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Improvement of thermal conductivity of polymer present a key to realizing efficient thermal transport used for various applications remains a long-standing challenge. In fact, we investigate the effect of TBPO-capped CdSe nanoparticles concentration on Thermal properties in Poly (3-hexylthiophene) (P3HT) thin films. We employed photothermal deflection technique PTD for thermal conductivity and diffusivity determination. Thermal conductivity and diffusivity were determined by fitting theoretical amplitude and phase of PTD signal to the experimental ones. We remark that thermal diffusivity D decreased for 3.52– 0.23 m2/s as function of CdSe nanoparticles concentration (NPs) in P3HT. However, thermal conductivity K increases for 1.78– 3.18 W/m.K as respect of CdSe nanoparticles concentration in P3HT. High thermal conductivity and lower thermal diffusivity are obtained for 40% TBPO-capped CdSe concentration in P3HT sample. [ABSTRACT FROM AUTHOR]

Diurnal and seasonal variations in soil and surface temperature measured with the HP3 ${\mathrm{H}\mathrm{P}}^{3}$ thermal probe and radiometer of NASA's InSight Mars mission are reported. At a representative depth of 10–20 cm, an average temperature of 217.5 K was found, varying by 5.3–6.7 K during a sol and by 13.3 K during the seasons. From the damping of the temperature variation with depth and the phase shift, a thermal diffusivity of (3.93 ± $\pm $ 0.39) × 10−8 ${10}^{-8}$m2 ${\mathrm{m}}^{2}$/s was derived for the upper ∼ ${\sim} $10 cm from the diurnal temperature variation and of (3.63 ± $\pm $ 0.53) × 10−8 ${10}^{-8}$m2 ${\mathrm{m}}^{2}$/s for the ∼ ${\sim} $40 cm depth range of the mole from the annual temperature variation. Using published thermal conductivity and inertia values together with the diffusivities, soil densities of 1,470 and 1,730 kg/m3 ${m}^{3}$ were derived for these depths. The temperatures allow the deliquescence of thin films of brine, the efflorescence of which may explain the cemented duricrust observed. Plain Language Summary: Temperature is an important factor in understanding the physical properties of Martian soil. It determines how quickly physical processes and chemical reactions occur, including the transport of heat and materials. Temperature is crucial to astrobiology because it affects the habitability of the soil and the potential for water or brine to support microbial life. We measured the temperature in the soil during several Martian days and over a Martian year using the NASA InSight Mars mission's Heat Flow and Physical Properties Package. The average temperature was −56°C (217.5 K) over the depth extent of the thermal probe, which was about 40 cm. The temperature varied by 5–7° during the day, which is only a tenth of the daily surface temperature variation. It varied by 13° during the seasons. The temperature is subfreezing for water, but it allows the formation of thin films of salty brine for 10 hr or more during a Martian day. The solidification of the brine is a likely explanation for the observed few tens of centimeters thick duricrust, a layer of consolidated, cohesive sand, which is thought to have hampered the penetration to greater depth of the mission's thermal probe. Key Points: We measured the temperature and its diurnal and annual variations in the top 40 cm of the Martian soil at the InSight landing siteThe soil thermal diffusivity was calculated from the diurnal and seasonal surface and soil temperature variationsThe soil temperature allows the formation of thin films of brine; their efflorescence may explain the formation of the observed duricrust [ABSTRACT FROM AUTHOR]

This work addresses the problem of obtaining of Ca 3 Co 4 O 9+δ -based ceramics with enhanced thermoelectric performance. Phase-inhomogeneous layered calcium cobaltite ceramics with cationic nonstoichiometry were prepared by solid-state reactions method and a field assisted sintering technology (FAST). Comprehensive experimental characterizations were conducted on the prepared bulk samples, focusing on their phase composition, as well as thermal (including thermal expansion, thermal diffusivity, and thermal conductivity), electrical (encompassing electrical conductivity and the Seebeck coefficient), and functional properties (such as power factor and figure-of-merit). The FAST technique allowed to obtain ceramics with low porosity and high electrical conductivity, which increased as the Ca:Co ratio within the samples decreased, while sample phase inhomogeneity considerably increased the Seebeck coefficient. The best thermoelectric performance was demonstrated for cationic nonstoichiometric Ca 3 Co 4.4 O 9+δ , which power factor and figure-of-merit values at 825 °C reached 427 μW⋅m−1⋅K−2 and 0.146, respectively. • Ca 3 Co 4 O 9+δ -based ceramics prepared by field assisted sintering technology possessed low porosity and high conductivity. • Electrical conductivity of bulk samples increased at decreasing Ca:Co ratio. • Phase inhomogeneity of prepared ceramics increased the Seebeck coefficient. • Ca 3 Co 4.4 O 9+δ ceramics showed the best thermoelectric performance. [ABSTRACT FROM AUTHOR]

Thermal and electrical properties were investigated for five nominally phase‐pure high entropy carbide ceramics. The compositions (Hf0.2Nb0.2Ta0.2Ti0.2Zr0.2)C, (Cr0.2Hf0.2Ta0.2Ti0.2Zr0.2)C, (Hf0.2Mo0.2Ta0.2Ti0.2Zr0.2)C, (Hf0.2Ta0.2Ti0.2W0.2Zr0.2)C, and (Hf0.2Mo0.2Ti0.2W0.2Zr0.2)C were synthesized by carbothermal reduction of oxides. The thermal diffusivity and heat capacity were measured from room temperature to 1800°C. The room temperature thermal conductivity ranged from 5.1 W/mK for (Hf0.2Mo0.2Ti0.2W0.2Zr0.2)C to 9.0 W/mK for (Cr0.2Hf0.2Ta0.2Ti0.2Zr0.2)C. The thermal conductivity increased over the temperature range with maximum conductivities of 19.6 W/mK measured for (Hf0.2Mo0.2Ta0.2Ti0.2Zr0.2)C to 29.7 W/mK for (Cr0.2Hf0.2Ta0.2Ti0.2Zr0.2)C at 1800°C. The electron contribution to thermal conductivity calculated from measured electrical resistivity varied from 41% to 52% of the total thermal conductivity. The tungsten and molybdenum containing compositions had higher phonon contributions while the niobium and chromium containing compositions had nearly equal electron and phonon contributions to thermal conductivity. [ABSTRACT FROM AUTHOR]

The thermophysical properties of molten salts promising for the nuclear industry are crucial, but the available data are limited and contradictory. The thermal diffusivity of the molten mixtures (NaF-KF)eut–UF4 containing 30, 40, and 50 mol % UF4 was measured by the laser flash method. The thermal diffusivity was found to be almost independent of temperature in the range of about 100° (1070 K–1170 K), which makes it possible to extrapolate values to low or high temperatures. The thermal conductivity of the molten mixtures (NaF-KF)eut–UF4 was calculated using the thermal diffusivity, density, and heat capacity data. Density was estimated using the molar volume of the molten binary systems NaF-UF4 and KF-UF4. The heat capacity of the ternary system NaF-KF-UF4 was evaluated based on the heat capacity of individual salts, taking into account the additivity law. The thermal conductivity of the molten mixtures 0.7(NaF-KF)eut–0.3UF4, 0.6(NaF-KF)eut–0.4UF4, and 0.5(NaF-KF)eut–0.5UF4 changes slightly with the UF4 content and temperature; for example, at 1123 K it is 0.48, 0.45, and 0.45 W·m−1·K−1, respectively. The thermal diffusivity of the pure molten UF4 was estimated using three independent approaches: the concentration, the temperature, and the volume dependences of the thermal diffusivity. The estimated value of the thermal diffusivity for the molten UF4 was about 0.12 × 10–6 ± 0.05 × 10–6 m2·s−1. [ABSTRACT FROM AUTHOR]

