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In order to find the anti-freezing durability differences between concrete in the frequent natural freeze–thaw conditions in the northwest of Sichuan Province, China, and concrete in the rapid freeze–thaw conditions of the standard rapid method, the typical temperature and humidity of the northwest of Sichuan Province were simulated. The results showed that the average number of freeze–thaw cycles in the northwest of this province can reach up to 150 per year. The relative dynamic modulus of C30 ordinary concrete, which is 100% pre-saturated, still remained above 90% after 450 cycles in simulated environments. However, during the rapid freeze–thaw test, even the C30 air-entrained concrete failed after 425 cycles. Compared to the saturation degree of concrete itself, the continuous replenishment of external moisture during freeze–thaw cycles is a key factor affecting the frost resistance of concrete. Rapid freeze–thaw reduces the number of the most probable pore sizes in ordinary concrete, and the pore size distribution curve tends to flatten. The reduction rate of the surface porosity of air-entrained concrete before and after rapid freeze–thaw is only about one third of that of ordinary concrete.