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The extent to which solid‐state volume diffusion modifies rare earth element (REE) abundances in accessory minerals during high‐temperature metamorphism governs our ability to link recorded trace‐element compositions to particular thermal events. We model diffusion of REE in zircon under different temperature–time conditions and show that, for both short‐lived (e.g. 1100°C for 1–5 Ma) and more prolonged (e.g. 1050°C for 10–30 Ma or 1000°C for 200 Ma) episodes of ultra‐high‐temperature (UHT) metamorphism, REE diffusion in igneous zircon is sufficiently rapid for REE in a ~50‐μm grain to equilibrate with the new metamorphic mineral assemblage of the host rock. By contrast, unless diffusion is accelerated by recrystallization, the presence of fluids or other processes at temperatures below 900°C zircon will largely retain its original pre‐metamorphic REE abundance pattern, even when the thermal event is long lived (≥100 Ma). Where volume diffusion is dominant, for instance, in the absence of a fluid phase, the sensitivity of REE mobility to temperature can help constrain the temperature–time path of high‐grade metamorphic rocks. Modelling of well‐characterized natural samples from the regional‐scale aureole surrounding the Rogaland Igneous Complex (RIC) in SW Norway shows that variations in REE concentration patterns in zircon indicate a T–t evolution that is consistent with independent P–T–t estimates for regional metamorphism based on phase equilibrium modelling (850–950°C at 7–8 kbar for ~100 Ma). Greater modification of REE abundance patterns in zircons within 2 km of the RIC contact, however, indicates that UHT conditions persisted for ~150 Ma close to the intrusion, with a temperature of ~1100°C for 1–5 Ma at the RIC contact. Thermal modelling suggests that the inferred T–t histories of samples from different distances from the RIC contact are best explained if the complex was emplaced incrementally over 1–5 Ma. [ABSTRACT FROM AUTHOR]

The final assembly of the Mesoproterozoic supercontinent Nuna was marked by the collision of Laurentia and Australia at 1.60 Ga, which is recorded in the Georgetown Inlier of NE Australia. Here, we decipher the metamorphic evolution of this final Nuna collisional event using petrostructural analysis, major and trace element compositions of key minerals, thermodynamic modelling, and multi‐method geochronology. The Georgetown Inlier is characterised by deformed and metamorphosed 1.70–1.62 Ga sedimentary and mafic rocks, which were intruded by c. 1.56 Ga old S‐type granites. Garnet Lu–Hf and monazite U–Pb isotopic analyses distinguish two major metamorphic events (M1 at c. 1.60 Ga and M2 at c. 1.55 Ga), which allows at least two composite fabrics to be identified at the regional scale—c. 1.60 Ga S1 (consisting in fabrics S1a and S1b) and c. 1.55 Ga S2 (including fabrics S2a and S2b). Also, three tectono‐metamorphic domains are distinguished: (a) the western domain, with S1 defined by low‐P (LP) greenschist facies assemblages; (b) the central domain, where S1 fabric is preserved as medium‐P (MP) amphibolite facies relicts, and locally as inclusion trails in garnet wrapped by the regionally dominant low‐P amphibolite facies S2 fabric; and (c) the eastern domain dominated by upper amphibolite to granulite facies S2 foliation. In the central domain, 1.60 Ga MP–medium‐T (MT) metamorphism (M1) developed within the staurolite–garnet stability field, with conditions ranging from 530–550°C at 6–7 kbar (garnet cores) to 620–650°C at 8–9 kbar (garnet rims), and it is associated with S1 fabric. The onset of 1.55 Ga LP–high‐T (HT) metamorphism (M2) is marked by replacement of staurolite by andalusite (M2a/D2a), which was subsequently pseudomorphed by sillimanite (M2b/D2b) where granite and migmatite are abundant. P–T conditions ranged from 600 to 680°C and 4–6 kbar for the M2b sillimanite stage. 1.60 Ga garnet relicts within the S2 foliation highlight the progressive obliteration of the S1 fabric by regional S2 in the central zone during peak M2 metamorphism. In the eastern migmatitic complex, partial melting of paragneiss and amphibolite occurred syn‐ to post‐ S2, at 730–770°C and 6–8 kbar, and at 750–790°C and 6 kbar, respectively. The pressure–temperature–deformation–time paths reconstructed for the Georgetown Inlier suggest a c. 1.60 Ga M1/D1 event recorded under greenschist facies conditions in the western domain and under medium‐P and medium‐T conditions in the central domain. This event was followed by the regional 1.56–1.54 Ga low‐P and high‐T phase (M2/D2), extensively recorded in the central and eastern domains. Decompression between these two metamorphic events is ascribed to an episode of exhumation. The two‐stage evolution supports the previous hypothesis that the Georgetown Inlier preserves continental collisional and subsequent thermal perturbation associated with granite emplacement. [ABSTRACT FROM AUTHOR]