The miniaturization and high-power density of modern electronic devices pose significant thermal management issues, particularly affecting their performance and lifetime. Ladder-like polysilsesquioxanes (LPSQs) offer a promising solution due to their remarkable thermal, mechanical, and chemical properties. By incorporating thermally conductive fillers, LPSQ composites can achieve high thermal conductivity (TC), making them ideal for thermal management in advanced electronic applications. In this study, LPSQ-based nanocomposites containing functionalized alumina nanoparticles were prepared by solution casting and UV curing, and the effects of varying amounts of Irgacure-184 photoinitiator on their structural and thermal properties were investigated. Three sets of samples were prepared with a fixed amount of LPSQs, 80 wt.% of nanoparticles, and 1, 5, or 10 wt.% of photoinitiator with respect to the matrix. TC was evaluated from the measured values of heat capacity, density, and thermal diffusivity. TC values increased by 60%, 71.2%, and 93.1% for the three samples, respectively, compared to the neat matrix. Results indicate that an intermediate amount of photoinitiator (5%) preserved LPSQs' structural integrity, namely the presence of long linear silsesquioxane chains, and provided good filler dispersion and distribution, high polymerization degree, thermal stability, and high TC. [ABSTRACT FROM AUTHOR]

The thermophysical properties of molten salts promising for the nuclear industry are crucial, but the available data are limited and contradictory. The thermal diffusivity of the molten mixtures (NaF-KF)eut–UF4 containing 30, 40, and 50 mol % UF4 was measured by the laser flash method. The thermal diffusivity was found to be almost independent of temperature in the range of about 100° (1070 K–1170 K), which makes it possible to extrapolate values to low or high temperatures. The thermal conductivity of the molten mixtures (NaF-KF)eut–UF4 was calculated using the thermal diffusivity, density, and heat capacity data. Density was estimated using the molar volume of the molten binary systems NaF-UF4 and KF-UF4. The heat capacity of the ternary system NaF-KF-UF4 was evaluated based on the heat capacity of individual salts, taking into account the additivity law. The thermal conductivity of the molten mixtures 0.7(NaF-KF)eut–0.3UF4, 0.6(NaF-KF)eut–0.4UF4, and 0.5(NaF-KF)eut–0.5UF4 changes slightly with the UF4 content and temperature; for example, at 1123 K it is 0.48, 0.45, and 0.45 W·m−1·K−1, respectively. The thermal diffusivity of the pure molten UF4 was estimated using three independent approaches: the concentration, the temperature, and the volume dependences of the thermal diffusivity. The estimated value of the thermal diffusivity for the molten UF4 was about 0.12 × 10–6 ± 0.05 × 10–6 m2·s−1. [ABSTRACT FROM AUTHOR]

This study investigated the thermal properties of autoclaved aerated concrete (AAC) wall sections constructed with distinct mortars. Within the scope of the study, four distinct wall sections of 25x25x5cm dimensions were created using AAC special adhesive mortar, cement mortar, lime mortar and cement-lime mortar. The thermal conductivity(ρEXP) that was determined by the heat flow meter (HFM) method and bulk density(ρEXP) of each wall section was determined in the laboratory. Specific heat values(cEXP) of mortars and aerated concrete material were determined experimentally in the study. The thermal diffusivity value(aEXP), thermal effusivity value(eEXP) and volumetric heat capacity (VHCEXP) of each wall sample were calculated using the experimental data obtained in the laboratory. In addition, aTEO, eTEO and VHCTEO of each wall sample were calculated theoretically using the thermal conductivity, bulk density and specific heat value given in the literature and standards for the same wall sections. In the study, experimental data was compared to the theoretical data. As a result, the thermal properties of walls constructed with distinct mortars and thermal differences formed in the walls due to the effect of these mortars could be determined with experimental data. However, it was observed that theoretical data were insufficient to detect these thermal differences. [ABSTRACT FROM AUTHOR]

Lunar meteorites are the most diverse and readily available specimens for the direct laboratory study of lunar surface materials. In addition to informing us about the composition and heterogeneity of lunar material, measurements of their thermo‐physical properties provide data necessary to inform the models of the thermal evolution of the lunar surface and provide data on fundamental physical properties of the surface material for the design of exploration and resource extraction hardware. Low‐temperature data are particularly important for the exploration of low‐temperature environments of the lunar poles and permanently shadowed regions. We report low‐temperature‐specific heat capacity, thermal conductivity, and linear thermal expansion for six lunar meteorites: Northwest Africa [NWA] 5000, NWA 6950, NWA 8687, NWA 10678, NWA 11421, and NWA 11474, over the range 5 ≤ T ≤ 300 K. From these, we calculate thermal inertia and thermal diffusivity as functions of temperature. Additionally, heat capacities were measured for 15 other lunar meteorites, from which we calculate their Debye temperature and effective molar mass. [ABSTRACT FROM AUTHOR]

Accurate measurement of thermal properties in thin films is crucial for optimizing devices and deepening our understanding of heat transfer at nano and micro scales. This study presents a combined experimental and computational investigation on a chip-integrated technique for the assessment of in-plane thermal properties of thin films. This method stands out by incorporating inherent error cancelation to lessen the impact of radiative heat loss and allows simultaneous, independent determination of both thermal conductivity and diffusivity through straightforward linear fittings from the same dataset, reducing error propagation. We examine an 84 nm thick SiNx membrane over a temperature range from 100 K to nearly 500 K, aligning with previous studies. Further investigations into a conducting polymer film post-doping demonstrate a notable increase in both thermal conductivity and diffusivity, corroborating scanning thermal microscopy observations, confirming the technique's efficacy and reliability. [ABSTRACT FROM AUTHOR]

This experimental study aimed to investigate the potential control of microstructural-mineralogical characteristics on thermal properties and its relation with the deformational behaviour in mild to high temperature (25°–800°C) regime of coal-bearing sandstone from an underground coal mine fire region. Barakar sandstone from Jharia Coalfield, India, one of the world's largest underground coal mine fire regions, was chosen. The thermal parameters and their relations to the mineralogical, microstructural, and damage characteristics of Barakar sandstone have been discussed. Thermal conductivity (λ), thermal diffusivity (κ), and specific heat capacity (Cp) of heat-treated samples were determined using the transient plane source method. Additionally, detailed petrography, scanning electron microscopy, and electron probe micro-analyser were used to understand the thermal effect on mineralogy and microstructures. The deformational behaviour with elevated temperature was investigated through the universal testing machine. The obtained results suggest three characteristic temperature regimes: mild temperature regime (25°–300°C), transitional temperature regime (300º–500°C) and high temperature regime (500º–800°C). Moreover, prediction models for thermal properties have also been developed using multi-gene genetic programming (MGGP), considering physical properties as input parameters. In view of experimental constraints to determine the thermos-elastic properties of a rock due to tedious experimental processes, the proposed prediction models shall be very useful to indirectly estimate the thermal properties of sandstone rocks using easily determined physical parameters. The outcome of the present study may be useful to understand the subsidence induced by underground coalmine fire, which is a distressing issue in the Jharia region due to persistent coalmine fire. [ABSTRACT FROM AUTHOR]

