1. Carbon dioxide conversion to acetate and methane in a microbial electrosynthesis cell employing an electrically-conductive polymer cathode modified by nickel-based coatings
- Author
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Sasha Omanovic, Boris Tartakovsky, Abraham Gomez Vidales, Sabahudin Hrapovic, and Emmanuel Onyekachi Nwanebu
- Subjects
conductive polymer cathode ,Materials science ,microbial electrosynthesis ,Ni-Fe-Mn alloy ,020209 energy ,Energy Engineering and Power Technology ,02 engineering and technology ,Electrocatalyst ,7. Clean energy ,law.invention ,Metal ,chemistry.chemical_compound ,Polylactic acid ,law ,0202 electrical engineering, electronic engineering, information engineering ,chemistry.chemical_classification ,Renewable Energy, Sustainability and the Environment ,Microbial electrosynthesis ,CO₂ conversion ,Polymer ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Cathode ,Fuel Technology ,chemistry ,Chemical engineering ,visual_art ,Electrode ,visual_art.visual_art_medium ,lipids (amino acids, peptides, and proteins) ,0210 nano-technology ,Faraday efficiency - Abstract
In this study, CO₂ conversion to acetate and CH₄ was achieved in a flow-through laboratory-scale microbial electrosynthesis (MES) cell composed of a 3D conductive polylactic acid (cPLA) lattice cathode with electrodeposited metal electrocatalyst coatings. The MES cell with a bare cPLA cathode showed the poorest performance with the lowest H₂ and CH₄ production rates and low Coulombic efficiency. This was ascribed to a poor electrocatalytic activity of cPLA towards H₂ production and high electrode resistivity. When the cPLA electrode was modified with metal coatings, the CH₄, acetate and H₂ production rate increased significantly, with the following trend: cPLA < Ni < NiFe < NiFeMn. The better performance of the metal-coated cPLA in terms of CH₄ production was attributed to the lower electrical resistance, enhanced H₂ production and enhanced electron transfer between the cathode and the biofilm. At the cell potential of 2.8 V, the best-performing NiFeMn cPLA cathode showed stable production of CH₄ (50 ± 6 mL d⁻¹), acetate (185 ± 27 mg d⁻¹), and H₂ (545 ± 175 mL d⁻¹) at close to 100% Coulombic efficiency.
- Published
- 2023