Here, we present results of the first 40Ar/39Ar dating of osumilite, a high‐T mineral that occurs in some volcanic and high‐grade metamorphic rocks. The metamorphic osumilite studied here is from a metapelitic rock within the Rogaland–Vest Agder Sector, Norway, an area that experienced regional granulite facies metamorphism and subsequent contact metamorphism between 1,100 Ma and 850 Ma. The large grain size (~1 cm) of osumilite in the studied rock, which preserves a nominally anhydrous assemblage, increases the potential for large portions of individual grains to have remained essentially unaffected by the effects of diffusive argon loss, potentially preserving prograde ages. Step‐heating diffusion experiments yielded a maximum activation energy of ~461 kJ/mol and a pre‐exponential factor of ~8.34 × 108 cm2/s for Ar diffusion in osumilite. These parameters correspond to a relatively high closure temperature of ~620°C for a cooling rate of 10°C/Ma in an osumilite crystal with a 175 µm radius. Fragments of osumilite separated from the sample preserve a range of ages between c. 1,070 and 860 Ma. The oldest ages are inferred to date the growth of coarse‐grained osumilite during prograde granulite facies regional metamorphism, which pre‐date contact metamorphism that has historically been ascribed to the growth of osumilite in the region. The majority of fragments record ages between c. 920 and 860 Ma, inferred to reflect the growth of osumilite and/or diffusive argon loss during contact metamorphism. The retention of old 40Ar/39Ar dates was facilitated by the low diffusivity of Ar in osumilite (i.e. a closed system), large grain sizes, and anhydrous metamorphic conditions. The ability to date osumilite with the 40Ar/39Ar method provides a valuable new thermochronometer that may constrain the timing and duration of high‐T magmatic and metamorphic events. [ABSTRACT FROM AUTHOR]

• 1560 Ma TTG suite and migmatised mafic source exposed in NE Australia. • 'High-pressure' TTG generated at a depth of 25–35 km. • Field observations and trace-element modelling point to fluid-fluxed melting. • TTG chemical diversity reflects variable hydration, not depth. Across the Archaean to Proterozoic transition, the composition of newly-formed felsic continental crust changed from tonalite–trondhjemite–granodiorite (TTG) to calc-alkaline granitoid, possibly coinciding with the emergence of plate tectonics. Nevertheless, TTG suites were sporadically produced in Proterozoic and Phanerozoic orogenic belts, and such occurrences may provide petrological and tectonic insights into the formation of ancient continents. Here we demonstrate that the ca 1560 Ma Forest Home TTG plutonic suite in the Georgetown Inlier, NE Australia, was derived from partial melting of spatially-associated mafic rocks in a post-collisional setting. The studied TTG rocks have a 'high-pressure' geochemical signature, with elevated Sr, low heavy rare earth element and low high field strength element contents. Established petrogenetic models suggest they were derived by partial melting either of hydrated basaltic crust at >70 km depth or enriched lithospheric mantle, or by fractionation of lower-pressure mafic magmas. Using phase equilibrium calculations and trace-element modelling, we show that the geochemical signature of the Georgetown TTG likely resulted from fluid-fluxed crustal melting at relatively shallow depths (25–35 km), consistent with field observations and the inferred metamorphic evolution of the inlier. Our results suggest that the chemical variability of TTGs can reflect the variable availability of fluids rather than depth of melting, which has implications for tectonic processes responsible for the formation of early continental crust. [ABSTRACT FROM AUTHOR]