In this study, the thermal characterisation of natural rock samples from Zimbabwe for low‐temperature industrial thermal energy storage (TES) applications was carried out. Thermal stability, specific heat capacity, thermal diffusivity, thermal conductivity and density were determined. Variations in these parameters were evaluated and their impact on thermal storage performance was analysed. Basalt and dolerite samples from different locations were found to have average specific heat capacities of 826 and 853 J/kg K, respectively, at room temperature. Insignificant variations were observed with differences of 3.4% for basalt and 1.7% for dolerite samples. Also, negligible differences of 0.3% and 0.7% in densities for rocks of the same type but of different origins were obtained for basalt and dolerite samples, respectively. However, significant variations in thermal diffusivity of all the igneous and metamorphic samples were observed with quartzite rock exhibiting the highest value of 2.1 × 10−6 m2/s, while the values for the other samples range from 0.9 × 10−6 to 1.6 × 10−6 m2/s. This implies that the thermal efficiency of sensible TES systems that use different or the same rock types from different locations can be significantly high to be overlooked. Thermo‐gravimetric analysis results revealed that the rock samples studied have good thermal stability for low‐temperature heat storage applications. [ABSTRACT FROM AUTHOR]

The thermal properties of major minerals play a key role in understanding the internal dynamic mechanism and thermal evolution of the Earth and rocky planets. In this study, we first investigated the effect of Fe on the thermal conductivity (κ) and the thermal diffusivity (D) of orthopyroxene at 1–3 GPa and 293–873 K by the transient plane source method. The κ and D both decrease with increasing temperature and decreasing pressure. With increasing Fe content, the two parameters both quickly decrease from the beginning and then slack off. We further modeled the thermal evolution of S‐type asteroids, which strongly depends on the composition model and the dimension of the planet. Combining the present data with surface heat flow and heat production, the lunar's geotherm until 1,400 km is constructed. The core‐mantle boundary temperature of the Moon is refined from 1,883 to 1,754 K. Plain Language Summary: The thermal state and the thermal evolution of rocky planets are strongly influenced by the thermal properties of the major constituent minerals. Orthopyroxene is one of such minerals for rocky planets (e.g., S‐type asteroids and moon). The Fe content can potentially affect the thermal properties of orthopyroxene. However, there are no relevant studies up to now. In this study, we systematically measured the thermal conductivity and the thermal diffusivity of pyroxene with variable Fe content at high temperature and high pressure. Our research shows that the thermal conductivity and the thermal diffusivity of orthopyroxene decrease with increasing Fe content. Adopting the results of this study, we simulate the thermal evolution of S‐type asteroids with different compositions and dimensions and construct the lunar's geotherm until the core‐mantle boundary. Key Points: Both the thermal conductivity and the thermal diffusivity of orthopyroxene decrease with temperature and increase with pressureThe thermal conductivity and the thermal diffusivity of orthopyroxene quickly decrease with iron contentThe thermal evolutions of S‐type asteroids are first simulated and the thermal structure of the lunar interior until the CMB is constrained [ABSTRACT FROM AUTHOR]

The use of iron waste in concrete is now of considerable importance, mainly because of the benefits for the environment and for improving the strength of concrete. The increased and unused of this industrial byproducts represents a challenge for the environment and human health. This article experimentally explores the influence of utilizing iron powder waste and iron fibers in concrete in order to enhance the thermophysical properties of concrete and reduce the environmental impact resulting from iron waste. The aim of this work is to study the thermophysical properties (thermal conductivity, volumetric heat capacity, thermal diffusivity and thermal effusivity) of concrete with waste iron powder and iron fibers for application in building construction. The iron powder waste was added to the concrete with different percentages of 0%, 5%, 15%, 20% and 25% respectively as a partial replacement of sand. The iron fibers were added with mix proportions including 1.0%, 1.5%, 2.0% and 2.5% by volume of concrete, and in two different arrangements, uniform and random. The thermal conductivity and the volumetric heat capacity of these samples were measured experimentally in the dry state at ambient temperature (20 °C), and at 28 days of age. The effect of the integration of iron powder and fiber on thermal properties was analysed. [ABSTRACT FROM AUTHOR]

Clinochlore is a major hydrous mineral in subduction zones, and its thermophysical properties at high temperature and pressure are critical to the thermal structures of subduction zones. Here, we used the pulse heating method to measure thermal diffusivity and thermal conductivity of clinochlore at 0.5-4.0 GPa and 298-1373 K. Our results indicate that upon heating, thermal diffusivity and thermal conductivity decrease from ~9.6 x 10-7 m² s-1 to 4.3 x 10-7 m² s-1 and from ~3.5 W m-1 K-1 to 1.9 W m-1 K-1, respectively, before dehydration, but this trend is reversed after dehydration. In general, the pressure derivatives for the thermal transport properties also decrease with temperature before dehydration. Lattice heat transfer is the dominant mechanism before dehydration, but fluid is involved after dehydration. Using our experimental data, we simulated the temperature distribution of subducting slabs containing clinochlore at volume fractions of 0%, 10%, 20%, 50%, and 100%. Our simulations showed that the heat insulation effect caused by the presence of clinochlore could result in an increase in temperature by 30-60 K for the upper part of the subducting slab. [ABSTRACT FROM AUTHOR]

This study investigates a sustainable coating method for modified expanded polystyrene (MEPS) beads to improve the thermal insulation of lightweight concrete intended for wall application. The method employed in this study is based on a novel coating technique that represents a significant advancement in modifying Expanded Polystyrene (EPS) beads for enhanced lightweight concrete. This study experimentally assessed the energy-saving capabilities of MEPS concrete in comparison to control groups of uncoated EPS beads and normal concrete by analysing early-stage temperature, thermal conductivity, specific heat capacity, heat flux, and thermal diffusivity. The thermal conductivity of MEPS concrete is approximately 40% lower than that of normal concrete, demonstrating its usefulness in enhancing insulation. The heat flux calculated for MEPS concrete is significantly reduced (approximately 35%), and it has a 20% lower specific heat capacity than ordinary concrete, indicating a reduction in energy transfer through the material and, thus, potential energy-efficiency benefits. Furthermore, the study discovered that all test objects have very low thermal diffusivity values (less than 0.5 × 10−6 m2/s), indicating a slower heat transport through the material. The sustainable coating method utilized fly ash-enhanced thermal efficiency and employed recycled materials, hence decreasing the environmental impact. MEPS concrete provides a practical option for creating sustainable and comfortable buildings through the promotion of energy-efficient wall construction. Concrete incorporating coated EPS can be a viable option for constructing walls where there is a need to balance structural integrity and adequate insulation. [ABSTRACT FROM AUTHOR]

