153, and FZ1222 hereafter), respectively. The clay mineral assemblages of FZ1111 show evidence of melting, and the temperature in a ~2cm band within the black gouge zone is estimated to be from 900°C to 1100°C by comparing the SEM images of in situ natural samples with those of heated materials, and the finding of no recrystallization of kaolinite-amorphous aluminosilicates-spinel in the fault samples. The clay mineral assemblages of FZ1153 suggested that kaolinite has been broken down by the thermal decomposition/dehydroxylation but chlorite has not. The clay characteristics and results of SEM/EDX and TGA constrain the faulting temperature from 500°C to 900°C, with a spatial distribution up to ~1.3m. The clay characteristics of FZ1222 indicated that clays were changed by experiencing high temperature acid fluids, instead of thermal decomposition/dehydroxylation processes, and that the temperature is localized in ~2cm and ranges from 350°C to 500°C, the lowest temperature among three fault zones. The estimates of temperature ranges, and thermal anomaly intervals among three fault zones provide important information and constraints on the physical and chemical processes, coseismic dynamic weakening mechanism, and earthquake energy budget in the future. [Copyright &y& Elsevier]

Dust plays an important role in climate changes as it can alter atmospheric circulation, and global biogeochemical and hydrologic cycling. Many studies have investigated the relationship between dust and temperature in an attempt to predict whether global warming in coming decades to centuries can result in a less or more dusty future. However, dust and temperature changes have rarely been simultaneously reconstructed in the same record. Here we present a 1600-yr-long quantitative record of temperature and dust activity inferred simultaneously from varved Kusai Lake sediments in the northern Qinghai-Tibetan Plateau, NW China. At decadal time scale, our temperature reconstructions are generally in agreement with tree-ring records from Karakorum of Pakistan, and temperature reconstructions of China and North Hemisphere based on compilations of proxy records. A less or more dusty future depends on temperature variations in the Northern Qinghai-Tibetan Plateau, i.e. weak and strong dust activities at centennial time scales are well correlated with low and high June-July-August temperature (average JJA temperature), respectively. This correlation means that stronger summer and winter monsoon should occur at the same times in the northern Qinghai-Tibetan Plateau.

Background: The prevalence of resistance to fusidic acid of methicillin-resistant Staphylococcus aureus (MRSA) was increased each year in a Taiwan hospital. Thirty-four MRSA clinical isolates collected in 2007 and 2008 with reduced susceptibility to FA were selected for further evaluation the presence of resistance determinants., Results: The most common resistance determinant was fusC, found in 25 of the 34 MRSA isolates. One of the 25 fusidic acid-resistant MRSA harboured both fusB and fusC, which is the first time this has been identified. Mutations in fusA were found in 10 strains, a total of 3 amino-acid substitutions in EF-G (fusA gene) were detected. Two substitutions with G556S and R659L were identified for the first time. Low-level resistance to fusidic acid (MICs, ≤32 μg/ml) was found in most our collection. All collected isolates carried type III SCCmec elements. MLST showed the isolates were MRSA ST239. PFGE revealed nine different pulsotypes in one cluster., Conclusions: Our results indicate that the increase in the number of fusidic acid resistant among the MRSA isolates in this hospital is due mainly to the distribution of fusC determinants. Moreover, more than one fusidic acid-resistance mechanism was first detected in a same stain in our collection.