Current highly integrated devices require heat interface materials with excellent heat conductivity. A simple approach was employed to synthesize thermally conductive and outstanding thermal stability nanocomposite. Calcium carbonate nanoparticles (nano CaCO 3) reinforced with reduced graphene oxide (rGO) nanoparticles (rGO/CaCO 3) are synthesized using a novel process, and the effect of rGO in CaCO 3 structure is examined by Field Emission Scanning Electron Microscope, X-ray diffraction, TGA-DTA, and thermal conductivity. The experimental results show that adding rGO resulted in higher crystallinity and thermal stability. As the wt.% of rGO increases from 1 to 5%, the crystallite size was suppressed by 21.06%, 27.39%, 32.48%, 41.5%, and 45.30%, respectively, compared to the pure nano-CaCO 3. Additionally, rGO enhances the thermal conductivity by 35.31% and thermal diffusivity to 1.834 mm2/s by adding 5% rGO. [ABSTRACT FROM AUTHOR]

The thermodynamic and kinetic simulations based on the re-assessment of the thermodynamic and kinetic database of the Ni-Ti-Cu system were employed to predict the phenomena of mechanical alloying, spark plasma sintering and thermal properties of the intriguing Ni-Ti-Cu system. Thermodynamic calculations are presented for the stable and unstable phases of NiTiCu materials and support a correlation with the evolving microstructure during the technological process. Also, the thermal conductivity, the thermal diffusivity and the specific heat of spark plasma sintered and aged Cu-alloyed NiTi-based shape memory alloys (NiTiCu) with two compositions, Ni45Ti50Cu5 and Ni40Ti50Cu10, are evaluated and the influence of mechanical alloying and precipitates on thermal properties is discussed. Measurements of these thermal properties were carried out from 25 °C up to 175 °C using the laser flash method, as well as differential scanning calorimetry. The thermal hysteresis of the 20 mm diameter samples was between 8.8 and 24.5 °C. The observed T0 temperatures from DSC experimental transformation features are in reasonable accordance with the thermodynamic predictions. The determined k values are between 20.04 and 26.87 W/m K and in agreement with the literature results. Moreover, this paper can provide some suggestions for the preparation of NiTiCu shape memory alloys and their applications. [ABSTRACT FROM AUTHOR]

In the present work, a metal–matrix composite was casted using the LM13 aluminum alloy, which is most widely used for casting automotive components. Such applications require materials to withstand high operating temperatures and perform reliably without compromising their properties. In this regard, particulate-reinforced composites have gained widespread adaptability. The particulate reinforcements used comprise of one of the widely available industrial by-products. which is fly ash, along with the abundantly available quartz. Hybrid composites are fabricated through the economical liquid route that is widely used in mass production. Though there are numerous published research articles investigating the mechanical properties of metal–matrix composites, very few investigated the thermal properties of the composites. In the present work, thermal properties such as thermal conductivity and thermal diffusivity of cast hybrid composites were evaluated. The particulate reinforcements were added in varied weight percentages to the molten LM13 alloy and were dispersed uniformly using a power-driven stirrer. The melt with the dispersed particulate reinforcements was then poured into a thoroughly dried sand mold, and the melt was allowed to solidify. The quality of the castings was ascertained through density evaluation followed by a microstructural examination. It was found that the composites with only the fly ash particles as a reinforcement were less dense in comparison to the composites cast with the quartz particulate reinforcement. However, the hybrid composite, with both particulate reinforcements were dense. The microstructure revealed a refined grain structure. The thermal diffusivity and thermal conductivity values were lower for the composites cast with only the fly ash reinforcement. On the other hand, the composites cast with only quartz as the particulate reinforcement exhibited higher thermal diffusivity and thermal conductivity. The specific heat capacity was found to be lower for the fly ash-reinforced composites and higher for the quartz-reinforced composites in comparison to the LM13 base matrix alloy. However, the highest value of thermal diffusivity and thermal conductivity were reported for the hybrid composites with a 10 wt.% inclusion of both fly ash and quartz particulate reinforcements. [ABSTRACT FROM AUTHOR]

The efficiency, durability, and overall performance of a car engine are influenced by several critical factors. The quality and properties of engine oil play a crucial role, and oil is used in internal combustion engines for lubrication and cooling purposes. This research study aimed to compare the impact of fullerene-C60 (99.5%), Fe2O3, and TiO2 nanoparticles on the thermal properties of C.A.L.T.E.X. red engine oil with grades 10W30, 20W40, and 20W50. This study focused on the effect of a nanoparticle concentration of 0.01 wt.% in different engine oil grades at various temperature values of 30–120 °C. The nanofluids were prepared using the two-step direct mixing method, employing a magnetic stirrer and an ultrasonicator, ensuring uniform distribution of nanoparticles in the base fluids. The thermal conductivity, thermal diffusivity, and volumetric heat capacity of the base fluids and nanofluids were measured using the FLUCON LAMBDA thermal conductivity meter. Additionally, flash points were measured using the flash point tester. It was concluded that the thermal properties of TiO2 and Fe2O3 showed considerable enhancement; in contrast, fullerene only showed a 212 °C flash point. [ABSTRACT FROM AUTHOR]

Today, the construction sector consumes 30-40% of the world's total energy and contributes one-third of total greenhouse gas emissions. Consequently, the development of new eco-friendly building materials with improved properties is becoming increasingly important. Olive pomace waste is released into the environment, which has a negative impact on it. Recycling this olive pomace waste as an alternative raw material in the construction industry can protect the environment and at the same time reduce the additional costs of managing and disposing of this waste for local authorities. It is an environmentally friendly and sustainable solution to waste recycling. This study investigated the effect of adding olive pomace (OP) to building materials. Four proportions of this additive (4%, 8%, 12% and 16%) were used. Physical, thermal properties (conductivity and diffusivity) as well as mechanical properties (compressive and flexural strength) of the composites were carried out. The traditional gypsum-based composites had a thermal conductivity of 0.478 W.m-1.K-1, while the composites of gypsum with additive show an interesting thermal conductivity of 0.390 W.m-1.K-1 for a percentage of 16% (OP16) with a reduction rate of 22.56%, and mechanical properties lower than those of the reference gypsum-based composite but in accordance with the standard EN 133279-1, with compressive strength of almost 4.10MPa for a percentage of 16% (OP16), and flexural strength equal to 2MPa. This is due to the increase in porosity as indicated by the microstructure of the composites. We also tested water absorption by capillary action for each specimen, and found that this coefficient increased with increasing percentage of waste. [ABSTRACT FROM AUTHOR]

Graphite films are frequently used in the thermal interface materials (TIM) of thermal dissipation due to its high thermal conductivity. However, accurately measuring the thermal diffusivity of graphite films requires careful consideration of key parameters. In this study, four typical graphite films were analyzed to identify these parameters. The results revealed that pulse width was the most important parameter in accurately measuring thermal diffusivity. Specifically, when the pulse width was less than 1.8% of the half-heating time, thermal diffusivity measurements were more accurate. Conversely, when the pulse width exceeded 1.8% of the half-heating time, heating curves were affected, resulting in a gradual decrease in thermal diffusivity. Additionally, pulse voltage had little effect on thermal diffusivity measurements. These findings provide important guidance for accurately characterizing the thermal properties of graphite films and can inform the accurate measurement and development of efficient thermal interface materials. [ABSTRACT FROM AUTHOR]

Binary blends of unsaturated polyester (70%) and nitrile rubber (NR) (30%) and their composites are prepared. Zinc oxide nanoparticles (ZnONPs) were used as a filler in the hand-lay method. ZnONP weight ratios ranged from 0 to 3 wt.%. The ZnONPs were characterised using techniques such as X-ray diffraction (XRD) and scanning electron microscopy (SEM) to examine their crystalline structure and shape. The thermal and dielectric properties of the samples were examined as a function of filler content. Additionally, the theoretical and experimental densities of the nanocomposites were examined using the mixing rule and Archimedes’ principle, respectively. The thermal conductivity and diffusivity values exhibited variations between increasing and decreasing trends as the filler concentrations increased. Among all samples tested, the one containing 2.5% ZnONPs demonstrated the highest thermal conductivity and the lowest diffusivity when compared to the pure blend. As the ZnONP weight ratio increased, the corresponding dielectric constant value rose linearly, while the resistivity decreased linearly. Thermogravimetric analysis (TGA) revealed a significant improvement in the level of char yield and thermal stability of nanocomposites with increasing ZnONP concentration in the matrix. [ABSTRACT FROM AUTHOR]

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This study investigated the influence of fiber content, temperature, and relative humidity on the thermal insulation properties of nonwoven mats made of seed fibers from Asclepias Syriaca, commonly known as milkweed floss. Nonwoven mats with a 1-inch thickness were produced by uniformly arranging milkweed fibers within a mold. Various quantities of fiber were employed to obtain nonwoven mats with a fiber content ranging from 5 to 35 kg/m3. Thermal conductivity and thermal diffusivity were measured across diverse relative humidity levels and temperatures. Simultaneously, milkweed floss samples were exposed to identical environmental conditions to assess the moisture regain and specific heat capacities of the fiber. The specific heat capacity of milkweed and thermal conductivity of the nonwovens exhibited a linear increase with temperature. The thermal diffusivity and thermal conductivity of the nonwovens decreased with rising fiber content. The thermal insulation properties of the nonwovens remained partially stable below 30% relative humidity but substantially deteriorated at higher levels. The nonwovens exhibited optimal thermal insulation properties at a fiber content between 20 and 25 kg/m3. The results of this study highlighted several technical advantages of employing milkweed floss as a sustainable and lightweight solution for thermal insulation. [ABSTRACT FROM AUTHOR]

The thermal properties of the aluminum EN AW-2024 alloy (duralumin) delivered in the T3 condition (solution annealed, quenched, cold-deformed, and naturally aged) were experimentally investigated using differential thermal analysis (DTA), differential scanning calorimetry (DSC), and light flash apparatus (LFA) for thermal diffusivity and thermal conductivity evaluation. The microstructure of the alloy in the initial state and after heating to 400?C was investigated by scanning electron microscope (SEM) and energy-dispersive spectroscopy. The presence of an exothermic thermal effect in the temperature range from 230 to 283?C during the first heating of the examined sample was determined by the results of DTA/DSC analysis. The thermal diffusivity of the investigated alloy was measured in the temperature range from 25 to 400?C using three heating runs. During the first heating, the thermal diffusivity of the investigated alloy increased with an increase in temperature up to approximately 300?C, after which it decreased. During the second and third heating, it was observed that the measured thermal diffusivity values at temperatures lower than 300?C were significantly higher than during the first heating, and the thermal diffusivity gradually decreased with increasing temperature in the entire investigated temperature range. Experimentally determined thermal diffusivity and density, as well as calculated specific heat capacity data, were used to determine the thermal conductivity of the studied alloy in the temperature interval from 25 to 400?C. The obtained results indicate that initial heating to a temperature above 300?C causes a significant increase in the values of the thermal diffusivity and thermal conductivity of the investigated 2024-T3 alloy. [ABSTRACT FROM AUTHOR]

This paper reports an experimental investigation of the thermal properties of frozen tap, demineralized, and sea water. The presented research assists in a better understanding of the thermal properties of ice and the processes within it and contributes regarding the generation of novel experimental data. The thermal conductivity was measured in a range from −14 °C to −33 °C using the Transient Plane Source (TPS) method. Ice blocks were placed in an expanded polystyrene box in the freezer, which is where the measurements took place. The thermal conductivity of the tap water ice was observed to vary in a range from 1.915 ± 0.005 Wm−1K−1 at −14 °C to 2.060 ± 0.004 Wm−1K−1 at −33 °C. The values obtained for the ice made of demineralized water differed by less than 10%. The thermal conductivity of the sea ice was shown to be more temperature dependent, with the values ranging from 1.262 ± 0.005 Wm−1K−1 at −14 °C to 1.970 Wm−1K−1 ± 0.004 at −33 °C. A noticeable fall in the thermal conductivity of the sea ice was observed in the temperature range from −26 °C to −19 °C. A possible reason for this could be the increased precipitation of salt in that temperature range. Measurements of thermal diffusivity displayed similar trends as those of thermal conductivity. Specific volumetric heat capacity was indirectly calculated. [ABSTRACT FROM AUTHOR]

Fused Filament Fabrication (FFF) is a 3D‐printing technique that enables the production of complex geometries with a high level of customization at low cost. The poor mechanical properties of FFF‐printed parts often undermine the application of this technology for structural purposes. To overcome this limitation, a two‐step metallization method is performed to deposit a copper layer on the exterior of an Acrylonitrile–Butadiene–Styrene (ABS) substrate, using a non‐toxic and cost‐effective plating solution. Electroplating over the exposed grid infill, at various densities, is exploited to improve the load transfer between copper and ABS. The resulting samples are characterized mechanically and thermally, and finite element modeling simulations are used to better understand the characterization results. It is found that an infill of 50–60% provides the best compromise between mechanical performance and thermal conductivity because the infill density is low enough to allow copper penetration into the material to create a strong mechanical interlocking with ABS, yet high enough to create multiple conductive bridges through the thickness of the sample. This study demonstrates the effectiveness of electroplating as a post‐processing technique to simultaneously enhance the mechanical and thermal properties of FFF‐printed parts and provides insights into the optimal design parameters for achieving this goal. [ABSTRACT FROM AUTHOR]

Magnesium aluminate (MA) spinel has shown potential as a refractory material under harsh environments, such as high temperatures and frequent temperature variations. However, understanding the mechanical and thermal properties of MA spinel is a key step towards further improvement of MA spinel refractory materials in high-temperature fields. The formation of solid solution represents a prominent strategy to improve mechanical and thermal properties. The present study develops novel (1- x)MgAl 2 O 4 - x Mg 2 TiO 4 (0≤ x ≤ 0.1) solid solutions by single-step reaction sintering method using light-burned magnesia, reactive alumina, and as-prepared Mg 2 TiO 4 (M 2 T) powders. The effects of M 2 T content on the crystal structure, mechanical properties, and thermal properties of the MgAl 2 O 4 -Mg 2 TiO 4 solid solutions (MATss) were studied. Based on XRD, TEM, and HRTEM results, MATss were highly crystallized with a cubic spinel structure. Besides, the M 2 T addition facilitated the flexural strength, hardness, and elastic modulus in the MA spinel. Among these solid solutions, the x = 0.08 sample exhibited the highest flexural strength, hardness, and elastic modulus of 219.47 MPa, 19.99 GPa, and 270.2 GPa, respectively. M 2 T additive played a solid-solution strengthening role, which enhanced the inherent resistance to microstructural damage. Additionally, the x = 0.08 sample had the highest thermal conductivity and thermal diffusivity of 12.45 W/(m·K) and 7.98 mm2/s, respectively. In comparison with pure MA spinel, the x = 0.08 sample showed a lower thermal expansion coefficient (8.63 × 10-6 K-1 at 1550 °C). These excellent mechanical properties and exceptional thermal behavior enabled its widespread application in refractory materials. [ABSTRACT FROM AUTHOR]

The purpose of this study was to analyze the effects of sludge biochar (BC) application (2, 5, 10, 15% w/w) on the physico-chemical and thermal properties (thermal capacity, thermal conductivity and thermal diffusivity) of loess and the mechanism of action. The results showed that the application of BC changed the soil particle size distribution, reduced the soil bulk density, increased the soil total porosity (1.19–11.51%), organic matter content (10.94–85.02%), saturated water content (1.85–7.15%) and field water capacity (0.09–13.00%), and decreased the soil thermal capacity, thermal conductivity and thermal diffusivity, with an average decreasing amplitude of 2.13, 5.45 and 7.54%, respectively. Soil bulk density and water content (<30%) were positively correlated with soil thermal capacity, thermal diffusivity and thermal conductivity. The mechanisms are mainly that the negative impact of changing soil solid composition and increasing total porosity by biochar with low density and thermal parameter values; and the positive effect of raising water content by improving soil water holding capacity. Sludge biochar shows great potential in soil improvement and can realize sludge sustainable management. [ABSTRACT FROM AUTHOR]

Lightweight eco-materials are in high demand in many sectors, such as aerospace, industry, and building due to their several characteristics. The present paper is an experimental investigation of the thermal characteristics of novel sandwich panels made with local and ecological materials namely agglomerated cork for the core and bio-composite materials for the skin. Three configurations (symmetric, asymmetric, and two layers) were studied with different cork core thicknesses. Density values have been measured and compared. Thermal characterization consists of determining thermal conductivity and specific heat using a HFM apparatus; whilst thermal diffusivity and thermal effusivity have been calculated using the experimental findings. The panels are lightweight and thermally insulating. The values of thermal conductivity are in the range 0.071 and 0.102 W.m−1.K−1. The comparison between experimental results of thermal conductivity to theoretical values highlights the accuracy of method for multi-layer thermal characterization and the good adhesion between layers. Finally, a life cycle assessment of the new sandwich panels has been carried out and compared with common insulation materials. The sandwich panels are efficient in terms of embodied energy and CO2 emissions compared to commercialized insulators and some insulators based on recycled or natural materials, the embodied energy for symmetric configuration with 4 cm cork core are 79.73, 94.75, and 89.35 MJ/FU corresponding to an embodied carbon 5.33, 6.32, and 6.01 CO2/FU respectively. They can be classified in the middle between synthetic and natural insulators. Based on the findings, it was concluded that utilizing these sandwich panels as construction materials for interior paneling or partition walls could offer benefits in terms of being environmentally sustainable and cost-efficient. [ABSTRACT FROM AUTHOR]

The effect of moisture absorption and temperature on the thermal properties of dried tigernut was studied. The proximate composition includes moisture content ranging from 0.97% to 6.45%, Ash content from 0.63% to 1.93%, fat from 12.95% to 16.63%, crude fiber from 18.71% to 33.78%, and carbohydrate from 43.58% to 58. 68%. The thermal properties were determined by using the value obtained from the proximate composition and calculated using the Okoi and choi's equation. The value obtained from the thermal properties are thermal conductivity which ranged from 0.28866 w/moc to 0.3562 w/moc, thermal diffusivity ranging from 0.1123m2/s to 0.2172ms/s and specific heat capacity ranging 1.8484 kg/kgoc to 1.9261 kg/kgoc. The percentage moisture absorption capacity was also analyzed in the sample which ranged from 46.6% to 94.4%. Thermal properties refer to the response in their temperature. The result obtained showed that the sample conditioned at 100°C had the highest thermal properties and this implied that the thermal properties of food is generally influenced by moisture, temperature and their proximate composition. Further studies should be carried out on the Rheological properties of tigernut, kinetic rate of reaction of the nutrient with respect to time and the thermal properties should be utilized for the design of equipment and for the mathematical model in terms of simulation and mass heat transfer in the material. [ABSTRACT FROM AUTHOR]

The roasting process of Gari (Gelatinized cassava mash), a shelf-stable cassava product, is energy-intensive. Due to a lack of information on thermal characteristics and scarcity/rising energy costs, heat and mass transfer calculations are essential to optimizing the traditional gari procedure. The objective of this study was to determine the proximate, density, and thermal properties of traditionally processed de-watered cassava mash and gari at initial and final processing temperatures and moisture contents (MCwb). The density and thermal properties were determined using proximate composition-based predictive empirical models. The cassava mash had thermal conductivity, density, specific heat capacity, and diffusivity of 0.34 to 0.35 W m−1 °C−1, 1207.72 to 1223.09 kg m−3, 2849.95 to 2883.17 J kg−1 °C, and 9.62 × 10−8 to 9.76 × 10−8 m2 s−1, respectively, at fermentation temperatures and MCwb of 34.82 to 35.89 °C and 47.81 to 49%, respectively. The thermal conductivity, density, specific heat capacity and diffusivity of gari, ranged from 0.27 to 0.31 W m−1 °C−1, 1490.07 to 1511.11 kg m−3, 1827.71 to 1882.61 J kg−1 °C and 9.64 × 10−8 to 1.15 × 10−8 m2 s−1, respectively. Correlation of all the parameters was achieved, and the regression models developed showed good correlation to the published models developed based on measuring techniques. [ABSTRACT FROM AUTHOR]

The thermal properties of soils can be influenced by additives of different origins (non-organic, organic and mineral) and roles in soil quality. This study aims to evaluate the effects of microplastics, vermicompost, and zeolite on the thermal properties of two soil types using a combination of experimental data and modeling approaches. Laboratory experiments were conducted using surface layer samples of a clay soil (Vertic Phaeozem) and a loam soil (Haplic Cambisol). Each additive was applied at a mass ratio of 10% to the soil samples. The thermal conductivity (λ), thermal diffusivity (D) and volumetric heat capacity (Cv) were measured with the SH1 sensor of a KD2Pro device during the drainage process of the soil samples at different matric potentials. The relationships between λ, Cv, D, gravimetric water content, and matric suction (h) were analyzed using linear and polynomial regression models (for Cv and D) and a closed-form equation (for λ). The fitted models exhibited small errors, such as a root mean square error (RMSE) of 0.03-0.06 W m-1 K-1, and high coefficient of determination R2>0.9. The effects of the different additives on water retention, λ, Cv and D were found to be specific to each soil type and depended on the properties of both the soil and the additives. These findings highlight the significance of additives in modifying soil thermal properties and emphasize the importance of considering the interactions between soil characteristics and additive properties. The combination of experimental data and modeling approaches provides valuable insights into understanding the complex dynamics of soil thermal properties and the potential impacts of additives on soil functionality and quality. [ABSTRACT FROM AUTHOR]

Measurement of thermal properties of thin films is challenging. In particular, thermal characterization is very difficult in semi-transparent samples. Here, we use two photothermal methods to obtain information about the thermal diffusivity as well as thermal conductivity of azoheteroarene functionalized polymer thin layers. The photothermal beam deflection (PBD) method is employed to gather data directly on thermal conductivity and thermal diffusivity, while the thermal lens (TL) method is employed to measure the effective thermal diffusivity. Consequently, the thermal diffusivity of the layers is indirectly estimated from the effective thermal diffusivity using a well-established theoretical relationship. Despite the utilization of distinct methods, our study reveals a remarkable consistency in the highly accurate results obtained from both approaches. This remarkable agreement reaffirms the reliability and mutual compatibility of the employed methods, highlighting their shared ability to provide accurate and congruent outcomes. [ABSTRACT FROM AUTHOR]

Thermal properties such as thermal conductivity, heat capacity, and thermal diffusivity and physical properties such as calorific value, density, and kinematic viscosity of liquid fuels play a significant role in the combustion process. These properties vary with the chemical structures and the fatty acid profiles of biodiesels. Making correlations for various properties with respect to fatty acid profile helps to analyze the combustion process. Most of the reported works generated correlations using data taken from the literature, and the correlations based on the fatty acid profile for thermal properties of biodiesel are unavailable. As coconut oil, sunflower oil, and palm oil have entirely different fatty acid profiles, in this study, biodiesels produced from these three waste cooking oils and their three hybrids (each in a 1:1 ratio) were used for biodiesel production, followed by correlation formulation. Higher thermal conductivity (0.2211 W mK−1) and thermal diffusivity (0.2459 mm2 s−1) and lower heat capacity (0.8993 MJ m−3 K−1), density (862.8 kg m−3), kinematic viscosity (2.71 cSt), and calorific value (36.73 cSt) were observed for coconut-based biodiesels compared with other biodiesels. The addition of coconut content to hybrid biodiesel enhanced thermal conductivity and thermal diffusivity and reduced heat capacity, density, and kinematic viscosity. From the experimental data of thermal conductivity, heat capacity, thermal diffusivity, density, kinematic viscosity, and calorific value, empirical correlations were proposed with the fatty acid profile. Good agreement was obtained between experimental and calculated values. [ABSTRACT FROM AUTHOR]

We show that the centroid molecular dynamics (CMD) method provides a realistic way to calculate the thermal diffusivity a = λ/ρcV of a quantum mechanical liquid such as para-hydrogen. Once a has been calculated, the thermal conductivity can be obtained from λ = ρcVa, where ρ is the density of the liquid and cV is the constant-volume heat capacity. The use of this formula requires an accurate quantum mechanical heat capacity cV, which can be obtained from a path integral molecular dynamics simulation. The thermal diffusivity can be calculated either from the decay of the equilibrium density fluctuations in the liquid or by using the Green–Kubo relation to calculate the CMD approximation to λ and then dividing this by the corresponding approximation to ρcV. We show that both approaches give the same results for liquid para-hydrogen and that these results are in good agreement with the experimental measurements of the thermal conductivity over a wide temperature range. In particular, they correctly predict a decrease in the thermal conductivity at low temperatures—an effect that stems from the decrease in the quantum mechanical heat capacity and has eluded previous para-hydrogen simulations. We also show that the method gives equally good agreement with the experimental measurements for the thermal conductivity of normal liquid helium. [ABSTRACT FROM AUTHOR]

This experimental study aimed to characterize the thermal properties of ex vivo porcine and bovine kidney tissues in steady-state heat transfer conditions in a wider thermal interval (23.2–92.8 °C) compared to previous investigations limited to 45 °C. Thermal properties, namely thermal conductivity (k) and thermal diffusivity (α), were measured in a temperature-controlled environment using a dual-needle probe connected to a commercial thermal property analyzer, using the transient hot-wire technique. The estimation of measurement uncertainty was performed along with the assessment of regression models describing the trend of measured quantities as a function of temperature to be used in simulations involving heat transfer in kidney tissue. A direct comparison of the thermal properties of the same tissue from two different species, i.e., porcine and bovine kidney tissues, with the same experimental transient hot-wire technique, was conducted to provide indications on the possible inter-species variabilities of k and α at different selected temperatures. Exponential fitting curves were selected to interpolate the measured values for both porcine and bovine kidney tissues, for both k and α. The results show that the k and α values of the tissues remained rather constant from room temperature up to the onset of water evaporation, and a more marked increase was observed afterward. Indeed, at the highest investigated temperatures, i.e., 90.0–92.8 °C, the average k values were subject to 1.2- and 1.3-fold increases, compared to their nominal values at room temperature, in porcine and bovine kidney tissue, respectively. Moreover, at 90.0–92.8 °C, 1.4- and 1.2-fold increases in the average values of α, compared to baseline values, were observed for porcine and bovine kidney tissue, respectively. No statistically significant differences were found between the thermal properties of porcine and bovine kidney tissues at the same selected tissue temperatures despite their anatomical and structural differences. The provided quantitative values and best-fit regression models can be used to enhance the accuracy of the prediction capability of numerical models of thermal therapies. Furthermore, this study may provide insights into the refinement of protocols for the realization of tissue-mimicking phantoms and the choice of tissue models for bioheat transfer studies in experimental laboratories. [ABSTRACT FROM AUTHOR]

An improved method to simultaneously determine the heat capacity, thermal diffusivity, and thermal conductivity of a small-sized material is described. In this method, the heat of a square wave with a superimposed constant component is applied to one side of a plate-shaped sample using a thin-film heater, which is thermally linked to a heat reservoir. The response temperature is measured by a thermometer attached to the heater. In contrast to a previously reported method, the amplitude of the temperature oscillation detected by the thermometer is enhanced by the internal thermal relaxation in the improved method. This feature is advantageous for determining thermal properties with low-heat modulation. We theoretically analyzed the proposed method using a one-dimensional model and demonstrated the method on synthetic quartz (SiO2) and poly(methyl methacrylate) plates in the temperature range of 80–300 K. The thermal properties obtained for both samples using the proposed method were consistent with values reported in the literature. The deviations from the data for the specific heat capacity, thermal diffusivity, and thermal conductivity were estimated to be ∼1%, 2%, and 2%, respectively. [ABSTRACT FROM AUTHOR]

In induction heating processes, knowledge of the charge material parameters, i.e., thermal conductivity and volumetric heat capacity, as well as resistivity and magnetic permeability, is important both at the stage of preparatory process simulations and during their implementation. The paper presents a measurement method for estimating the thermal diffusivity, volumetric heat capacity, and resistivity of the charge material as a function of temperature on a single measuring setup, using a generator for induction heating as the source of signals. The method is based on the study (for forced temperature levels) of the temperature responses of cylindrical samples of the test materials and the voltage induced in the designed measuring coil after short- or long-term step excitation impulses. The presented approach enabled the dedicated computer-controlled system to obtain the initial values of the searched parameters with an accuracy of several percent. The procedure constitutes an introductory step in the simultaneous determination of a set of searched characteristics, and, by performing measurements, significantly narrows the range of variability in the decision variables of the optimization process. [ABSTRACT FROM AUTHOR]

High heat fluxes generated in electronics and semiconductor packages require materials with high thermal conductivity to effectively diffuse the heat and avoid local hotspots. Engineered heat spreading materials typically exhibit anisotropic conduction behavior due to their composite construction. The design of thermal management solutions is often limited by the lack of fast and accurate characterization techniques for such anisotropic materials. A popular technique for measuring the thermal diffusivity of bulk materials is the Ångstrom method, where a thin strip or rod of material is heated periodically at one end, and the corresponding transient temperature profile is used to infer the thermal diffusivity. However, this method is generally limited to the characterization of one-dimensional samples and requires multiple measurements with multiple samples to characterize anisotropic materials. Here, we present a new measurement technique for characterizing the isotropic and anisotropic in-plane thermal properties of thin films and sheets as an extension of the one-dimensional Ångstrom method and other lock-in thermography techniques. The measurement leverages non-contact infrared temperature mapping to measure the thermal response from laser-based periodic heating at the center of a suspended thin film sample. Uniquely, our novel data extraction method does not require precise knowledge of the boundary conditions. To validate the accuracy of this technique, numerical models are developed to generate transient temperature profiles for hypothetical anisotropic materials with known properties. The resultant temperature profiles are processed through our fitting algorithm to extract the in-plane thermal conductivities without knowledge of the input properties of the model. Across a wide range of in-plane thermal conductivities, these results agree well with the input values. Experiments demonstrate the approach for a known isotropic reference material and an anisotropic heat spreading material. The limits of accuracy of this technique are identified based on the experimental and sample parameters. Further standardization of this measurement technique will enable the development and characterization of engineered heat spreading materials with desired anisotropic properties for various applications. [ABSTRACT FROM AUTHOR]

Combining the picosecond transient thermoreflectance (ps-TTR) and picosecond laser flash (ps-LF) techniques, we have developed a novel method to simultaneously measure the thermal effusivity and the thermal diffusivity of metal thin films and determine the thermal conductivity ( κ) and the heat capacity ( c v ) altogether. In order to validate our approach and evaluate the uncertainties, we analyzed five different metal films (Al, Cr, Ni, Pt, and Ti) with thicknesses ranging from 297 nm to 1.2 µm. Our results on thermal transport properties and heat capacity are consistent with reference values, with the uncertainties for the thermal conductivity and the heat capacity measurements below 25% and 15%, respectively. Compared with the ps-TTR technique alone, the combined approach substantially lowers the uncertainty of the thermal conductivity measurement. Uncertainty analyses on various materials show that this combined approach is capable of measuring most of the materials with a wide range of thicknesses, including those with low thermal conductivity (e.g., mica) down to thicknesses as small as 60 nm and ultrahigh thermal conductivity materials (such as cubic BAs) down to 1400 nm. Simultaneous measurement of thermal conductivity and heat capacity enables exploration of the thermal physical behavior of materials under various thermodynamic and mechanical perturbations, with potential applications in thermal management materials, solid-state phase transitions, and beyond. [ABSTRACT FROM AUTHOR]

The burgeoning issue of plastic waste, exacerbated by urbanization and pollution, has emerged as a global concern. A novel approach to address this problem involves the recycling of waste plastics and their incorporation into concrete, thereby promoting sustainability and environmental responsibility. This study offers a comprehensive review of the effects of integrating plastic waste into concrete to enhance its thermal properties. The findings reveal that the inclusion of waste plastics considerably reduces the thermal conductivity of concrete, augments its thermal resistance, and optimizes its thermal diffusivity. Moreover, the utilization of plastic waste in concrete yields environmental advantages, such as the mitigation of detrimental impacts on marine and terrestrial ecosystems resulting from plastic pollution. This research contributes to the expanding body of literature on sustainable concrete production and waste plastic recycling, providing valuable insights for the development of eco-friendly construction materials. [ABSTRACT FROM AUTHOR]

In this research work, for the first time, the thermal transport properties of the natural Azerbaijani bentonites (Gobu and Atyali) as well as their Multi-Walled Carbon NanoTube/Gobu and Multi Walled Carbon Nano Tube/Atyali ceramic composites were investigated, their application abilities were studied, and the initial mechanism for explaining the thermal properties of these nanocomposites was studied. A laser flash technique was used to determine the thermal conductivity and thermal diffusivity of the prepared nanocomposites. The nanocomposites were prepared by an irreversible dispersion method that was developed by our research group. The highest thermal conductivity and thermal diffusivity were observed for 16% MWCNT-containing nanocomposites. The highest values of thermal conductivity and thermal diffusivity are κ = 1.3 W·(m·K−1) at T = 498 K, a = 1.539 × 10–6 m2·s−1 at T = 543 K for Gobu/x MWCNT (x = 16%) and κ = 0.97 W·(m·K−1) at T = 473 K, a = 1.013 × 10–6 m2·s−1 at T = 300 K for Atyali/x MWCNT (x = 16%) ceramic composites, respectively, and are mostly limited by phonon scattering within the bundles, by MWCNT and natural bentonite ceramic matrix interfaces, formed structure types of MWCNT networks. Experimental results prove that the cross-bar structure of MWCNTs inside Atyali matrices affects thermal conductivity negatively in comparison to the horizontally aligned structure of MWCNTs inside Gobu matrices. The electrical conductivity of these ceramic nanocomposites was significantly increased (for Gobu/x MWCNT (x = 16%) − 284 S·m−1 and for Atyali/x MWCNT 89.8 S·m−1). As these nanocomposites are electrically and thermally conductive at the same time, they can potentially be used as non-corrosive electrodes for electrolysis processes, as substrates like coolers for electronic devices with less heat release, and as heating elements for coveralls and for heating apartments. [ABSTRACT FROM AUTHOR]

This research aimed to quantify the effects of biochar derived from corn straw on soil thermal conductivity, capacity, and diffusivity. Firstly, the amount of biochar application (w/w) added to light sierozem soil was 0% to 5%, and the mixtures were packed into soil columns at a consistent bulk density (1.20 g.cm-3). Secondly, soil columns with a consistent biochar addition rate (5%) were packed to different bulk densities of 1.30, 1.25, 1.20, 1.15, and 1.10 g.cm-3. Soil thermal characteristics were measured under the control of soil moisture content from 0% to 40%. Under consistent bulk-density conditions, biochar could significantly reduce soil thermal conductivity and diffusivity. Still, there wasn't a significant influence on soil heat capacity in most soil moisture content levels. With the decrease of soil bulk density, soil thermal conductivity, capacity, and diffusion coefficient reduced significantly. As soil water content increased, all the indexes of thermal properties largely improved, and the effects were much more significant than those of biochar amendment and bulk density change on soil thermal performances. This research could supply an implication to evaluate the influence of biochar amendment on soil thermal performances. [ABSTRACT FROM AUTHOR]